(sorry, the minus sign should stay as minus - my head is a little bit too 
tired atm :"D )

Em sexta-feira, 26 de maio de 2023 às 14:33:44 UTC+2, Cecília Álvares 
escreveu:

> Hey there,
>
> As I am about to start doing some force-matching, I have been checking the 
> official Parrinello FM paper and also the official publication VOTCA's 
> publication to try to understand the mathematical formalism and how it is 
> implemented. I was wondering if there is a typo in the equation (22) for 
> C_kappa. I am asking because, unless I am stupidly doing some bad basic 
> math, the second derivative of f(kappa), which is meant to hold during an 
> interval [kappa_n, kappa_n+1], will not have its due value at the limits of 
> the interval.
>
> Would the correction be the one I showed below? If so, is it indeed the 
> only place in which I should have kappa_n+1 instead of kappa_n in the 
> equations of C_kappa and D_kappa?
>
> [image: Untitled.png]
>

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