I meant that is there any method to modify the tabulated angle potentials, 
which are generated by inversion Boltzmann distribution? I think that my 
angle potentials are wrong and hence the angular distribution due to the AA 
simulation and those obtained after the coarse-grained simulation are 
mismatched. 

On Friday, September 9, 2016 at 8:26:07 PM UTC+5:30, Christoph Junghans 
wrote:
>
>
>
> 2016-09-09 5:39 GMT-06:00 ArS <[email protected] <javascript:>>:
>
>> Dear VOTCA users,
>>
>> I am coarse graining a surfactant molecule. I am deriving the bonded 
>> potentials using Boltzmann inversion. First I got the distributions of 
>> bonds and angles due to mapping of atomistic model to a coarse-grained 
>> model, and from those distributions, bonded potentials were derived.
>> Then those potentials were used during the simulation. The non-bonded 
>> potentials are obtained using the MARTINI force-field. After the 20 ns NPT 
>> run of the coarse-grained system, I again checked for the distributions of 
>> bonds and angles. While comparing the distributions due to AA-model and the 
>> CG-model, the bond distributions match well but the angle distributions do 
>> not. Specially for the head bead, the angle distribution is very different. 
>>
>> This is how I generated the angle distributions by mapping AA model to CG 
>> model:
>>
>> cat boltzmann_btm_analysis_angle_shape  | csg_boltzmann --top 
>> ../../../npt.tpr --trj ../../../npt-180ns.xtc  --cg ../btm.xml --map-ignore 
>> "STE;Cl;SOL"
>>
>> The "boltzmann_btm_analysis_angle_shape" is written as:
>>
>> hist angle.dist.ib *:angle1:* 
>> tab set T 283
>> tab set scale angle1
>> tab angle.pot *:angle1:*
>> q
>>
>> After a run 0f 20 ns, the angle distribution of the coarse-grained model 
>> is generated as:
>> cat boltzmann_shape  | csg_boltzmann --top ../table.tpr --trj 
>> ../table.xtc --cg map_btm.xml  --map-ignore "STE;CL-;W"
>>  
>> The boltzmann_shape is written as:
>> hist bond.without_shift_btm1.ib *bond1:*
>> hist bond.without_shift_btm2.ib *bond2:*
>> hist bond.without_shift_btm3.ib *bond3:*
>> hist bond.without_shift_btm4.ib *bond4:*
>> hist bond.without_shift_btm5.ib *bond5:*
>> hist angle.without_shift_btm1.ib *angle1:*
>> hist angle.without_shift_btm2.ib *angle2:* 
>>
>> hist angle.without_shift_btm3.ib *angle3:*
>> hist angle.without_shift_btm4.ib *angle4:*
>> q
>>
>> While generating the tables for bonded and anglular potentials, I used 
>> csg_resample command, in the --grid option, I used step of 0.002 (example 
>> :  --grid 0.00:0.002:3.142). Similarly, while exporting the tables using 
>> csg_call --options, in the table.xml file, table_bins value is 0.002. 
>> If I change the step and the table_bins values, can I get a better angle 
>> potential so that the angle distribution of CG model matches with that of 
>> the AA model? 
>>
> I am afraid no, changing the bins sizes does very little to the potential 
> and hence the distribution. Making the bins size smaller might help to 
> resolve some peaks better, but it won't help with the shoulders of the 
> distribution.
>  
>
>> If there is any other way to modify the coarse-grained distribution, 
>> please suggest me. 
>>
> Use a different coarse-graining technique, e.g. force matching.
>  
>
>> How can I shift the angle distributions?
>>
> What do you mean by shifting?
>
> Christoph
>
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>
>
>
> -- 
> Christoph Junghans
> Web: http://www.compphys.de
>

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