At 07:30 -0700 7/22/09, trag wrote:
>On Jul 21, 3:02 pm, Aaron Parker <[email protected]> wrote:
>> Any tips for thoroughly cleaning the mainboard of some of these older
>> devices?  I've got an Apple II Plus and two Apple IIe's that were not well
>> cared for (yet still power on) that I'd like to clean up.
>
>The boards can be cleaned with a number of solvents.   If you still
>have a shop in town that sells electronics supplies you might check
>there for a can of flux remover or flux cleaner.   This will remove
>pretty much any kind of crud from your board.  You'll want to use it
>outside, as flux remover tends to include things like toluene and
>MEK.
>
>Other acceptable solvents are isopropyl (rubbing) alcohol, provided it
>does not contain any skin lotions, so the only ingredient besides
>alcohol should be water.   Our local grocery sells a 91% solution.
>Home Depot sells a one gallon can of denatured alcohol which would
>work, but that's probably a bit more than you'll ever need.
>
>Finally, for the last rinse distilled water is a good choice.
>
>Or you can run it through the dish washer with no detergent and no dry
>cycle...

Until the European RoHS rules changed the composition of solder around 2000 AD 
there were well established solvents and flux cleaners that were specifically 
listed and known to circuit board and component designers.

Toluene and Methyl-ethyl ketone were never on that list. Nor was acetone which 
is methyl-methyl ketone and removes nail polish.

Isopropyl and ethyl alcohol were specifically approved. Trichloro ethylene was 
but is now considered carcinogenic as is Toluene which is two benzene rings 
tied to each other.

Clean water has always been allowed. De-ionized water which is quite corrosive 
and difficult to use was approved.

The various plastics on boards were all carefully chosen to be resistant to the 
alcohols. You will not dissolve the memory sockets or the plastic casing of 
transistors with either of them.

Initial assembly of the circuit boards consists of raising the temperature of 
the board almost to the melting point of solder and then flashing for a couple 
of seconds to a bit over 200 centigrade for surface mount or passing over a 
wave of molten solder for through hole stuff that was used  in the Apple II era.

After soldering with tin-lead solder the board was washed. Ultrasonic in a 
tricloroethylene bath was neat but poisonous. It was replaced by water-based 
dishwasher technology though alcohol was good at removing the resin flux used 
for tin-lead solder. Boiling water temperatures are nothing compared to the 
soldering temperature.

But there is a rub that cannot be ignored:

>>>> There may have been special components that contained plastics or had heat 
>>>> sensitive properties that were placed on the board by hand after the 
>>>> cleaning.! <<<<

Water is always OK. It's cleaning the water up that's the problem. You mustn't 
leave residue that can interfere with connectors. A rinse with distilled water 
before drying can help. You can also remove water with a dip in alcohol which 
will absorb the water so you can shake off the mixture. But the alcohol needs 
to be dry - meaning not the rubbing alcohol which can be 50 % water.

For completeness, but not the OP's problem, RoHS means tin-lead solder is not 
allowed and resin flux no longer works. Soldering temperatures are higher and 
acid flux is used. High temperature washing with proprietary flux removers is 
needed to prevent later corrosion. That all means the washing rules for modern 
stuff are different. Flux-cleaner for that kind of solder is quite different 
than what you would use for the tin-lead on an Apple II.

Personally I use gallon jugs of isopropanol that I get from a commercial 
cleaning establishment. It's advertised as "dry absolute" meaning no water at 
all but that's a lie. After you open the container the alcohol absorbs water 
from the air so it doesn't stay really dry but's it's a lot better than rubbing 
alcohol.
 
I worry about denatured alcohol. It has additives to make it poisonous so you 
won't drink it but you can never find out what the denaturants are.  Might they 
affect the circuit board? Methanol was once added but that makes you blind and 
I suspect the lawyers don't approve of that anymore.

-- 

--> From the U S of A, the only socialist country that refuses to admit it. <--

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