Robin van Spaandonk wrote:
>
> In reply to  Frederick Sparber's message of Wed, 26 Oct 2005
> 05:40:57 -0500:
> Hi,
> [snip]
> >> Now that said, I fail to see why momentum can't be conserved
> >> between a molecule and an emitted photon. IOW why doesn't H
> >> recombine under emission of UV?
> >> 
> >Moot point.  Where is Ronny Bar-Gadda going to get the mole of 4.525
plus a mole of 5.17 eV
> >UV photons to split the H-OH  and O-H bonds respectively, when you can
take advantage
> >of the free energy of auto-ionization of water and use ~2.0 eV to
separate them?
> >
> >Or the Iodine-Sulfur thermal water-splitting process.
> >
> >Pie in the sky?  :-)
> >
> >FJS
> It may be a moot point, but I still want to know the answer.
>
My best shot at that first would be a look at the momentum
of the photon, mc = E/c and the momentum of the atom/molecule
mv from Boltzman's  K.E. = 0.5 mv^2 = kT.
Then a look at the Raman Effect, Compton Effect, and the Lamb Shift.
If memory serves there was an experiment ( ca. 1980) that involved an
infrared laser
shined on a gas and the frequency shift noted. This was done at the Arizona
University where Willis Lamb was on staff.

Google away, Robin.   :-)

Fred

>
> Robin van Spaandonk
>
> http://users.bigpond.net.au/rvanspaa/
>
> Competition provides the motivation,
> Cooperation provides the means.



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