Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG -- ONE MORE ...

2006-03-09 Thread MexicoDoug
Hola Sterling, and thank you for the gracious email.  Hopefully this gas 
cooled down; I won't go for another round on this one now, I promise.  I pray 
the 
tektite debate won't continue until after we are dust, but in some places, 
probably you are dead right there.

I've always thought that one of the great advantages of American education's 
system is the frequently criticized postal service and open communications in 
research, plus the Universities' quickness to pay for the postage of its 
faculty members without too many questions, and the researchers desire to share 
their work with other professionals and neophytes alike.

I'm really sad you don't have the access level you'd like, it reminds me of 
our situation in Mexico - So far from God, but so near to the USA.  
Thankfully, ten-year old Meteoritics full text articles are usually available 
from the 
Harvard NASA Smithsonian ADS service, so at least you can see et. al. 
including Dr. Koeberl's original article there:

http://adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992Metic..27R.298Tl
ink_type=GIFdb_key=AST

Oops wrong one.  This particular article is a provocative one though for 
another thread, with much more application that it ever dreamed and a lively 
subject for discussion where some meteoritical forensics can actually weigh in 
on 
these disputes.

So that you are properly armed and dangerous next time, here's the right link 
to Dr. Koeberl's article we discussed:
http://adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1991Metic..26...41Md
b_key=ASTlink_type=ARTICLE

As far as Guy Heinen's book, your second hand source, all I can say is that 
it is a superb collection of information under one roof, but as you can see, 
despite all their efforts, the translation probably has some issues, and as you 
found out, the table and conclusions were not very clear.  And the paper 
actually was more of a study of the Zhamanshin Crater, its source rock, and 
tektite-like Irghizites and then a suggested path to pursue bigger problems.  
Amazing, considering Dr. Koeberl helped edit the book, but I promised not to 
get 
into this, and the researchers are all good ones.  At least I can take solace 
now in the fact that the cosmo- and geochemists weren't really in a conspiracy 
to get me*, it was just a very motivated amateur astronomer who teaches 
elementary school in his paid time.  He sounds like he could be a very welcomed 
asset 
to out discussion group, though I don't know him personally!!

I completely agree with you regarding the clues in Fluorine, whether alone or 
with Boron, so I can't really add anything to what you've already said there, 
other than clues being relatively common, but true conclusions and 
generalizations are so darned elusive.

*Did I mention I am a lowly physical chemist?  Lowly, because at least here 
in Mexico, we can't seem to get much respect from the geologists.  It is 
really a sad situation but there is a distinct bias you could cut with a knife. 
 
And even the most prolific and one of the most distinguished Geologist of our 
State University's Geology Department is actually a Chemist like me, and he 
still get's a Rodney Dangerfield...
  

Saludos and best wishes, Doug



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Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-06 Thread Sterling K. Webb

Hi, Mike,

   The hypervelocity impact has always been
in the running for The Tektite Source, off and on.

   The worse case would be a comet with an
orbital eccentricity of .99 in a retrograde orbit.
In other words, a first-timer falling out of the
Oort Cloud from 10,000 AU or 20,000 AU
out that's traveling like the proverbial bat out
of hell by the time it gets to the inner Solar
System that would then smack into the Earth
when we're headed right for it. All the bad
luck in the world.

   A comet's still bound to the Sun's gravity,
so we can figure its velocity at the Earth's orbital
distance, sum up all the bad-luck velocities, and
get a maximum possible impact velocity of about
73.4 km/sec. That for any object gravitationally
bound to the Sun (not an alien spacecraft under
power), but comets are the only likely ones.

   The average impact velocity we'd get from
a NEA would be 15-20 km/sec, so the retrograde
comet hit would be about four times faster. Back to
the bad luck department: the energy depends on
the square of the velocity, so the bad-luck comet
hit would deliver sixteen times the energy per pound
than the usual mass-extincting disaster. Ouch x 16.

   So, it's really nice that the odds of a collision
with a long-period comet are so low... (To figure
those odds, calculate the area of a sphere with
a radius equal to the Earth's orbital distance,
divide by the cross-sectional area of the Earth's
disk, and you have the odds of any one long-period
comet, which could come from any direction,
hitting the Earth.) When all is said and done, the
chances are from one hit per 2,000,000,000 years
to one hit per 500,000,000 years, depending on
how frequent long-period comets are (argument
in progress).

   Really nice, because such a comet could just
as easily be up to 100 miles across or more, or
like the recent Hale-Bopp. (Was it only 40 or
60 miles across?) Getting hit by an object this size,
at any speed, makes the Big Kill All The Dinosaurs
Asteroid (10 miles across) look like a kid's fire-
cracker, a puny firecracker at that. Getting hit
by a 100 mile object is just plain unthinkable.

   Are there other big objects? Chiron, the
Centaur (which is both Comet 95P and Minor
Planet 2060) between Saturn and Uranus and
is about 160 miles across, was deflected there
by Jupiter (most likely).  All the Centaur objects
(all pretty big, over 100 of them!) are orbitally
unstable on a 100,000 year time scale and have
about a 20% chance of escaping inward
(and 80% outward). Root for them to head
outward, please.

   But comets in general have more eccentric
orbits than asteroids, which means higher impact
velocities in general, so their impacts are likely
to be more energetic (by the square, a mere 44%
increase resulting in double the punch).

   But even mildly big objects, 500 meters or
1000 meters, are not bothered by our atmosphere
one bit, even at a 30 degree angle. Air provides
great protection against small and medium bodies
but once you get up to the large size impactor,
it doesn't even slow it down. A 500 meter body
that would achieve 15 km/sec might only lose
less than 1 km/sec of that velocity, not a big help.
A 1000 meter (and up) body would lose even less
speed. A 10,000 meter body wouldn't slow down
at all.

   There are other reasons for suspecting a comet-
tektite connection, but I'm saving it for another post
to the List.

   Stay tuned.


Sterling K. Webb
-

- Original Message - 
From: Mike Fowler [EMAIL PROTECTED]

To: meteorite-list@meteoritecentral.com
Cc: Mike Fowler [EMAIL PROTECTED]
Sent: Saturday, March 04, 2006 11:11 AM
Subject: [meteorite-list] Largest Crater in the Sahara Desert and LDG


This is actually a more general point: there are lots and lots of  
impact

craters but very few tektite producing ones; why?


Sterling K. Webb



Why not very high velocity comet impacts, at a near vertical angle.   
Maximum cometary velocities would be about 10 times more than average  
asteroidal impacts.   Near vertical would reduce the atmospheric  
column that the explosion has to punch thru to the minimum.


Looked at from this point of view, perhaps only 1 in 100 crater  
producing impacts would qualify, which might explain why there are  
many large craters, but few tektite strewn fields.


Mike Fowler
Chicago
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Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-06 Thread MexicoDoug
Sterling W. writes:

Doug, the actual language Kroeberl uses
 is that the F/B ratio of tektites should tend
 toward 1.0. This is Professional Science
 Speak for too complex to model exactly,
 but most of the cows ought to stampede
 in this direction...

Hola Sterling, I asked you where you got the moldavite value for boron.  You 
are now a primary source on the Internet saying that moldavites have this 
content and some tektite man at some place like lpi may believe you...  It is 
very 
tedious to measure boron apparenty by spectrophotometric methods - it would 
be a fair question to ask you how you got it...Slap me, call me insulting, do I 
really deserve it because it sure sounded to me you might have invented the 
typical value of Boron=30 ppm in moldavites and pass it off as a typical 
number for moldavites because you got caught up in a roll fitting numbers to 
produce a 1.0 ratio you were trumpeting - when you had no such data.  If I am 
wrong please forgive me enough to be on speaking terms, and if I am right, 
please 
come clean.

Let me say I am much more comfortable with this last post you made than the 
prior last off-the-wall statements about tektite formation at 34,000 degree 
(you really did say this, I read all of your posting) plasma-formed tektites 
miraculously being heated in microseconds to the point where first fluorine is 
driven off to a theoretical identical level as boron, and then they diffuse 
out 
at identical rates ignoring petty chemical differences.

We could start with considering that at the temperature you quoted being 
reached, neither water, nor silicon dioxide the base material of tektite glass 
would survive, so I think you are confusing tektites with theoretical particle 
physics over a few pitchers in the Athenaeum.  I mean this in the nice way, and 
need to state it as it is the heart of my disagreement on the sloopy use of 
the data.  I am really entertained by your posts generally - you are probably 
my 
favorite poster!  But you have have mixed speculation with data here and 
taken liberties to mix them and present them labeled as fact. 

While Dr. Koeberl (please check the proper your spelling of your sources' 
surname) may have used the word tend as you state above, did it occur he just 
meant that the average of a few measurements was in a ballpark of 1?  Let's not 
turn this incredibly simple issue into a greased pig with talk of cows 
stampeding and so forth.  I don't need to sort it out with Dr. Koeberl as you 
suggested, I think his paper was self explanatory, well done though not one of 
his 
better ones, though it would have benefitted by someone proofreading better the 
English as to not give rise to such ambiguities in interpretation.  Also, as 
I asked you to kindly clarify, and you did, the sample size as I asked you to 
clarify was tiny - I'm not gonna let you off the hook on that yet.  

 And you're right; he didn't analyze that
 many samples. I wish he had more data.

Well, let's do better here: the paper has five tektite samples for which 
both fluorine and boron were determined.

He found one ivorite with a F/B ratio of
 0.40 (means more boron than fluorine).

Yes, he did. And you can't discount it.  It was one of only five samples.  
Call it an outlier if you wish.  But it totally nukes your wishful 
morphing-random walking diffusion plasmoid theory and imaginative mechanisms 
which you 
presented as fact.  

Most results were 0.8 to 1.2, which
 indeed is a 'tendency toward 1.0,
 if you think numbers have tendencies.

I don't think the numbers have tendencies in the sense you used them to build 
an astounding physicist view.  I think numbers are cold and cruel.  Let's 
look at the tektite numbers in the paper excluding the Muong Nongs as the 
authors 
suggest:
[F]/[B] ratios
Thailandite 1   1.2
Thailandite 2   1.5
Bediasite 1 0.8
Ivory C. tek. 1 1.2
Ivory C. tek. 2 0.4

Tending to 1.0?  Professional science speak huh?  No, no, no and no.  
Sorry, but no.  I'd go for Settle in the ball park of 1.0, provided no one 
uses 
Sterling's logic to shove Fluorine and Boron into one ball, and provided that 
no one saying and implying that these molecules or elements coordinate 
themselves to reach equal levels in time to loose their identies only to regain 
them 
again...

Degreasing the pig, let's grab a hold of it and cut to the throat of the 
issue.  You originally argued that LDG's were extremely hot like tektites 
pointing 
to this fluorine-boron thermometer and told us without references that the 
fluorine and boron values were 7 ppm each in LDGs, arguing that this made them 
comparable to heat for tektites, and that the low absolute ppm numbers (which 
were lowers than most tektites, btw).  You said that geochemists were behind 
this, not friendly physicists, and that all of this is established protocol 
for geo- and cosmo-chemists. You pointed to your theories of formation of 
tektites and then said this whole thing was not hatched by you.  

Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG -- ONE MORE TIME!

2006-03-06 Thread Sterling K. Webb
and their tektites do not match well
for all elements in ways hard to explain.
Paradoxically, the target rocks DO
produce impact glasses at the same
time and place; there are many varieties
of impact glasses at Ries, in addition to
the famous tektites, same for other sites.
The chemistry of these impactites do
not match the tektites from the same
location. Hmm.

   b) Tektites are all the same because
they are formed entirely from one specific
type of impactor (of which, for some
reason, we have no other samples, and
not at all from the local target rocks.
End of story.

   Anyone want to shave this puppy, or
is that greased pig, with Occam's Razor?



Koeberl?  Nah, let's just read his paper
to get it in writing: The low F and B contents
in LDG and Aouelloul impact glasses are most
probably due to low contents in the
precursor materials.


   Koeberl's most probably due sounds
suspiciously like he didn't test the source rock,
or look it up either. I translate most probably
due as I guess. Doesn't sound like hard
data to me. He doesn't say, Since Rock X
has F/B vaues of xxx/yyy... or even The
report of Messrs, A, B, and X give xxx ppm
for...  He doing the bread-and-butter thing,
writing a paper; if you have data, you use
it. But beyond that, arguing away some
parts of the results as due to characteristics
of the source rock ASSUMES that the
source rocks are the source of tektites,
but that's one of things we're trying to find
out, isn't it? Well, isn't it?

   Oh, and BTW, lighten up, Doug. People
will still be arguing about tektites long after
we're both dust, you know.


Sterling K. Webb
-
- Original Message - 
From: [EMAIL PROTECTED]

To: [EMAIL PROTECTED]; [EMAIL PROTECTED]
Cc: [EMAIL PROTECTED]; [EMAIL PROTECTED]; 
Meteorite-list@meteoritecentral.com

Sent: Monday, March 06, 2006 2:47 PM
Subject: Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG



Sterling W. writes:

Doug, the actual language Kroeberl uses
is that the F/B ratio of tektites should tend
toward 1.0. This is Professional Science
Speak for too complex to model exactly,
but most of the cows ought to stampede
in this direction...

Hola Sterling, I asked you where you got the moldavite value for boron. 
You

are now a primary source on the Internet saying that moldavites have this
content and some tektite man at some place like lpi may believe you...  It 
is very
tedious to measure boron apparenty by spectrophotometric methods - it 
would
be a fair question to ask you how you got it...Slap me, call me insulting, 
do I
really deserve it because it sure sounded to me you might have invented 
the
typical value of Boron=30 ppm in moldavites and pass it off as a 
typical
number for moldavites because you got caught up in a roll fitting numbers 
to
produce a 1.0 ratio you were trumpeting - when you had no such data.  If I 
am
wrong please forgive me enough to be on speaking terms, and if I am right, 
please

come clean.

Let me say I am much more comfortable with this last post you made than 
the
prior last off-the-wall statements about tektite formation at 34,000 
degree
(you really did say this, I read all of your posting) plasma-formed 
tektites
miraculously being heated in microseconds to the point where first 
fluorine is
driven off to a theoretical identical level as boron, and then they 
diffuse out

at identical rates ignoring petty chemical differences.

We could start with considering that at the temperature you quoted being
reached, neither water, nor silicon dioxide the base material of tektite 
glass
would survive, so I think you are confusing tektites with theoretical 
particle
physics over a few pitchers in the Athenaeum.  I mean this in the nice 
way, and
need to state it as it is the heart of my disagreement on the sloopy use 
of
the data.  I am really entertained by your posts generally - you are 
probably my

favorite poster!  But you have have mixed speculation with data here and
taken liberties to mix them and present them labeled as fact.

While Dr. Koeberl (please check the proper your spelling of your sources'
surname) may have used the word tend as you state above, did it occur he 
just
meant that the average of a few measurements was in a ballpark of 1? 
Let's not

turn this incredibly simple issue into a greased pig with talk of cows
stampeding and so forth.  I don't need to sort it out with Dr. Koeberl as 
you
suggested, I think his paper was self explanatory, well done though not 
one of his
better ones, though it would have benefitted by someone proofreading 
better the
English as to not give rise to such ambiguities in interpretation.  Also, 
as
I asked you to kindly clarify, and you did, the sample size as I asked you 
to

clarify was tiny - I'm not gonna let you off the hook on that yet.

And you're right; he didn't analyze that
many samples. I wish he had more data.

Well, let's do better here: the paper has five tektite samples for which
both fluorine

Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-05 Thread MexicoDoug
Sterling W. writes:

 I don't know the values for the Nubia Sandstone,
but the range of sandstones is fluorine 180 to 450
ppm and boron about 10 to 85 ppm. The figures
for LDG is fluorine 7 ppm and boron 7 ppm, so
you see how the ratios shift as the content drops.

As the temperature rises (microsecond by microsecond),
 the fluorine content drops much faster than the boron
 content. At some very high temperature (variable
 for each source rock), both fluorine and boron
 levels become the same, but at a higher level than
 in the final product.
 
 After that point, both are driven out of the melt
 plasma at the same rate, their petty chemical
 differences totally overwhelmed by the energy
 available. So, fluorine goes faster until that point
 is reached, after then, they drop together. 

Hola Sterling,
Petty chemical differenceshm.overwhelmed at moment x when they 
behave identically (this is the cartoon and then a miracle happens and we get 
the desired solution)...I hope you can do better than this!  This last 
paragraph has pegged my bogometer and the needle broke as I see physical laws 
being 
bent to accomodate your interesting and provolking speculations.  It's either 
the most unfounded, unscientific argument and counterintuitive I've ever heard 
you seriously make - or - you speak about this thermometer as if you actually 
were there watching the impact and taking notes by the microsecond on how 
Boron and Fluorine behave under singular circumstances and states that are 
poorly 
defined to start with!  I didn't dispute the use of [F]:[B] to compare 
different forms from the same source rock (a reasonable use of the 
thermometer), 
that is not what you are doing.  I hope you can see how you are pulling numbers 
from out of the air which are all over the map and cooking pretty conclusions 
out of them.  To answer my question, I'd back up and ask for the following 
modest data:
1. reference - Where you got moldavites bottoming out at [B]=30 ppm (for 
[F]=30 ppm, at least)?
2. Based on how many samples is your typical value [F]:[B] of Ivory Coast 
tektites and what was the low end for the ratio?  Was it a lot less than 1?  
How would your physics' scheme explain a value below 0.5 for the ratiosince 
you have re-enforced the point I most object to by saying they magically reach 
the same concentration and then decrease equally...
3. Without the respective values of F,B in Nubian sandstone near the crater, 
my question isn't anywhere near answered:( !!

You mentioned:
 It looks like LDG had a very hot forming event,
so the high water content is a real puzzle.
It's only a real problem puzzle in this context because you have read too 
much into and extrapolated much too far with the halogen thermometer concept.  
The water, rather than being a problem to explain, might be telling you that 
the 
F:B interpretation and extrapolations are all wet..., there is also a failure 
to consider different resident times for the measureables in the melt as yet 
another additional consideration.  Not to mention of course the alternative or 
coincident possibility that LDG's have that content due to the low or surface 
altitude at which they formed...

 And this:
ALL terrestrial rocks have a F/B ratio greater
than 5.0 (often 20 or 30). but all impact glasses,
even the weakest dirtiest just barely melted impact
glasses have a F/B ratio less than 5.0 -- the result
of a few thousand degrees of heating.

ALL is a very encompasing term.  Are you sure it wasn't mentioned 
principally regarding a total of two dozen tektite samples and three events for 
which 
the craters are known, weighted grossly in favor of Indochinites - rather than 
the whole wide world?  Sure,  5 quite possibly is the minimum in unimpacted 
sediments worldwide but I'd need more than an arbitrary statement to believe it 
after reading the other assertations...are we still refering to Dr. Koerbel's 
work?

Bedtime, I have a date with a comet in a couple of hours:), 'Night,Doug
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Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-05 Thread Sterling K. Webb

Gee, Doug,

   For once, I am not creating a crackers theory of my own.
I am merely explaining how a certain geochemical test procedure
works. Not being a geo- or a cosmo- chemist, I am taking the
word of Matthies, D. and Kroeberl, C., Fluorine and Boron
Geochemistry of Tektites, Impact Glasses, and Target Rocks,
Meteoritics, 26 (1991), 41-45, both of whom AM geochemists.
Also, see K. H. Wedepohl, Handbook of Geochemistry (1978).
Blah, blah.

   Think about it. You gotta rock. Mixture of complicated
crystals. Many elements. Huge heating event. Rock melts.
Rock vaporizes. Molecules dissociate. Now it's a plasma,
composed entirely of elements, too hot to form compounds.
The volatile elements in this plasma escape from the plasma
faster than the less volatile, which in turn escape faster
than the refractory (who are stubborn and hang around).
The plasma continues to heat. Volatiles go faster and faster.
At a high enough temperature, the mean free path of atoms
and their rate of escape is pretty much totally determined
by the thermal energy of the plasma and the mass of the atom
and the chemical characteristics of the substance matter not
at all. It's physics now, not chemistry. Element 5 (mass 11)
and element 9 (mass 19) are both moving like there was
a 38,000 degree plasma on their tail (and there is). They
now escape at a similar rate. Get the literature. Look at
the pretty graphs that show how it works. There's some
chemical reason why this happens about the time they're
at the same concentration, but I forget it. It's chemistry.
Me, when I look at things like equilibrium condensation
diagrams or the reverse of same, my eyes start to glaze
over... So I just take their word for it. But as a physical
phenomenon, it fits my intuition. Look at the other light
atoms. Not many of them hanging around either.

   Makes silly hand gestures, points to self. I no chemist.
Physicist. Like big things (universe, stars, planets, rocks
the size of countries). Like little things (quarks, leptons,
cute little bosons, petite atoms). Don't like things inbetween.
That's why God made chemists and botanists. Let them
sort it out. They like that sort of thing for some reason...
   In 1962, when the number of elementary particles
officially went over 200, Enrico Fermi, getting old and
cranky, yelled, Look at this f***g zoo! If I wanted this
mess, I'd have become a botanist! (He was right; how
can you have more elementary particles making up
elements than there are elements? Maybe it means that
making elements is hard.)
   Crusty old physicists. Show me String Theory when
you can put the whole thing on ONE PAGE. Otherwise,
go back and work on it some more.

   Deep breath. The F/B ratios for ALL terrestrial rocks
comes from Kroeberl and Company (all of this does). That's
for the bulk compositional analyses of crustal rocks everywhere
that geologists have made 100,000's of for the last century
or so. Boring... Boron's just not as common as fluorine. The
ratios run 10:1, 20:1, 30:1. Earth rock just isn't (in bulk)
boronic. That crusty stuff in Death Valley doesn't count...
If boron was common, would they have send Ronald Reagan
and those 20 mules into Death Valley? (Old TV referrence.)
   If you think this is all hooey, complain to Kroeberl and Co.
Also Wedepohl, who publishes thick books full of endless
tables of  bulk elemental compsitions. Lemme know what
happens.

   Seriously, I am miffed. I don't think this stuff is whacky
enough to be one of my whacky notions, and I'm insulted
that anyone should think so... Obviously, I'm not being
whacky enough.

   I'm quiting. It's late enough that I could go out
and wave at that comet myself.

Sterling K. Webb
--

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From: [EMAIL PROTECTED]
To: [EMAIL PROTECTED]; [EMAIL PROTECTED]; 
[EMAIL PROTECTED]; Meteorite-list@meteoritecentral.com

Sent: Sunday, March 05, 2006 2:34 AM
Subject: Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG



Sterling W. writes:

 I don't know the values for the Nubia Sandstone,
but the range of sandstones is fluorine 180 to 450
ppm and boron about 10 to 85 ppm. The figures
for LDG is fluorine 7 ppm and boron 7 ppm, so
you see how the ratios shift as the content drops.

   As the temperature rises (microsecond by microsecond),
the fluorine content drops much faster than the boron
content. At some very high temperature (variable
for each source rock), both fluorine and boron
levels become the same, but at a higher level than
in the final product.

After that point, both are driven out of the melt
plasma at the same rate, their petty chemical
differences totally overwhelmed by the energy
available. So, fluorine goes faster until that point
is reached, after then, they drop together. 

Hola Sterling,
Petty chemical differenceshm.overwhelmed at moment x when they
behave identically (this is the cartoon and then a miracle happens and we 
get

the desired solution

Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-05 Thread Larry Lebofsky
Sterling:

Sounds good to me (though I study big rocks that you can see with a 
telescope). It sounds like it is time for me to start reading up on tektites 
too!

As a novice, would you basically say that tektites come from volatilized 
material that has recondensed while an impactite derives from melted material 
that never got hot enough to vaporize.

Obviously, you would have ranges of materials (hotter vapor or hotter and more 
devolatilized liquid).

Larry

PS Did you see the comet? Never been clear enough and no access to a telescope 
where I am.

Quoting Sterling K. Webb [EMAIL PROTECTED]:

 Gee, Doug,
 
 For once, I am not creating a crackers theory of my own.
 I am merely explaining how a certain geochemical test procedure
 works. Not being a geo- or a cosmo- chemist, I am taking the
 word of Matthies, D. and Kroeberl, C., Fluorine and Boron
 Geochemistry of Tektites, Impact Glasses, and Target Rocks,
 Meteoritics, 26 (1991), 41-45, both of whom AM geochemists.
 Also, see K. H. Wedepohl, Handbook of Geochemistry (1978).
 Blah, blah.
 
 Think about it. You gotta rock. Mixture of complicated
 crystals. Many elements. Huge heating event. Rock melts.
 Rock vaporizes. Molecules dissociate. Now it's a plasma,
 composed entirely of elements, too hot to form compounds.
 The volatile elements in this plasma escape from the plasma
 faster than the less volatile, which in turn escape faster
 than the refractory (who are stubborn and hang around).
 The plasma continues to heat. Volatiles go faster and faster.
 At a high enough temperature, the mean free path of atoms
 and their rate of escape is pretty much totally determined
 by the thermal energy of the plasma and the mass of the atom
 and the chemical characteristics of the substance matter not
 at all. It's physics now, not chemistry. Element 5 (mass 11)
 and element 9 (mass 19) are both moving like there was
 a 38,000 degree plasma on their tail (and there is). They
 now escape at a similar rate. Get the literature. Look at
 the pretty graphs that show how it works. There's some
 chemical reason why this happens about the time they're
 at the same concentration, but I forget it. It's chemistry.
 Me, when I look at things like equilibrium condensation
 diagrams or the reverse of same, my eyes start to glaze
 over... So I just take their word for it. But as a physical
 phenomenon, it fits my intuition. Look at the other light
 atoms. Not many of them hanging around either.
 
 Makes silly hand gestures, points to self. I no chemist.
 Physicist. Like big things (universe, stars, planets, rocks
 the size of countries). Like little things (quarks, leptons,
 cute little bosons, petite atoms). Don't like things inbetween.
 That's why God made chemists and botanists. Let them
 sort it out. They like that sort of thing for some reason...
 In 1962, when the number of elementary particles
 officially went over 200, Enrico Fermi, getting old and
 cranky, yelled, Look at this f***g zoo! If I wanted this
 mess, I'd have become a botanist! (He was right; how
 can you have more elementary particles making up
 elements than there are elements? Maybe it means that
 making elements is hard.)
 Crusty old physicists. Show me String Theory when
 you can put the whole thing on ONE PAGE. Otherwise,
 go back and work on it some more.
 
 Deep breath. The F/B ratios for ALL terrestrial rocks
 comes from Kroeberl and Company (all of this does). That's
 for the bulk compositional analyses of crustal rocks everywhere
 that geologists have made 100,000's of for the last century
 or so. Boring... Boron's just not as common as fluorine. The
 ratios run 10:1, 20:1, 30:1. Earth rock just isn't (in bulk)
 boronic. That crusty stuff in Death Valley doesn't count...
 If boron was common, would they have send Ronald Reagan
 and those 20 mules into Death Valley? (Old TV referrence.)
 If you think this is all hooey, complain to Kroeberl and Co.
 Also Wedepohl, who publishes thick books full of endless
 tables of  bulk elemental compsitions. Lemme know what
 happens.
 
 Seriously, I am miffed. I don't think this stuff is whacky
 enough to be one of my whacky notions, and I'm insulted
 that anyone should think so... Obviously, I'm not being
 whacky enough.
 
 I'm quiting. It's late enough that I could go out
 and wave at that comet myself.
 
 Sterling K. Webb
 --
 
 
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-- 
Dr. Larry A. Lebofsky
Senior Research Scientist
Co-editor, Meteorite 

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Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-05 Thread Sterling K. Webb
 the impact site, goes right out the window.
The high speed re-entry of an immense swarm
of glassy rubble (and when I say immense, I mean
many billions of pieces) could produce a rain of
glass vapor cooling to molten microspheres in
the last moment before landing, and then another
swarm, and another. Would that necessarily
happen adjacent to the crater? No.
   There are ocean finds of layered tektites off
the Caribbean coast of South America. That's a
long way from the Chessy Crater. Of course,
they could also be found closer to the crater,
like in Georgia (they are), but they could be
anywhere in the strewn field. That's the point.
   This just takes an already headache level,
very complicated mystery and boosts it way
up the Migraine Scale to what-is-going-on-here?
It produces the paradoxical result that,
while ordinary tektites may be superheated
droplets of melt that didn't quite vaporize, the
Muong Nongs may be the product of droplet
condensation from a vapor, a conclusion
that is pretty much completely backwards
from the way most people conceptualize
the formation of tektites. There's that
headache factor again... Why do the layers
tend to alternate colors? Shut up; I have
a headache...
   As for Darryl's analysis of the micro-voids
in Muong Nongs, I don't know if he ever
published or even communicated it. We were
talking about it the week he died. Somebody
want to section a Muong Nong and look?
By the way, there are layered tektites from
three of the four major strewn fields, all but
the Ivory Coast. (But, then, ivorites are very
rare, with few examples compared to other
falls.) So, it's probably a universal outcome
of the Tektite Event, whatever that is.

   While I always worried about the asteroid
hit, or the stray comet hit, the usual cosmic
catastrophe, a straightforward impact event,
I was so fascinated by tektites that I never
thought to worry that much about the event.
But after envisioning clouds of rock vapor
and repeated fiery rains of molten droplets
over hundreds of miles, I wonder if we ought
to worry more than we do. Or at least,
figure out what they are...


Sterling K. Webb
--

- Original Message - 
From: Norm Lehrman [EMAIL PROTECTED]

To: Larry Lebofsky [EMAIL PROTECTED]; Sterling K. Webb
[EMAIL PROTECTED]
Cc: [EMAIL PROTECTED]; [EMAIL PROTECTED]; [EMAIL PROTECTED];
Meteorite-list@meteoritecentral.com
Sent: Sunday, March 05, 2006 9:13 AM
Subject: Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG



All,

Thanks for the fabulous discussion.  I had to take
time out from the discourse to wash, size-sort, cull,
and count 10,000 tektites for an order I'm supposed to
ship tomorrow, and all of this gave me a lot to mull
over.  And it did a lot to reinvigorate the wonderment
of the puzzle that first drew me to tektites.

For any of you on the list that may be new to the
subject, this discussion serves as an appetizer for
the much larger array of puzzles posed by tektites.

On the more immediate topics;  Doug, I very much like
your thought of an aerial thermal event like a
mega-Tunguska for Muong Nongs and maybe Edieowie also.
And Sterling, I to find the F/B story intuitively
comfortable and rational.  Larry, your comment
regarding something like a plasma condensate for true
tektites as opposed to simple splash glass impactites
feels good.  Pieces are beginning to fall into place
in new combinations for me.

More after I get the counting finished---

Norm
http://tektitesource.com

--- Larry Lebofsky [EMAIL PROTECTED] wrote:


Sterling:

Sounds good to me (though I study big rocks that you
can see with a
telescope). It sounds like it is time for me to
start reading up on tektites
too!

As a novice, would you basically say that tektites
come from volatilized
material that has recondensed while an impactite
derives from melted material
that never got hot enough to vaporize.

Obviously, you would have ranges of materials
(hotter vapor or hotter and more
devolatilized liquid).

Larry

PS Did you see the comet? Never been clear enough
and no access to a telescope
where I am.


--
Dr. Larry A. Lebofsky
Senior Research Scientist
Co-editor, Meteorite








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Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-05 Thread Kevin Forbes
 like oceanic microtektites do. A rock (or big
tektite) is a great piece of packaging to preserve
the original composition within. A concretation
of 50 micrometer particles is not.
   They fell (repeatedly) as tiny particles on
dirt, water, plant life, big tropical bugs, perhaps
the occasional hapless hominid, incorporating a
lot of junk. Then, the tiny spheres of the more
porous tektite started soaking up gases, water
vapor, losing silica content, and so forth, a kind
of weathering their more solid cousins are immune
to. Oceanic microtetites decay this way and
are believed to decay to clays eventually.
   Muong Nongs are layered, sub-layered, and
sub-sub-layered, the result of many rains of fire
over some short time scale. Fiery rain, fiery rain,
fiery rain, and after that, fiery rain. So, again the
simple impact scenario -- boom, melt, plop!
-- fails.  There's only one impact, hence there
would be only one plop!
   In fact, with this composition, the one thing
everybody seems certain of, that they are found
near the impact site, goes right out the window.
The high speed re-entry of an immense swarm
of glassy rubble (and when I say immense, I mean
many billions of pieces) could produce a rain of
glass vapor cooling to molten microspheres in
the last moment before landing, and then another
swarm, and another. Would that necessarily
happen adjacent to the crater? No.
   There are ocean finds of layered tektites off
the Caribbean coast of South America. That's a
long way from the Chessy Crater. Of course,
they could also be found closer to the crater,
like in Georgia (they are), but they could be
anywhere in the strewn field. That's the point.
   This just takes an already headache level,
very complicated mystery and boosts it way
up the Migraine Scale to what-is-going-on-here?
It produces the paradoxical result that,
while ordinary tektites may be superheated
droplets of melt that didn't quite vaporize, the
Muong Nongs may be the product of droplet
condensation from a vapor, a conclusion
that is pretty much completely backwards
from the way most people conceptualize
the formation of tektites. There's that
headache factor again... Why do the layers
tend to alternate colors? Shut up; I have
a headache...
   As for Darryl's analysis of the micro-voids
in Muong Nongs, I don't know if he ever
published or even communicated it. We were
talking about it the week he died. Somebody
want to section a Muong Nong and look?
By the way, there are layered tektites from
three of the four major strewn fields, all but
the Ivory Coast. (But, then, ivorites are very
rare, with few examples compared to other
falls.) So, it's probably a universal outcome
of the Tektite Event, whatever that is.

   While I always worried about the asteroid
hit, or the stray comet hit, the usual cosmic
catastrophe, a straightforward impact event,
I was so fascinated by tektites that I never
thought to worry that much about the event.
But after envisioning clouds of rock vapor
and repeated fiery rains of molten droplets
over hundreds of miles, I wonder if we ought
to worry more than we do. Or at least,
figure out what they are...


Sterling K. Webb
--

- Original Message - From: Norm Lehrman [EMAIL PROTECTED]
To: Larry Lebofsky [EMAIL PROTECTED]; Sterling K. Webb
[EMAIL PROTECTED]
Cc: [EMAIL PROTECTED]; [EMAIL PROTECTED]; [EMAIL PROTECTED];
Meteorite-list@meteoritecentral.com
Sent: Sunday, March 05, 2006 9:13 AM
Subject: Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG



All,

Thanks for the fabulous discussion.  I had to take
time out from the discourse to wash, size-sort, cull,
and count 10,000 tektites for an order I'm supposed to
ship tomorrow, and all of this gave me a lot to mull
over.  And it did a lot to reinvigorate the wonderment
of the puzzle that first drew me to tektites.

For any of you on the list that may be new to the
subject, this discussion serves as an appetizer for
the much larger array of puzzles posed by tektites.

On the more immediate topics;  Doug, I very much like
your thought of an aerial thermal event like a
mega-Tunguska for Muong Nongs and maybe Edieowie also.
And Sterling, I to find the F/B story intuitively
comfortable and rational.  Larry, your comment
regarding something like a plasma condensate for true
tektites as opposed to simple splash glass impactites
feels good.  Pieces are beginning to fall into place
in new combinations for me.

More after I get the counting finished---

Norm
http://tektitesource.com

--- Larry Lebofsky [EMAIL PROTECTED] wrote:


Sterling:

Sounds good to me (though I study big rocks that you
can see with a
telescope). It sounds like it is time for me to
start reading up on tektites
too!

As a novice, would you basically say that tektites
come from volatilized
material that has recondensed while an impactite
derives from melted material
that never got hot enough to vaporize.

Obviously, you would have ranges of materials

Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-04 Thread Sterling K. Webb
-
- Original Message - 
From: [EMAIL PROTECTED]
To: [EMAIL PROTECTED]; [EMAIL PROTECTED]; 
Meteorite-list@meteoritecentral.com

Sent: Friday, March 03, 2006 7:15 PM
Subject: Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG


Hola Norm, so it seems we actually agree on most of the points, including 
the
most important one: the subjectivity of the definition.  You are just 
wanting

to be more liberal...and me more stoodgy...I wasn't dodging the layered
tektite issue when I said not to bring it up (which you unfortunately 
did:)).
Clearly layered tektites are closer to impact glasses in the continuum and 
I was
just trying to cleanly conceptualize.  The definition of 'tektite' is a 
human
classification which like most, depends on a clear understanding of a 
concept,
not a recipe.  The Muong Nong glasses (vs. tektites) as many experts also 
call

them deserve a category by themselves so if you want to point to experts
calling them tektites as support for calling the LDG's also tektites, all 
I can
say is we are pushing the concept even further.  You do mention the 
meteoritic
content of Indochinites (=Australasian tektites).  Yes a small component 
of
iron has been detected, but this is very rare, and no where near the 
content in

LDG which can approach a 0.5%.

You didn't mention that the partial pressure of the air in the bubbles of 
the

Indochinites corresponds to the upper atmosphere, and that in LDG I am
assuming it corresponds to the surface.  This shouldn't be a surprise as 
the water

should not be linearly independent - thus they ought to track similarly.

Good point on the desert weathering, but is there a real strewn field 
defined
for LDG's, as we find with other conceptually true-to-form tektites 
(pun:))?

If any evidence could be found, your argument would be more solid, as a of
evidence isn't any proof of anything.  Try checking nobel gas ratios and I 
bet

the tektite concept will be even further away...

Where I must really agree with you and put all grammatical gymnastics and
opinions aside, is where you make the best point of the whole discussion, 
imho.
That maybe our definition of tektites whatever that concept may be is 
based on

faulty ideas.  With liberty taken, that maybe it will change as we learn
more.  Yes, I buy that, I believe that is a distinct possibility.  Things 
were so

much simpler when we all agreed they were blasted from the Moon and the
aerodynamic shapes and low water content actually meant something more to 
the
experts of that time.  Gor the time being, I be conservative on the 
definitions for
the distinctions mentioned.  Show me one aerodynamically shaped LDG 
besides
one sculpted by a Neanderthal, and I'll recommend you for a Harvey award 
which

would be quite fitting:), and definitely a nobel prize in the meteoritical
community...for the moment we think there is a crater now, well, we 
already called

them impact glasses, and now we have all these years of human transport
mucking it up for these highly prized special glasses.

Perhaps little Norm and little Doug in the 100th century will follow in 
our
footsteps.  Norm will say, Doug, look at all the chondrites in the USA, 
and
there are none in the Sahara.  Looks like the major strewn field is into 
North
America and then a minor one into Europe.  And Doug will say, I don't 
know, they
weren't witnessed falls  Jokes aside, the concepts are pretty 
clear --- 
high energy, less meteoritic content, water content too low for earth's 
surface

under all available explanations, aerodynamic shapes, minimal nobel gas
concentration typical of higher atmosphere, upper atmosphere
pressures(=low)...where does LDG have a positive?  A crater in the same 
environment///I'll sit this

one out on the fence...but note it duly with curiosity and opportunity...

Saludos, Doug


Norm L. wrote:

Doug,

Good points all, but if you want to raise the
water/purity issue, you can't dodge the Muong Nong
issue.  (The best answer is that they shouldn't be
called tektites, BUT, they ARE so called by all
authorities).

With LDG, it can be reasonably argued that
flight-related morphology has been erased by
ventifaction.  In the area where this stuff is found,
it is literally reasonable that ALL of the material
has seen the wind and its entrained sand.  LDG is
pretty fine, clean glass, albeit with a higher water
content. (So, here again, people have dodged the issue
by calling them Muong Nongs---)

As for inclusion of impactor material in LDG, you've
got to remember that iron spherules are found in
Australasian tektites. Good chance that's impactor
condensate.

I truly have no argument with the water content
criterion.  That's probably the best definitional
parameter we have.  But it makes me a bit nervous to
turn the whole matter over to such a narrow
definition.  Are we positive, given all that we don't
know about tektites, that there can't be any wet ones?
 Should we now start calling Pyrex another variety

Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-04 Thread MexicoDoug
Sterling W. writes:

 Crustal rocks have 5 or 10 times
 more fluorine than boron. Tektites should have a ratio of 1.0,
 indicating that they were heated to temperatures high enough
 to drive off most of the fluorine and leave the two halogens
 at identical levels (however low the absolute amount), and indeed
 tektites have values that float around 1.0 (like 0.8 to 1.2).
 The tested LDG F/B ratio is 1.0.   

Norm, Sterling, Mark, Tracy, list,

I'm still on the fence about Libyan Desert Glass and how it fits into the 
puzzle and I wanted to thank Norm for the motivation to reconsider some of it 
based on the additional support that that LDG may have actually been tossed a 
significant (lateral?) distance to its resting point.  Norm, my thoughts on the 
difference in the mechanism of formation here are basically along the lines 
pursued by Wasson, that Muong Nongs (and probably LDG's) result from a 
different 
conceptual and physical event: that while they may be clearly or partially 
impacted and have received a portion of their formation from that, that 
importantaly also: a major source of the energy that led to their formation was 
being 
broiled by an overhead explosion perhaps of a manyfold-Tunguska type, or by the 
same clould of incredible enery flux that formed some of the true-to-form 
tektites.  This is why I am on the fence - because I feel more comfortable with 
that scenario to fall back upon.

Just want to hold on to a concept, of what tektite means to me as Norm 
originally asked.  While Norm argued to liberalize the definition to include 
LDG's, 
I'm playing the conservative interpretation here like Sterling is also joining 
to do.  I don't disagree, just ask for one positive indication in my 
preferred set of rules.  Norm might just be right if we play by his rules and 
accept 
that LDG's were chucked a good distance and thus call them tektites based on 
that criterion.  At minimumn LDGs are more important now as we glean more 
information from them and maybe an additional piece of the endless puzzle.

I am really not quite sure why Sterling mentions the F and B assays would  
tend to identical levels in tektites, and I while it may be my turn to split 
hairs, I think this is an interesting research point, but presented inside out. 
 Yes, Fluorine is generally more volatile and probably preferentially driven 
off, though we should verify this is true for the source matrix solubility 
before being 100% convinced.  The major problem I have here is that there is 
nothing magic about having them with the same concentration level as you imply, 
I 
think this is just a coincidence on what has been looked at so far, possibly 
related to the temperatures and residence times (determined by physical 
constraints) in the liquid state of formation too, yes, of course, but that is 
as far 
as I would go.  That is why I think it is too great a leap of faith to 
discuss why they would be perfect tektites based on these measurements.

Putting this [F]:[B] further under the microscope, it is also of academic 
interest to compare this to the source rock - but I would never flip that 
around 
to discuss why [F] and [B] should be identical or at a particular ratio 
without knowing the initial values in the source rock, since I cannot fathom 
any 
mechanism that would insist that tektites should have these levels identical, 
and the range you quote and attribute some special meaning to, anyway for 
tektites floating goes below 1.0 anyway, and as a matter of fact the tektites 
could easily have much lower values for this ratio than you quote, has Dr. 
Koerbel and colleagues ever fired up their special Boron sensitive electrode to 
check these numbers for moldavites lately?

Basically, Sterling is making a big assumption by saying that the source 
rocks of the sandstone are in the range of 5 - 10 for a [F]:[B] ratio, and I 
think 
frankly that is a poke in the dark or leap of faith at minimum.  I would much 
rather see someone actually go measure the [F] and [B] numbers for relatively 
unaltered sandstone near the excitingly discussed crater just to check that 
the ratios didn't happen to start out at values much closer to equal ... there 
is significant variation on the earth.

The bottom line in my view is that the interpretation of the Fluorine and 
Boron concentration numbers and ratios is meaningful for an apples to apples 
comparison when the situation of the crater is not known if and only if we had 
tektites (or some other glass type) formed from the LDG event then we could 
measure (at least Dr. Koerbel and his colleagues could) and compare the 
tendencies 
with the series (e.g.,LDG, hypothetical button, hypothetical splashform,etc.) 
which I consider the more appropriate interpretation of this.  Not take it out 
of context and generalize for the whole planet and say they should be 
perfect tektites.  So there are not enough numbers put on this pig, in my 
opinion, 
and wish my disagreement on that split 

Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-04 Thread Sterling K. Webb
 all.

   I wonder what they thought when the sky dropped
millions of pieces of hot glass on them, to fall with a
sizzle into the still water below? First, everything floods
and we have to move up into these stinking FEMA
treehouses, and now there's hot glass falling from the
sky...  The world is going to hell.

   Doug, did I answer your question?


Sterling K. Webb
-
- Original Message - 
From: [EMAIL PROTECTED]
To: [EMAIL PROTECTED]; [EMAIL PROTECTED]; 
[EMAIL PROTECTED]; Meteorite-list@meteoritecentral.com

Sent: Saturday, March 04, 2006 4:05 PM
Subject: Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG



Sterling W. writes:

 Crustal rocks have 5 or 10 times
more fluorine than boron. Tektites should have a ratio of 1.0,
indicating that they were heated to temperatures high enough
to drive off most of the fluorine and leave the two halogens
at identical levels (however low the absolute amount), and indeed
tektites have values that float around 1.0 (like 0.8 to 1.2).
The tested LDG F/B ratio is 1.0.   

Norm, Sterling, Mark, Tracy, list,

I'm still on the fence about Libyan Desert Glass and how it fits into the
puzzle and I wanted to thank Norm for the motivation to reconsider some of 
it
based on the additional support that that LDG may have actually been 
tossed a
significant (lateral?) distance to its resting point.  Norm, my thoughts 
on the
difference in the mechanism of formation here are basically along the 
lines
pursued by Wasson, that Muong Nongs (and probably LDG's) result from a 
different

conceptual and physical event: that while they may be clearly or partially
impacted and have received a portion of their formation from that, that
importantaly also: a major source of the energy that led to their 
formation was being
broiled by an overhead explosion perhaps of a manyfold-Tunguska type, or 
by the
same clould of incredible enery flux that formed some of the 
true-to-form
tektites.  This is why I am on the fence - because I feel more comfortable 
with

that scenario to fall back upon.

Just want to hold on to a concept, of what tektite means to me as Norm
originally asked.  While Norm argued to liberalize the definition to 
include LDG's,
I'm playing the conservative interpretation here like Sterling is also 
joining

to do.  I don't disagree, just ask for one positive indication in my
preferred set of rules.  Norm might just be right if we play by his rules 
and accept
that LDG's were chucked a good distance and thus call them tektites based 
on

that criterion.  At minimumn LDGs are more important now as we glean more
information from them and maybe an additional piece of the endless puzzle.

I am really not quite sure why Sterling mentions the F and B assays would
tend to identical levels in tektites, and I while it may be my turn to 
split
hairs, I think this is an interesting research point, but presented inside 
out.
Yes, Fluorine is generally more volatile and probably preferentially 
driven

off, though we should verify this is true for the source matrix solubility
before being 100% convinced.  The major problem I have here is that there 
is
nothing magic about having them with the same concentration level as you 
imply, I
think this is just a coincidence on what has been looked at so far, 
possibly

related to the temperatures and residence times (determined by physical
constraints) in the liquid state of formation too, yes, of course, but 
that is as far

as I would go.  That is why I think it is too great a leap of faith to
discuss why they would be perfect tektites based on these measurements.

Putting this [F]:[B] further under the microscope, it is also of academic
interest to compare this to the source rock - but I would never flip that 
around

to discuss why [F] and [B] should be identical or at a particular ratio
without knowing the initial values in the source rock, since I cannot 
fathom any
mechanism that would insist that tektites should have these levels 
identical,

and the range you quote and attribute some special meaning to, anyway for
tektites floating goes below 1.0 anyway, and as a matter of fact the 
tektites

could easily have much lower values for this ratio than you quote, has Dr.
Koerbel and colleagues ever fired up their special Boron sensitive 
electrode to

check these numbers for moldavites lately?

Basically, Sterling is making a big assumption by saying that the source
rocks of the sandstone are in the range of 5 - 10 for a [F]:[B] ratio, and 
I think
frankly that is a poke in the dark or leap of faith at minimum.  I would 
much
rather see someone actually go measure the [F] and [B] numbers for 
relatively
unaltered sandstone near the excitingly discussed crater just to check 
that
the ratios didn't happen to start out at values much closer to equal ... 
there

is significant variation on the earth.

The bottom line in my view is that the interpretation of the Fluorine and
Boron

Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-03 Thread Norm Lehrman
Bernd  list,

This is indeed exciting, and may finally justify LDG
being recognized as a true tektite rather than a
simple impactite.

Although the article doesn't give us much for location
beyond at the northern tip of the Gilf Kebir region,
that's close enough, as the LDG strewn field is
immediately north of the Gilf Kebir.

The 28.5 ma date for LDG should be a good number
(fission track).  The 100 million year sandstone
mentioned as the crater target rock is perfect.  For
years it has been argued that the Nubia group
sandstones are the geochemically perfect precursor for
LDG.  Interestingly, this raised a problem for
researchers looking for a local LDG source crater as
there are good geological arguments that the Nubia
sandstones were covered by younger formations in the
LDG strewn field at 28.5 ma and would not have been
available as target rocks.

With the revelation that this newly recognized crater
did indeed impact the sandstones, we're almost there. 
Now, all we have to do is eject the LDG a hundred km
or so northwards and the picture works fine. (The long
axis of the strewn field is roughly N-S).

Where is the dividing line between impactite and
tektite?  I'd like to hear what others may understand,
but my impression is that it fundamentally hinges on
distance the glassy material is ejected from the
crater.  Material found only in and immediately around
the source crater is impactite.  Stuff blasted tens to
hundreds of km or more crosses the definitional
boundary into tektites.

If this is the criterion, LDG was already home free in
my book insofar as the known strewn field has a long
axis of at least 150 km, so even if there was a
now-erosionally removed crater at one end of the
strewn field proper, some of the glass would've
already required over 100 km ejection distance.  

Now, I'm guessing we may be talking a couple hundred
km, maybe more.  Is that sufficiently far to
legitimize LDG as a true tektite?  (From
Ries-Norlingen to the Czech moldavite fields is about
300 km).

Cheers,
Norm
http://tektitesource.com

--- [EMAIL PROTECTED] wrote:

 Hi Ron and List,
 
 Like so many others, I was eagerly flying over the
 lines in search of
 a hint to LDG (Libyan Desert Glass),and, there it is
 (of course ;-):
 
 since its shape points to an origin of
 extraterrestrial impact, it will likely prove to
  be  the event responsible for the extensive field
 of 'Desert Glass'-yellow-green silica
  glass fragments found on the desert surface between
 the giant dunes of the Great Sand Sea
  in southwestern Egypt.
 
 But:
 
 may have been formed by a meteorite impact tens of
 millions of years ago.
 
 How many *tens* of millions of years ago ???
 
 If current age estimates are correct, LDG has an age
 of ~28 Ma.
 
 Any thoughts out there, ... Norm?
 
 Cheers,
 
 Bernd
 
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Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-03 Thread MexicoDoug
Norm L. writes:

 Where is the dividing line between impactite and
 tektite?  I'd like to hear what others may understand,
 but my impression is that it fundamentally hinges on
 distance the glassy material is ejected from the
 crater.  Material found only in and immediately around
 the source crater is impactite.  Stuff blasted tens to
 hundreds of km or more crosses the definitional
 boundary into tektites.
 
 If this is the criterion, LDG was already home free  

Hola Norm, yet again here's another one of those awkward definitions that 
when overyly analyzed starts falling apart.  I think the distance criterion is 
not THE criterion, but rather a tektite differs from an impact glass in that 
the 
tektite has actually been exposed to general conditions of enough kinetic and 
thermal energy to create a greater melt uniformity where the original 
impactor has transmitted that energy cleanly, and in such a great quantity 
that the 
energy is also enough to propel tektites into the upper atmosphere and have 
them re-enter ablating like meteorites.

These are a bunch of hand-waving concepts, but as we know, it seems the one 
factor that really distinguishes tektites is the low water content.  LDG's 
have at least 5 times the typical water content of the cleaner tektites, and 
they contain inclusions including those of the impactor, and aerodynamic shapes 
are not really known I believe.

In fact the water content of LDG's at the low end of 5 times the amount of 
the cleaner tektites actually goes practically as high as obsidian.  They don't 
usually look very aerodynamic and they have meteorites inside them.  They 
deserve some distinction, they are dirty glass.  Now all of this about water 
content might be just an academic distinction, except for one exception.  One 
of 
the greatest mysteries of tektites is derived from the mystery of exactly what 
physical laws were twisted to get that low water content and this more than 
anything else is the criterion as much as the mystery.  Plus they are generally 
clean (OK, they have smalled fused cuartz. etc., but there there tends to be a 
bimodal distribution between clean tektites and impact glasses as far as 
inclusions = so far you have clean ones and dirty ones)  Please don't bring up 
layered tektites I don't want the definition system to fail even more...

But practically speaking, you would have to be right that there is a 
continuum, just like in the definition of a planet, etc., the world tends 
towards 
complexity just when you get it all figured out...and soon we will come to know 
of 
the impektite that bridges tektites, water and all, with LDGs and other 
impact glasses.  Better yet how about just saying they are all impact glasses - 
which they are no matter who starts talking about flying - and that tektites 
just 
had a higher energy/diffusion/flux melt event which is witnessed in the 
record by water content...If cats could only talk they could tell us how long 
we 
have erred on visible light as they see into the near UV, don't they?  What's 
the use of going at it with a cat over the definition of visible light?:)

My 2 centavos...Doug
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Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-03 Thread Norm Lehrman
Doug,

Good points all, but if you want to raise the
water/purity issue, you can't dodge the Muong Nong
issue.  (The best answer is that they shouldn't be
called tektites, BUT, they ARE so called by all
authorities).  

With LDG, it can be reasonably argued that
flight-related morphology has been erased by
ventifaction.  In the area where this stuff is found,
it is literally reasonable that ALL of the material
has seen the wind and its entrained sand.  LDG is
pretty fine, clean glass, albeit with a higher water
content. (So, here again, people have dodged the issue
by calling them Muong Nongs---)

As for inclusion of impactor material in LDG, you've
got to remember that iron spherules are found in
Australasian tektites. Good chance that's impactor
condensate.

I truly have no argument with the water content
criterion.  That's probably the best definitional
parameter we have.  But it makes me a bit nervous to
turn the whole matter over to such a narrow
definition.  Are we positive, given all that we don't
know about tektites, that there can't be any wet ones?
 Should we now start calling Pyrex another variety of
tektite?  Clearly, we are including some
process-related factors (even if just inferred) in our
definition.

It is very much like the planet issue.  I keep
thinking that there have been a lot of grade-school
kids that got marked down on tests for answering the
question: How many planets are in our solar system?
wrong according to the erroneous wisdom of a given
time.  How many tektite-producing impacts have there
been?  I get weary of qualifying my answers with,
Well, depending on whether or not you count LDG

Cheers,
Norm
http://tektitesource.com


--- [EMAIL PROTECTED] wrote:

 Norm L. writes:
 
  Where is the dividing line between impactite and
  tektite?  I'd like to hear what others may
 understand,
  but my impression is that it fundamentally hinges
 on
  distance the glassy material is ejected from the
  crater.  Material found only in and immediately
 around
  the source crater is impactite.  Stuff blasted tens
 to
  hundreds of km or more crosses the definitional
  boundary into tektites.
  
  If this is the criterion, LDG was already home free
  
 
 Hola Norm, yet again here's another one of those
 awkward definitions that 
 when overyly analyzed starts falling apart.  I think
 the distance criterion is 
 not THE criterion, but rather a tektite differs from
 an impact glass in that the 
 tektite has actually been exposed to general
 conditions of enough kinetic and 
 thermal energy to create a greater melt uniformity
 where the original 
 impactor has transmitted that energy cleanly, and
 in such a great quantity that the 
 energy is also enough to propel tektites into the
 upper atmosphere and have 
 them re-enter ablating like meteorites.
 
 These are a bunch of hand-waving concepts, but as we
 know, it seems the one 
 factor that really distinguishes tektites is the
 low water content.  LDG's 
 have at least 5 times the typical water content of
 the cleaner tektites, and 
 they contain inclusions including those of the
 impactor, and aerodynamic shapes 
 are not really known I believe.
 
 In fact the water content of LDG's at the low end of
 5 times the amount of 
 the cleaner tektites actually goes practically as
 high as obsidian.  They don't 
 usually look very aerodynamic and they have
 meteorites inside them.  They 
 deserve some distinction, they are dirty glass.  Now
 all of this about water 
 content might be just an academic distinction,
 except for one exception.  One of 
 the greatest mysteries of tektites is derived from
 the mystery of exactly what 
 physical laws were twisted to get that low water
 content and this more than 
 anything else is the criterion as much as the
 mystery.  Plus they are generally 
 clean (OK, they have smalled fused cuartz. etc., but
 there there tends to be a 
 bimodal distribution between clean tektites and
 impact glasses as far as 
 inclusions = so far you have clean ones and dirty
 ones)  Please don't bring up 
 layered tektites I don't want the definition system
 to fail even more...
 
 But practically speaking, you would have to be right
 that there is a 
 continuum, just like in the definition of a planet,
 etc., the world tends towards 
 complexity just when you get it all figured
 out...and soon we will come to know of 
 the impektite that bridges tektites, water and all,
 with LDGs and other 
 impact glasses.  Better yet how about just saying
 they are all impact glasses - 
 which they are no matter who starts talking about
 flying - and that tektites just 
 had a higher energy/diffusion/flux melt event which
 is witnessed in the 
 record by water content...If cats could only talk
 they could tell us how long we 
 have erred on visible light as they see into the
 near UV, don't they?  What's 
 the use of going at it with a cat over the
 definition of visible light?:)
 
 My 2 centavos...Doug
 


Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-03 Thread MexicoDoug
Hola Norm, so it seems we actually agree on most of the points, including the 
most important one: the subjectivity of the definition.  You are just wanting 
to be more liberal...and me more stoodgy...I wasn't dodging the layered 
tektite issue when I said not to bring it up (which you unfortunately did:)).  
Clearly layered tektites are closer to impact glasses in the continuum and I 
was 
just trying to cleanly conceptualize.  The definition of 'tektite' is a human 
classification which like most, depends on a clear understanding of a concept, 
not a recipe.  The Muong Nong glasses (vs. tektites) as many experts also call 
them deserve a category by themselves so if you want to point to experts 
calling them tektites as support for calling the LDG's also tektites, all I can 
say is we are pushing the concept even further.  You do mention the meteoritic 
content of Indochinites (=Australasian tektites).  Yes a small component of 
iron has been detected, but this is very rare, and no where near the content in 
LDG which can approach a 0.5%.

You didn't mention that the partial pressure of the air in the bubbles of the 
Indochinites corresponds to the upper atmosphere, and that in LDG I am 
assuming it corresponds to the surface.  This shouldn't be a surprise as the 
water 
should not be linearly independent - thus they ought to track similarly.  

Good point on the desert weathering, but is there a real strewn field defined 
for LDG's, as we find with other conceptually true-to-form tektites (pun:))?  
If any evidence could be found, your argument would be more solid, as a of 
evidence isn't any proof of anything.  Try checking nobel gas ratios and I bet 
the tektite concept will be even further away...

Where I must really agree with you and put all grammatical gymnastics and 
opinions aside, is where you make the best point of the whole discussion, imho. 
 
That maybe our definition of tektites whatever that concept may be is based on 
faulty ideas.  With liberty taken, that maybe it will change as we learn 
more.  Yes, I buy that, I believe that is a distinct possibility.  Things were 
so 
much simpler when we all agreed they were blasted from the Moon and the 
aerodynamic shapes and low water content actually meant something more to the 
experts of that time.  Gor the time being, I be conservative on the definitions 
for 
the distinctions mentioned.  Show me one aerodynamically shaped LDG besides 
one sculpted by a Neanderthal, and I'll recommend you for a Harvey award which 
would be quite fitting:), and definitely a nobel prize in the meteoritical 
community...for the moment we think there is a crater now, well, we already 
called 
them impact glasses, and now we have all these years of human transport 
mucking it up for these highly prized special glasses.

Perhaps little Norm and little Doug in the 100th century will follow in our 
footsteps.  Norm will say, Doug, look at all the chondrites in the USA, and 
there are none in the Sahara.  Looks like the major strewn field is into North 
America and then a minor one into Europe.  And Doug will say, I don't know, 
they 
weren't witnessed falls  Jokes aside, the concepts are pretty clear --- 
high energy, less meteoritic content, water content too low for earth's surface 
under all available explanations, aerodynamic shapes, minimal nobel gas 
concentration typical of higher atmosphere, upper atmosphere 
pressures(=low)...where does LDG have a positive?  A crater in the same 
environment///I'll sit this 
one out on the fence...but note it duly with curiosity and opportunity...

Saludos, Doug


Norm L. wrote:
 
 Doug,
 
 Good points all, but if you want to raise the
 water/purity issue, you can't dodge the Muong Nong
 issue.  (The best answer is that they shouldn't be
 called tektites, BUT, they ARE so called by all
 authorities).  
 
 With LDG, it can be reasonably argued that
 flight-related morphology has been erased by
 ventifaction.  In the area where this stuff is found,
 it is literally reasonable that ALL of the material
 has seen the wind and its entrained sand.  LDG is
 pretty fine, clean glass, albeit with a higher water
 content. (So, here again, people have dodged the issue
 by calling them Muong Nongs---)
 
 As for inclusion of impactor material in LDG, you've
 got to remember that iron spherules are found in
 Australasian tektites. Good chance that's impactor
 condensate.
 
 I truly have no argument with the water content
 criterion.  That's probably the best definitional
 parameter we have.  But it makes me a bit nervous to
 turn the whole matter over to such a narrow
 definition.  Are we positive, given all that we don't
 know about tektites, that there can't be any wet ones?
  Should we now start calling Pyrex another variety of
 tektite?  Clearly, we are including some
 process-related factors (even if just inferred) in our
 definition.
 
 It is very much like the planet issue.  I keep
 thinking that there have been a lot of 

Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-03 Thread Norm Lehrman
Doug,

I do enjoy your contributions.  Always stimulating.

I have no fundamental disagreements.  Just a few
hair-splitting points.

Re: the partial pressures in Australasian bubbles.  It
has been argued that our numbers are bogus.  As
atmospheric water is absorbed into the hydrating
tektite selvage lining a bubble,  internal pressures
can be considerably reduced, giving the false
appearance of high altitudes.  I have never seen
anything about partial pressures in LDG glass.  I'm
not sure anything has ever been found sufficiently
large to measure.  Lacking such data,  this argument
is conceptual, not real.  However it is a great
research suggestion.  With modern micro-techniques LDG
bubbles should be revisited!

As for a real strewnfield defined for LDGs as we find
with other conceptually true to form tektites, yes,
the finding area is quite sharply delimited at about
150 km X 50 km.  If anything, the LDG area is
atypically WELL defined relative to other tektites (I
don't know much about Ivory Coast distribution.  It
may be comparable or smaller).

I must admit, I have never seen anything even remotely
resembling an erosionally-modified aerodynamically-
shaped Libyan Desert Glass form.  If you started with
the typical morphologies of Australasians and
sand-blasted them within an inch of their existence,
we would still recognize some traces of original
morphology.  I must decline any hope of the Harvey
Award on this matter.  You are totally correct.  LDG
shows absolutely no hint of aerodynamic ablation
modification.

Deep enough,
Norm
http://tektitesource.com  (a great place to view a
huge selection of prime Libyan Desert Glass!)



--- [EMAIL PROTECTED] wrote:

 Hola Norm, so it seems we actually agree on most of
 the points, including the 
 most important one: the subjectivity of the
 definition.  You are just wanting 
 to be more liberal...and me more stoodgy...I wasn't
 dodging the layered 
 tektite issue when I said not to bring it up (which
 you unfortunately did:)).  
 Clearly layered tektites are closer to impact
 glasses in the continuum and I was 
 just trying to cleanly conceptualize.  The
 definition of 'tektite' is a human 
 classification which like most, depends on a clear
 understanding of a concept, 
 not a recipe.  The Muong Nong glasses (vs. tektites)
 as many experts also call 
 them deserve a category by themselves so if you want
 to point to experts 
 calling them tektites as support for calling the
 LDG's also tektites, all I can 
 say is we are pushing the concept even further.  You
 do mention the meteoritic 
 content of Indochinites (=Australasian tektites). 
 Yes a small component of 
 iron has been detected, but this is very rare, and
 no where near the content in 
 LDG which can approach a 0.5%.
 
 You didn't mention that the partial pressure of the
 air in the bubbles of the 
 Indochinites corresponds to the upper atmosphere,
 and that in LDG I am 
 assuming it corresponds to the surface.  This
 shouldn't be a surprise as the water 
 should not be linearly independent - thus they ought
 to track similarly.  
 
 Good point on the desert weathering, but is there a
 real strewn field defined 
 for LDG's, as we find with other conceptually
 true-to-form tektites (pun:))?  
 If any evidence could be found, your argument would
 be more solid, as a of 
 evidence isn't any proof of anything.  Try checking
 nobel gas ratios and I bet 
 the tektite concept will be even further away...
 
 Where I must really agree with you and put all
 grammatical gymnastics and 
 opinions aside, is where you make the best point of
 the whole discussion, imho.  
 That maybe our definition of tektites whatever that
 concept may be is based on 
 faulty ideas.  With liberty taken, that maybe it
 will change as we learn 
 more.  Yes, I buy that, I believe that is a distinct
 possibility.  Things were so 
 much simpler when we all agreed they were blasted
 from the Moon and the 
 aerodynamic shapes and low water content actually
 meant something more to the 
 experts of that time.  Gor the time being, I be
 conservative on the definitions for 
 the distinctions mentioned.  Show me one
 aerodynamically shaped LDG besides 
 one sculpted by a Neanderthal, and I'll recommend
 you for a Harvey award which 
 would be quite fitting:), and definitely a nobel
 prize in the meteoritical 
 community...for the moment we think there is a
 crater now, well, we already called 
 them impact glasses, and now we have all these years
 of human transport 
 mucking it up for these highly prized special
 glasses.
 
 Perhaps little Norm and little Doug in the 100th
 century will follow in our 
 footsteps.  Norm will say, Doug, look at all the
 chondrites in the USA, and 
 there are none in the Sahara.  Looks like the major
 strewn field is into North 
 America and then a minor one into Europe.  And Doug
 will say, I don't know, they 
 weren't witnessed falls  Jokes aside, the
 concepts are pretty clear --- 
 high energy, less 

Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-03 Thread Pete Pete

Maybe they're just kryptonite!  Occam's razor. Think about it. ;]

http://theages.superman.ws/Encyclopaedia/kryptonite.php


While I only have one small sample in my collection, reading the bantering 
about tektites on this List is always an interesting education for a rookie!


Cheers,
Pete




From: Norm Lehrman [EMAIL PROTECTED]
To: [EMAIL PROTECTED], 
[EMAIL PROTECTED],Meteorite-list@meteoritecentral.com

Subject: Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG
Date: Fri, 3 Mar 2006 18:23:29 -0800 (PST)

Doug,

I do enjoy your contributions.  Always stimulating.

I have no fundamental disagreements.  Just a few
hair-splitting points.

Re: the partial pressures in Australasian bubbles.  It
has been argued that our numbers are bogus.  As
atmospheric water is absorbed into the hydrating
tektite selvage lining a bubble,  internal pressures
can be considerably reduced, giving the false
appearance of high altitudes.  I have never seen
anything about partial pressures in LDG glass.  I'm
not sure anything has ever been found sufficiently
large to measure.  Lacking such data,  this argument
is conceptual, not real.  However it is a great
research suggestion.  With modern micro-techniques LDG
bubbles should be revisited!

As for a real strewnfield defined for LDGs as we find
with other conceptually true to form tektites, yes,
the finding area is quite sharply delimited at about
150 km X 50 km.  If anything, the LDG area is
atypically WELL defined relative to other tektites (I
don't know much about Ivory Coast distribution.  It
may be comparable or smaller).

I must admit, I have never seen anything even remotely
resembling an erosionally-modified aerodynamically-
shaped Libyan Desert Glass form.  If you started with
the typical morphologies of Australasians and
sand-blasted them within an inch of their existence,
we would still recognize some traces of original
morphology.  I must decline any hope of the Harvey
Award on this matter.  You are totally correct.  LDG
shows absolutely no hint of aerodynamic ablation
modification.

Deep enough,
Norm
http://tektitesource.com  (a great place to view a
huge selection of prime Libyan Desert Glass!)



--- [EMAIL PROTECTED] wrote:

 Hola Norm, so it seems we actually agree on most of
 the points, including the
 most important one: the subjectivity of the
 definition.  You are just wanting
 to be more liberal...and me more stoodgy...I wasn't
 dodging the layered
 tektite issue when I said not to bring it up (which
 you unfortunately did:)).
 Clearly layered tektites are closer to impact
 glasses in the continuum and I was
 just trying to cleanly conceptualize.  The
 definition of 'tektite' is a human
 classification which like most, depends on a clear
 understanding of a concept,
 not a recipe.  The Muong Nong glasses (vs. tektites)
 as many experts also call
 them deserve a category by themselves so if you want
 to point to experts
 calling them tektites as support for calling the
 LDG's also tektites, all I can
 say is we are pushing the concept even further.  You
 do mention the meteoritic
 content of Indochinites (=Australasian tektites).
 Yes a small component of
 iron has been detected, but this is very rare, and
 no where near the content in
 LDG which can approach a 0.5%.

 You didn't mention that the partial pressure of the
 air in the bubbles of the
 Indochinites corresponds to the upper atmosphere,
 and that in LDG I am
 assuming it corresponds to the surface.  This
 shouldn't be a surprise as the water
 should not be linearly independent - thus they ought
 to track similarly.

 Good point on the desert weathering, but is there a
 real strewn field defined
 for LDG's, as we find with other conceptually
 true-to-form tektites (pun:))?
 If any evidence could be found, your argument would
 be more solid, as a of
 evidence isn't any proof of anything.  Try checking
 nobel gas ratios and I bet
 the tektite concept will be even further away...

 Where I must really agree with you and put all
 grammatical gymnastics and
 opinions aside, is where you make the best point of
 the whole discussion, imho.
 That maybe our definition of tektites whatever that
 concept may be is based on
 faulty ideas.  With liberty taken, that maybe it
 will change as we learn
 more.  Yes, I buy that, I believe that is a distinct
 possibility.  Things were so
 much simpler when we all agreed they were blasted
 from the Moon and the
 aerodynamic shapes and low water content actually
 meant something more to the
 experts of that time.  Gor the time being, I be
 conservative on the definitions for
 the distinctions mentioned.  Show me one
 aerodynamically shaped LDG besides
 one sculpted by a Neanderthal, and I'll recommend
 you for a Harvey award which
 would be quite fitting:), and definitely a nobel
 prize in the meteoritical
 community...for the moment we think there is a
 crater now, well, we already called
 them impact glasses, and now we have all these years
 of human

Re: [meteorite-list] Largest Crater in the Sahara Desert and LDG

2006-03-03 Thread tracy latimer
Perhaps, rather than falling like a dead rat into the division between 
tektites and impactites, LDG is an indicator of more of a continuous 
spectrum.  We already admit that there are anomalies where Muong Nong 
tektites and some aspects of australites don't fit comfortably within 
tektite parameters.  The meteorite community acknowledges that almost every 
meteorite classification has its odd ducks that show characteristics more 
appropriate to other groups, or fit no existing group (that's how we get new 
classifications!)  Could there conceivably be in between stages, where the 
irregularities of things like LDG actually indicate a median?


Neither fish nor fowl,
Tracy Latimer




 Hola Norm, so it seems we actually agree on most of
 the points, including the
 most important one: the subjectivity of the
 definition.



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