Hey Christoph

You are right, from looking in the literature it does seem complicated.. 
and my idea of doing some interpolation is not very rightful because by 
doing that I would be introducing "forces" at given pairwise distances 
which do not come from predictions from the force matching method. I mean, 
if the whole purpose is to find a potential that reproduces the forces, I 
think I would jeopardize the whole thing to one extent or another if my 
superatoms end up being, even if for a tiny moment, in the artificial 
repulsive regions I was planning to introduce.

I saw some people who do FM at high temperature in order to get the 
separate peaks to merge. Seems to have worked for me for the peaks sitting 
at > 10 angs. And since my first and second peaks in the RDF I showed comes 
from 1-2 and 1-3 neighbors, I could assign them a separate bonded potential 
instead. I still have some other problems in the potential I am obtaining 
but I will figure out :))

Thanks!
Best,
Cecilia

Em sábado, 3 de junho de 2023 às 16:20:38 UTC+2, Christoph Junghans 
escreveu:

> On Wed, May 31, 2023 at 4:27 AM Cecília Álvares
> <[email protected]> wrote:
> >
> > Hmm.. maybe this is actually a very stupid question, because, given that 
> the potential is built by using splines that hold within a small 
> subinterval defined in <step>, I suppose I could get the same result by 
> splitting the ranges of non-zero RDF in different interactions. (it should 
> give the same results, right?)
>
> The reason why we haven't implemented support for non-continuous
> domains is mainly that it is complicated to get all the cases right
> and so we thought one could just do a piecewise ibi and then combine
> it.
>
> Christoph
>
> >
> > Em quarta-feira, 31 de maio de 2023 às 12:07:35 UTC+2, Cecília Álvares 
> escreveu:
> >>
> >> (I mean, in this case, I could get "chops" of how the potential would 
> look like in different intervals (corresponding to g(r) != 0) and I later 
> can connected the different portions by doing some sort of interpolation 
> myself.)
> >>
> >> Em quarta-feira, 31 de maio de 2023 às 11:54:18 UTC+2, Cecília Álvares 
> escreveu:
> >>>
> >>> Hello everyone,
> >>>
> >>> I was wondering if there is a way to define a "non-continuous" domain 
> interval when setting up the settings.xml file to do force-matching of 
> non-bonded potentials (for example) within VOTCA. I mean, in my case, since 
> I am deriving potentials for a xtalline solid, I have peaks in the RDF that 
> go up and down back to 0 (e.g. below), which would give rise to non-sampled 
> intervals for the potential if I was to use a continuous interval for rij 
> going from the first peak to the last.
> >>>
> >>>
> > --
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>
>
>
> -- 
> Christoph Junghans
> Web: http://www.compphys.de
>

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