A completely filled curved cylinder on its side would be best, especially if 
the curvature was smaller on one side than the other.

 

A vertical tube shaped like a Force-Free Spiral (google this!) would probably 
be the very best, but very tricky to design and build.

 

Scott
 


From: jone...@pacbell.net
To: vortex-l@eskimo.com
Subject: RE: [Vo]:Scott on Mpemba effect
Date: Sun, 11 Apr 2010 08:32:04 -0700







Pardon the wordy and repetitive prior post… geeze …. one might think I got 
locked out of my car yesterday J
 
There was one point I forgot to make – which might make a good subject for 
further study: the “geometry of the container being used” for freezing and how 
the shape of that container might affect convection, and more particularly the 
“momentum of convection” as it becomes cooler and the active zone becomes 
diminished.
 
My premise is that “convection-inertia” will be maintained at a higher level 
with a geometry that promotes a symmetrical and circular flow. Why? 
 
A form of inertia applicable to convection currents might be rotational inertia 
(moment of inertia), which refers to the fact that a rotating body maintains a 
state of uniform rotational motion. The “body” in this case is not rigid, but 
there is some similarity and analogy.
 
Assuming that conservation of angular momentum is applicable, then – the 
geometry of the freezing container could come into play if it promotes or 
hinders that factor. We might expect the Mpemba effect to be minimal with a 
capillary tube, low with test tube, for instance - but maximized with spherical 
pyrex (labware).
 
Rotational inertia depends on a spin object (“metaphorical” ) and therefore its 
structurally integrity as a rigid body, would come into play - and any geometry 
that diminished that hidden “structure”, would thereby lower the convection 
rate (of the hotter container).
 
 
 
 
From: Jones Beene 
 
Yes, the “continuity” of an established convection rate, which Scott mentions - 
is the only detail not specifically addressed (but it is implied) in  Horace 
Heffner’s fine 10 yr old analysis which is still online at:
 
http://www.mtaonline.net/~hheffner/Mpemba.pdf
 
… and it is a key detail which is quantifiable by analyzing the convection 
currents over time.
 
A key point of Horace’s paper is that it takes as much heat transfer to drop 
~80 deg. C as it does to then freeze 0 deg. C water. 
 
The “heat transfer rate” then is the key to any anomaly – and this rate is 
controlled by convection currents which themselves have momentum.
 
“Momentum” then, or inertia, and its continuity - may be the key to any 
improved understanding… although it is implied in the prior analysis.
 
HH: “Convection currents can dramatically affect heat transfer rates, by 
exposing large volumes of the liquid directly to the heat transfer boundary, be 
that the container walls or the
ice itself. Slow moving molecules are culled out of the moving stream of water 
at the
water-ice boundary. If the water does not move, then the relatively slower 
mechanism of thermal conduction is all that remains to effect the freezing…. If 
the heat transfer rate at 0 deg. C is only doubled by the increased convection, 
then water with an initial temperature of less than about 39.9 deg. C will 
freeze at about the same time as water initially at 0 deg. C. *An almost 40 
deg. advantage is given to the hotter water.*
 
If the convection momentum is greater than doubled, which it probably is – then 
more than 40 degrees can be offset.
 
Jones
 
From: Wm. Scott Smith 
 
I think that water that is warmer than its surrounding will experience greater 
convection; this means that the water is set into a more vigorous motion that 
is sustained even as the temperature difference passes that of the more-still, 
originally colder water.
 
Scott
 
 

Remarkably consistent results. See:

http://arxiv.org/abs/1003.3185

A search for the Mpemba effect: When hot water freezes faster than cold water

James D. Brownridge 


(Submitted on 16 Mar 2010)

Abstract


An explanation for why hot water will sometime freeze more rapidly than cold 
water is offered. Two specimens of water from the same source will often have 
different spontaneous freezing temperatures; that is, the temperature at which 
freezing begins. When both specimens supercool and the spontaneous freezing 
temperature of the hot water is higher than that of the cold water, then the 
hot water will usually freeze first, if all other conditions are equal and 
remain so during cooling. The probability that the hot water will freeze first 
if it has the higher spontaneous freezing temperature will be larger for a 
larger difference in spontaneous freezing temperature. Heating the water may 
lower, raise or not change the spontaneous freezing temperature. The keys to 
observing hot water freezing before cold water are supercooling the water and 
having a significant difference in the spontaneous freezing temperature of the 
two water specimens. We observed hot water freezing before cold water 28 times 
in 28 attempts under the conditions described here.

 

- Jed

 
 



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