If you like playing with rattlesnakes, Lithium Hydride melts at 680 C and
with electrolysis liberates Hydrogen at the anode.
 
 
http://www.espi-metals.com/msds's/Lithium%20Hydride.htm
 
 
http://www.ucc.ie/ucc/depts/chem/dolchem/html/elem/elem001.html

"For example, on the electrolysis of fused lithium hydride, the hydrogen is liberated at the positive electrode (i.e. a negatively charged hydrogen ion is discharged), and not the negative electrode as is the case when water is electrolysed."

A metal can pressurized with  argon  perhaps?

Frederick

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