Hi,

try

\documentclass{article}
\usepackage[osf]{libertine}

\newfontfamily\libertineX[Mapping=tex-text,
                          RawFeature=+liga% ;+pnum
                         ]{Linux Libertine O}

\begin{document}
A0123456789

{\libertineX
B0123456789
}

A0123456789

\end{document}

tested with libertine.sty 4.8.4 and xelatex 3.1415926-2.2-0.9997.4 (TeX Live 2010).

You can change the rawfeature as you like.
smcp, frac, hlig, dlig, lnum, pnum, zero, ...

By
Michael



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