Jones Beene wrote:

>
> Fred - what do you think about this....
>
> Nitrogen is roughly 80% of air and has little value as an
> oxidizer. Oxygen is a strong oxidizer. All strong oxidizers
> can technically be called fuels, especially if they can be
> enriched to the level of being able to superoxidize water.
> Moreover, in the process of liquefying air, it is just as
> efficient (almost) to both liquefy and enrich the end
> product in oxygen. LOX has drawbacks and is not really
> needed.
>
You can buy a good used Medical Oxygen Generator that uses molecular sieves
to get 95% or better purity at the rate of 1.1 lb/hr O2 and about 4 lb/hr
N2 using
less than 700 watts out of the wall socket.
If you prefer to liquify the rejected N2, all you need is a $70.00 window
air
conditioner, an air compressor and some plumbing to crank out
about 100 lb/day LN2 at a cost of about 10 cents per pound. 
IF that Swiss LN2 operated motor (60 kW that will fit in a shoe box) gets
the claimed 40 miles per liter you can get by at a fuel cost of a
penny/mile. :-)
> By compressing air in two stages (which is normal) and
> separating the "first" stage of expansion magnetically
> (oxygen has good paramagnetism, nitrogen no) then you can
> chill the second stage with the nitrogen separated from
> stage-one and not loose any significant energy. IOW
> producing liquid enriched air of about 40% O2  content is
>
> However, one must realize that unless the electricity used
> to liquefy air or any gas mixture is coming from a nuclear
> plant (or wind, solar etc), there will still be carbon
> released "somewhere" to make any cryo-liquid. 
>
Of course, but where do you think the energy for recharging batteries or
converting methane or coal to hydrogen is coming from?
>
> Nevertheless, this still could be beneficial as the Carnot numbers make it
> more appealing than many realize. Plus during the cryogenic
> stages, some CO2 can be removed but not nearly as much as is
> produced in a coal fired plant making the electricity. It
> still beats a gasoline engine in all respects.
>
Sure does.
>
> This ability to separate magnetically is due to differences
> in electron distribution, called the Lewis structure.  O2
> has an unpaired electron on each atom. Molecules with
> unpaired electrons are paramagnetic and exhibit magnetic
> properties. With oxygen the magnetic properties are pretty
> dramatic, as the following images show.  The Lewis structure
> of N2 does not have unpaired electrons. Molecules with no
> unpaired electrons that do not exhibit magnetic properties
> and are diamagnetic and very easy to separate in the first
> stage of a two stage liquefaction process .
> http://www.chem.uiuc.edu/clcwebsite/liquido2.html
>
Interesting.

Frederick
>
> Think about it. What would you rather have - a real liquid
> fuel or a real chill....
>
> Jones
>



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