http://en.wikipedia.org/wiki/Lithium

Isotopes

Naturally occurring lithium is composed of two stable isotopes, 6Li and
7Li, the latter being the more abundant (92.5% natural
abundance).[3][13][23] Both natural isotopes have anomalously low nuclear
binding energy per nucleon compared to the next lighter and heavier
elements, helium and beryllium, which means that alone among stable light
elements, lithium can produce net energy through nuclear fission. The two
lithium nuclei have lower binding energies per nucleon than any other
stable nuclides other than deuterium and helium-3.[24] As a result of this,
though very light in atomic weight, lithium is less common in the Solar
System than 25 of the first 32 chemical elements.[1] Seven radioisotopes
have been characterized, the most stable being 8Li with a half-life of 838
ms and 9Li with a half-life of 178 ms. All of the remainingradioactive
isotopes have half-lives that are shorter than 8.6 ms. The shortest-lived
isotope of lithium is 4Li, which decays through proton emission and has a
half-life of 7.6 × 10−23 s.[25]

7Li is one of the primordial elements (or, more properly, primordial
nuclides) produced in Big Bang nucleosynthesis. A small amount of both 6Li
and 7Li are produced in stars, but are thought to be burned as fast as
produced.[26] Additional small amounts of lithium of both 6Li and 7Li may
be generated from solar wind, cosmic rays hitting heavier atoms, and from
early solar system 7Be and 10Be radioactive decay.[27] While lithium is
created in stars during the Stellar nucleosynthesis, it is further burnt.
7Li can also be generated in carbon stars.[28]

Lithium isotopes fractionate substantially during a wide variety of natural
processes,[29] including mineral formation (chemical precipitation),
metabolism, and ion exchange. Lithium ions substitute for magnesiumand iron
in octahedral sites in clay minerals, where 6Li is preferred to 7Li,
resulting in enrichment of the light isotope in processes of
hyperfiltration and rock alteration. The exotic 11Li is known to exhibit a
nuclear halo. The process known as laser isotope separation can be used to
separate lithium isotopes.[30]

Nuclear weapons manufacture and other nuclear physics uses are a major
source of artificial lithium fractionation, with the light isotope 6Li
being retained by industry and military stockpiles to such an extent as to
slightly but measurably change the 6Li to 7Li ratios even in natural
sources, such as rivers. This has led to unusual uncertainty in the
standardized atomic weight of lithium, since this quantity depends on the
natural abundance ratios of these naturally-occurring stable lithium
isotopes, as they are available in commercial lithium mineral sources.[31]

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