Jones,
I looked up your thread on Spill Over from last month which
I annotated below in light of your response to RE: [Vo]:Homogeneous Gold
Catalysis: Mechanism and Relativistic Effects of the Addition of Water to
Propyne <http://www.mail-archive.com/[email protected]/msg40974.html>
Regards
Fran
Jones Beene
Sun, 07 Nov 2010 15:54:17 -0800
"Spillover hydrogen" is a subset of 'adsorption spillover'
In the case catalytic or adsorbent systems where a metal species is
dispersed upon a support (or carrier) material (often quasi-inert oxides,
such as alumina or silica), it is possible for an adsorptive species to
indirectly adsorb to the support surface under conditions where such
adsorption is thermodynamically unfavorable.
SIDE NOTE "thermodynamically unfavorable" is not quite "overunity" in
itself, but is interesting in the context of "negative energy". ( to be
explained).
The presence of the metal serves as a lower-energy pathway for gaseous
species to first adsorb to the metal and then diffuse on the support
surface. This is possible because the adsorbed species attains a lower
energy state once it has adsorbed to the metal, thus lowering the activation
barrier between the gas phase species and the support-adsorbed species.
Ø This lower energy pathway may be relativistic - equivalent negative
acceleration quantized by Casimir geometry
Ø In the other thread they point to relativistic catalysis in gold where
maybe the lattice geometry is shaping dispersion forces?
Hydrogen spillover is the most common example of adsorptive spillover. In
the case of hydrogen, adsorption is most often accompanied with dissociation
of molecular hydrogen (H2) to atomic hydrogen (H), followed by spillover of
the hydrogen atoms.
Ø I believe the relativistic Atoms transition to a relativistic state
freely where you say The presence of the metal serves as a lower-energy
pathway for gaseous species to first adsorb to the metal and what you refer
to as spill over most often accompanied with dissociation of molecular
hydrogen (H2) to atomic hydrogen (H) is where I suggest the relativistic
atoms that form relativistic molecules can be disassociated at a discount by
exploiting motion induced by gas law that the a covalent bond opposes so
as the individual atoms in the molecule try to transition to a different
relativistic value the covalent bond weakens allowing for the possibility of
more energy being released upon formation than that which is required to
disassociate
.thermal runaway.
The spillover effect has been used to explain many observations in
heterogeneous catalysis and adsorption (see, for example, Rozanov and Krylov
1997), and has been proposed as a means of efficient hydrogen storage. END
of Wiki quote
Why is this phenomenon related to LENR? . and 'related' could be an
understatement ! Spillover could end up being the heart and soul of
gas-phase LENR - the missing link that finally cracks the case, so to speak.
My thinking is that spillover is the precursor step to "pychno" or dense
hydrogen (deuterium) and/or Rydberg matter. It could also be what Mills
misidentifies as being "below ground state".
Ø Or what Naudts calls Relativistic hydrogen and IMHO leads to a
relativistic interpretation of Casimir effect
Ø http://byzipp.com/energy/
BTW although the hydrogen molecule is not bosonic - the monatomic atom would
be bosonic in principle - but catch-22 you seldom see it listed as such,
because normally monatomic hydrogen has an extremely short lifetime - if
indeed it is not an abstraction in normal chemistry.
Ø Again a relativistic interpretation would explain why Naudts and
Bourgoin could use equations where electrons occupy the same state and
spatial position. From the perspective of different inertial frames hydrogen
atoms could all appear to be in the same spatial position while physically
separated due to time dilation
That is. IF . it is not first involved in the spillover/densification
process. Being a boson can be all-important since bosons with the same
energy can occupy the same place in space, and spillover gets them part of
the way there. Next they need to lose kinetic energy to get to the same
energy state. How can that happen?
Well, I will save this next key detail for the next installment of "Phrase
of the Day": "negative energy".
Negative energy is colder than cold, and it is to be found in many mundane
places - notably the Casimir Cavity. Or so it is claimed.
Gene Mallove would be pleased, as it resonates with "Fire from Ice". BTW -
if you haven't seen it, here is his Memorial Website:
http://www.eugenemallove.org/
Jones
