I'm surprised that many of you go through elaborate alternatives to the simple possibility that the second law of thermodynamics is weak at the nanometer scale. Is 2LoT worth such devotion?

If thermally driven random movements of molecules or mobile charges cause some of these particles to be in a temporarily higher energy state and the higher energy particles can be delivered to a process that brings them down to an average energy state so energy can be extracted from the particles as they return, 2LoT is not violated for the particles involved but 2LoT is violated in the outcome where zero grade ambient heat is reduced and an energy output produced. Maxwell's demon was devised to distinguish the kinetic theory of heat from the caloric fluid theory by allowing for such usable particle energy variations. Unfortunately, the demon required optical sensing which consumes more energy than the use of sorted higher energy states would produce. Smoluchowski's trapdoor does not need an energy consuming detector. Particles push through a trapdoor blindly if they have enough energy to do so. The trapdoors don't need springs because a higher pressure is built up behind the one way openable door, closing it until a high energy particle pushes in. A diode is a practical electronic form of Smoluchowski's trapdoor.

Aloha,
Charlie

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