I'm surprised that many of you go through elaborate
alternatives to the simple possibility that the second law
of thermodynamics is weak at the nanometer scale. Is 2LoT
worth such devotion?
If thermally driven random movements of molecules or
mobile charges cause some of these particles to be in a
temporarily higher energy state and the higher energy
particles can be delivered to a process that brings them
down to an average energy state so energy can be extracted
from the particles as they return, 2LoT is not violated
for the particles involved but 2LoT is violated in the
outcome where zero grade ambient heat is reduced and an
energy output produced. Maxwell's demon was devised to
distinguish the kinetic theory of heat from the caloric
fluid theory by allowing for such usable particle energy
variations. Unfortunately, the demon required optical
sensing which consumes more energy than the use of sorted
higher energy states would produce. Smoluchowski's
trapdoor does not need an energy consuming detector.
Particles push through a trapdoor blindly if they have
enough energy to do so. The trapdoors don't need springs
because a higher pressure is built up behind the one way
openable door, closing it until a high energy particle
pushes in.
A diode is a practical electronic form of Smoluchowski's
trapdoor.
Aloha,
Charlie
- [Vo]:RE; diode array in photodiode array Charles M. Brown
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