On Jun 8, 2007, at 10:58 AM, Michel Jullian wrote:

That's what I said:
"...some ambiguities slipped in:
...
"current is said to flow from the cathode to the anode" without saying they talk about external current (internal current goes the other way)."


Yes, you're right. I should have said: "I agree, EB got it backwards, or at least incomplete or misleading. The conventional current flows from the anode to the cathode in the electrolyte."

They might have said: "For historical reasons, electric current is defined to flow in the direction positive charge carriers move or would move, if present, to carry the current in a circuit. Thus, current is said to flow from the anode to the cathode through the electrolytic cell, and from the cathode to the anode in the part of the circuit which is external to the electrolytic cell. The current flow directions are reversed when an electrolytic cell acts as a battery."

Regards,

Horace Heffner

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