On Mar 1, 2006, at 10:43 AM, Steven Krivit wrote:

Does anybody wish to comment on this sentence?

"The primary greenhouse gas is water vapor, not carbon dioxide.7 "

Quote Source: http://www.nationalcenter.org/TSR020905.html

Quote Reference: "The Greenhouse Effect and Greenhouse Gases: An Overview," Energy Information Administration, U.S. Department of Energy (available at http://www.eia.doe.gov/cneaf/pubs_html/ attf94_v2/chap2.html) for a good summary of this issue understandable to the layman.


The above link appears to be no longer current.

The author of the above referenced line appears to have no appreciation for the effect high altitude water vapor, or of global warming on high altitude water vapor, and thus for the powerful feedback effect that is present.

There is a notable lack of H2O in the DOE Global Warming Potentials link:

http://www.eia.doe.gov/oiaf/1605/gg02rpt/pdf/appendixg.pdf

In fact, it states: "Short-lived gases such as water vapor, carbon monoxide, tropospheric ozone, and other ambient air pollutants (e.g., nitrogen oxide, and non methane volatile organic compounds), and tropospheric aerosols (e.g., sulfur dioxide products and black carbon), however, are present in very different quantities spatially around the world, and consequently it is difficult to quantify their global radiative forcing impacts. GWP values are generally not attributed to these gases that are short-lived and spatially heterogeneous in the atmosphere.11 "

However, it is high altitude water vapor that is the ultimate concern. Low altitude water vapor increases the Earth's albedo, but high altitude water vapor acts as a greenhouse gas, both here and on Venus. There is a good discussion of the Earth greenhouse effect at:

http://en.wikipedia.org/wiki/Greenhouse_effect

however, this discussion is centered on things as they are now, not as they will be as runaway global warming occurs. For that Venus serves as a better model. The non-linear response of high altitude water vapor to sea warming is astounding. See:

http://www.nasa.gov/centers/ames/news/releases/2002/02_60AR.html

which states: "Rabbette analyzed clear-sky data above the tropical Pacific from March 2000 to July 2001. She determined that water vapor above 5 kilometers (3 miles) altitude in the atmosphere contributes significantly to the runaway greenhouse signature. She found that at 9 kilometers (5.6 miles) above the Pacific warm pool, the relative humidity in the atmosphere can be greater than 70 percent - more than three times the normal range. In nearby regions of the Pacific where the sea surface temperature is just a few degrees cooler, the atmospheric relative humidity is only 20 percent. These drier regions of the neighboring atmosphere may contribute to stabilizing the local runaway greenhouse effect, Rabbette said."

Additionally, methane is lighter than air. As far as I know, little has been made of this fact. In the atmosphere, methane ultimately oxidizes to form CO2 and water vapor. Methane released directly into the air can thus be assumed to oxidize mostly at a high altitude. The coming arctic methane release will have a significant effect in the upper atmosphere due to methane's atmospheric life of 12 years. (For methane life see Table G1 in
http://www.eia.doe.gov/oiaf/1605/gg02rpt/pdf/appendixg.pdf).

I earlier made a number of relevant comments on vortex, summarized with references at

http://mtaonline.net/~hheffner/LastResort.pdf

and in 1998 debates on s.p.f, summarized with a few more current related references at

http://www.mtaonline.net/~hheffner/MJonesSPF.pdf


Horace Heffner

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