2013/3/15  <[email protected]>:
> Thank you for this.
>
> I tried csg_boltmann and got potentials and distributions for my bonds and
> angles. I tried to compare those distributions with those obtained by
> Gromacs using g_rdf -rdf mol_com
> and the equilibrium distance (maximum of distributions on x axis) lies in
> the same place but distribution obtained from gromacs is thousands times
> taller. Could you please explain this?
I guess, this is just a normalization issue. We calculate the
distribution P , not the histogram H.
Their relation ship is: P(r)= H(r) / (4*pi*r^2)
>
> Can csg_boltmann do dihedrals as well? Or would you recomment g_stat for
> this?
Yes, you can. You have to create a dihedral block (like the bond and
angle block) in the cg_bonded part of the mapping file, see the manual
for details.

Christoph
>
> Steven
>
> W dniu piątek, 8 marca 2013 17:21:31 UTC użytkownik Christoph Junghans
> napisał:
>>
>> 2013/3/8  <[email protected]>:
>> >
>> >
>> > W dniu poniedziałek, 4 marca 2013 18:02:23 UTC użytkownik Christoph
>> > Junghans
>> > napisał:
>> >>
>> >> Hi Steven,
>> >>
>> >> 2013/3/4  <[email protected]>:
>> >> > Dear Votca Users,
>> >> >
>> >> > I am new to the software. I tried some tutorials but many things are
>> >> > still
>> >> > not clear for me as my system is slightly more complex.
>> >> Welcome.
>> >
>> >
>> > Thank you for your prompt reply.
>> >
>> >>
>> >> >
>> >> > My atomistic simulation is one trimer of 3 amino acids in TIP3P water
>> >> > model.
>> >> > What I want to extract is just the bonded parameters by IBI between 3
>> >> > beads
>> >> > ech represented by amino acid.
>> >> >
>> >> > So the key is the tabulated potential of two bonded interactions and
>> >> > one
>> >> > angle. My questions:
>> >> >
>> >> > Does my reference simulation (atomistic) obtained by Gromacs should
>> >> > have
>> >> > [
>> >> > exlusions ] of non-bonded parameters so the potentials will be given
>> >> > only
>> >> > for bonded? Shall I include in my mdp file while performing
>> >> > atomistic:
>> >> > energy_grps so I can use g_energy then to see the bonded potential? I
>> >> > know
>> >> > VOTCA does this but not sure based on what kind of trajectory (with
>> >> > excluded
>> >> > nonbonded?).
>> >> Basically there are two strategies to obtain coarse-grained potential
>> >> for bonded interactions.
>> >> 1.) Separation of bonded and non-bonded. (see Tschoep et al. Acta
>> >> Polymerica 49, 61 (1998).)
>> >> - run the molecule in vacuum (without solvent) and exclude all
>> >> interaction, which are later covered by non-bonded interactions.
>> >> - use simple Boltzmann inversion to obtain the bonded interaction (use
>> >> csg_stat/awk or csg_boltzmann for that)
>> >
>> >
>> > Shall include [ exclusions ] in my atomistic simulation on vacuum of all
>> > atoms from the desired 1st bead with atoms from the 2nd and 3rd bead +
>> > exlclusions of atoms of the 2nd bead with atms of the 3rd? Or its better
>> > to
>> > group atoms in my index file in GMX - Bead1, Bead2, Bead3 and then
>> > in my mdp run:
>> > energygrp-excl = Bead1 Bead2    Bead1 Bead3    Bead2 Bead3
>> Energy group exclusions are on top of the topology, Gromacs has
>> another loop over all pairs of energy group.
>> And because they are not part of the molecular topology, VOTCA don't
>> know about them.
>>
>> But these exclusion would only matter if you calculate distribution
>> for atomic (unmapped) coordinated using csg_stat
>> As long the bead were somehow excluded during atomistic simulation and
>> are excluded after the mapping (csg_dump --cg --excl )
>> everything should be fine.
>>
>> > ?? How do you personally do it?
>> I usually put things in [exclusion], but that is more my personal
>> preference. Gromacs gets slower the more energy group you have, but
>> that is not so important for a single molecule in vacuum.
>>
>>
>> >
>> >> - obtain the other interaction by IBI of a cg simulation with the
>> >> above bonded interactions fixed (use csg_inverse)
>> >> 2.) Do IBI on all interaction (use csg_inverse)
>> >> - due to our lazyness in the implementation, you will also need
>> >> initial guesses for the bonded table here as well and hence you have
>> >> to the 2nd step of 1.).
>> >>
>> >> If 1.) or 2.) is better depends a bit on how stiff your bonded
>> >> interactions are and hence how good the separation works
>> >
>> >
>> >  In this case I think it is good to do the step 1 and then the table of
>> > bonded can be an input to the second one so results will be more
>> > realistic.
>> > Am I right?
>> In 2.) the tables for the bonded interaction are used as initial
>> guesses, an IBI update will still be applied on these, but it always
>> good to try 1.) first as it saves you a lot of time and work if it
>> works.
>> >
>> >
>> >>
>> >>
>> >> Concerning the exclusions, all VOTCA programs tolerate the exclusion
>> >> given in the tpr file if you don't map.
>> >> If you map first, VOTCA generates its own exclusion, which basically
>> >> mean every pair which is connected by a bonded interaction (specified
>> >> in the mapping file) is excluded. In both cases, exclusions can be
>> >> check using csg_dump --excl (together with --cg for mapped
>> >> trajectories).
>> >>
>> >> >
>> >> > Presuming I got my 3 bonded potentials (table.xvg). Shall i use in my
>> >> > CG
>> >> > run:
>> >> >
>> >> > mdrun -v -tablep tablep1.xvg tablep2.xvg -tablea tablea.xvg -deffnm
>> >> > md
>> >> >
>> >> > How Gromacs know which potential belong to which bond? Isnt it easier
>> >> > to
>> >> > fit
>> >> > the curve into the parabolic shape and extract both equilibrium
>> >> > distance/angle and the force constant adding to ffbonded.itp ?
>> >> Gromacs has a naming scheme for its tables.
>> >> For bonded tables:
>> >> <TRUNC>_<A,B or D><NR>.xvg
>> >> and for non-bonded tables:
>> >> <TRUNC>_<E1><_E2>.xvg
>> >>
>> >> TRUNC is determined by the -table (nonbonded) and -tableb (bonded)
>> >> options.
>> >> E1,E2 are energy groups
>> >> A,B,D stands for angle, bond, dihedral
>> >> NR is the integer you specify in 4th column for of the bonds or angles
>> >> block in the top file.
>> >> For example
>> >> [ angles ]
>> >> ;  ai    aj    ak funct    NR k
>> >>     1     2     3     8      1  1.0
>> >> (k ist another scale factor)
>> >>
>> >> I normally just use the default naming convention (mdrun without
>> >> -table options), which lead to table names like
>> >> table_A_B.xvg, table_b1.xvg and table_b1.xvg.
>> >>
>> >> Christoph
>> >>
>> >> >
>> >> > I am sorry for basic questions but it is not clear to me.
>> >> >
>> >> > Thanks,
>> >> >
>> >> >
>> >> > Steven
>> >> >
>> >> >
>> >> >
>> >> > --
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>> >> >
>> >> >
>> >>
>> >>
>> >>
>> >> --
>> >> Christoph Junghans
>> >> Web: http://www.compphys.de
>> >
>> > --
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>> >
>> >
>>
>>
>>
>> --
>> Christoph Junghans
>> Web: http://www.compphys.de
>
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>



--
Christoph Junghans
Web: http://www.compphys.de

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