But If I want to create a New file if I hit CTRL + Return
when I am over CamelCaseWord with the cursor.

That's because viki isn't enabled for the new buffer. It has to be set for every buffer.

If I want to active :VikiMode nothings happens. No highlightning of
Headings, list, CamelCase, ...

Is this the same buffer, in which you did :VikiMinorMode before? In this case, a variable b:vikiEnabled is set that would make :VikiMode exit before doing anything else. Try :set ft=viki.

Regards,
Thomas.

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