The recrystallization Temp of W is 1300-1500 C. Since it is known to
disassociate hydrogen when an arc is passed between tungsten electrodes for
atomic welding it might be a great candidate if it can form a nano powder
with the proper geometry. Although powdered tungsten properties remain the
same as bulk tungsten down to 1um , finer powders become pyrophoric – It is
suspected the high density of defects is responsible for the pyrophoricity.
This makes me suspect the disassociation capability will still be present
and could be maximized when oxygen is eliminated. My gut feeling is that
oxidation and hydride formations are actually poisons that cause this
quiescene  as a result of a very clean ZPE reaction that goes too far into
runaway.. The latest news regarding the negative TC for resistivity might
side step the quiescene issue by allowing a much faster control loop. A PWM
scheme that employs multiple resistance sensors and reaction sites might be
able to exploit the ZPE without entering into this poison zone. I think the
new reactor dimensions that DK mentions is a step in this direction since it
distributes the reaction sites and would facilitate multi sensors and
heating elements.

Fran

http://books.google.com/books?id=foLRISkt9gcC
<http://books.google.com/books?id=foLRISkt9gcC&pg=PA86&lpg=PA86&dq=pyrophori
c+tungsten&source=bl&ots=-suKEau0D2&sig=VM01tYvs5gF9_EDLIfxy-MvZLY8&hl=en&sa
=X&ei=SFgTT4aTCYb20gHT6I2ZAw&ved=0CCoQ6AEwAA#v=onepage&q=pyrophoric%20tungst
en&f=false>
&pg=PA86&lpg=PA86&dq=pyrophoric+tungsten&source=bl&ots=-suKEau0D2&sig=VM01tY
vs5gF9_EDLIfxy-MvZLY8&hl=en&sa=X&ei=SFgTT4aTCYb20gHT6I2ZAw&ved=0CCoQ6AEwAA#v
=onepage&q=pyrophoric%20tungsten&f=false

 

 

 

 

 

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