Re: [Biofuel] $1-billion worth of water pouring out of leaking lines - Niagara Falls Review - 2007.07.12

2007-08-14 Thread Doug Woodard
You're over-optimistic. A really good, modern coal fired power plant 
gives 40% thermal efficeicnecy at a high power rating. The line and 
transformer losses come after that. A combined-cycle natural gas fired 
plant (gas turbiine with a steam turbine working off the turbine exhaust 
gases ) will give a maximum of 58%.

Doug Woodard
St. Catharines, Ontario


Paul S Cantrell wrote:
 Funny thing, that's not funny is, about 50% of the energy contained in
 coal makes it to the power outlet.

 The rest is lost to heat loss, line losses and transformer losses.
   
[snip]

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[Biofuel] Peak phosphorus and our food supply

2007-08-14 Thread Doug Woodard

 Be sure to read Bart's Editorial Notes at the end.

 The question of phosphorous is especially important since most soils 
 seem to need added phosphorous to get the most benefit from nitrogen 
 fixing plants (legumes such as clover and alfalfa) which have been 
 the key to the post-medieval revolution in agricultural production 
 and wealth.

 Teh necessity to conserve phosphorous has implications for the type 
 of agriculture, implying organic methods to prevent the leaching 
 away of minerals, and the return of human excremnt and its contents 
 including phosphorous and nitrogen to the land. Especially in an 
 energy-frugal future with limited resources for transportation, this 
 suggests a pattern of human settlement more dispersed over the land.

 Doug Woodard
 St. Catharines, Ontario



 http://www.energybulletin.net/33164.html

 Published on 13 Aug 2007 by Energy Bulletin. Archived on 13 Aug 2007.

 Peak phosphorus

 by Patrick Déry and Bart Anderson

 Peak oil has made us aware that many of the resources on which 
 civilization depends are limited.

 M. King Hubbert, a geophysicist for Shell Oil, found that oil 
 production over time followed a curve that was roughly bell-shaped. 
 He correctly predicted that oil production in the lower 48 states 
 would peak in 1970. Other analysts following Hubbert's methods are 
 predicting a peak in oil production early this century.

 The depletion analysis pioneered by Hubbert can be applied to other 
 non-renewable resources. Analysts have looked at peak production for 
 resouces such as natural gas, coal and uranium.

 In this paper, Patrick Déry applies Hubbert's methods to a very 
 special non-renewable resource - phosphorus - a nutrient essential 
 for agriculture.

 In the literature, estimates before we run out of phosphorus range 
 from 50 to 130 years. This date is conveniently far enough in the 
 future so that immediate action does not seem necessary. However, as 
 we know from peak oil analysis, trouble begins not when we run out 
 of a resource, but when production peaks. From that point onward, 
 the resource becomes more difficult to extract and more expensive.

 Physicist Déry applied the technique of Hubbert Linearization to 
 data available from the United States Geological Survey (USGS)[1] to 
 phosphorus production in the following:

 The small Pacific island nation of Nauru, a former phosphate 
 exporter.

 The United States, a major phosphate producer.

 The world.

 He tested Hubbert Linearization first on data from Nauru to see 
 whether he could have predicted the year of its peak phosphate 
 production in 1973. Satisfied with the results, he applied the 
 method to United States and the world. He estimates that U.S. peak 
 phosphorus occurred in 1988 and for the world in 1989.

 Phosphorus - its role and nature

 Phosphorus (chemical symbol P) is an element necessary for life. 
 Because phosphorus is highly reactive, it does not naturally occur 
 as a free element, but is instead bound up in phosphates. Phosphates 
 typically occur in inorganic rocks.

 As farmers and gardeners know, phosphorus is one of the three major 
 nutrients required for plant growth: nitrogen (N), phosphorus (P) 
 and potassium (K). Fertilizers are labelled for the amount of N-P-K 
 they contain (for example 10-10-10).

 Most phosphorus is obtained from mining phosphate rock. Crude 
 phosphate is now used in organic farming, whereas chemically treated 
 forms such as superphosphate, triple superphosphate, or ammonium 
 phosphates are used in non-organic farming.

 Philip H. Abelson writes in Science:

 The current major use of phosphate is in fertilizers. Growing crops 
 remove it and other nutrients from the soil... Most of the world's 
 farms do not have or do not receive adequate amounts of phosphate. 
 Feeding the world's increasing population will accelerate the rate 
 of depletion of phosphate reserves.

 and

 ...resources are limited, and phosphate is being dissipated. Future 
 generations ultimately will face problems in obtaining enough to 
 exist.

 It is sobering to note that phosphorus is often a limiting nutrient 
 in natural ecosystems. That is, the supply of available phosphorus 
 limits the size of the population possible in those ecosystems.

 More information:

 Understanding Phosphorus and its Use in Agriculture from the 
 European Fertilizer Manufacturers Association.

 Phosphate Primer by Florida Institute of Phosphate Research.

 Prospect of a Phosphorus Peak

 In his frightening book Eating Fossil Fuels [3], Dale Allen Pfeiffer 
 shows that conventional agriculture is as oil-addicted as the rest 
 of society. A decline in oil production raises questions about how 
 we will feed ourselves.

 In the same way, agriculture is addicted to mined phosphates and 
 would be threatened by a peak in phosphate production. As the U.S. 
 Geological Survey (USGS) wrote in summary on phosphates (PDF):

 There are no substitutes for phosphorus in 

Re: [Biofuel] Peak phosphorus and our food supply

2007-08-14 Thread Tom Irwin

Hi Doug,
Phosphorus does cycle slowly in the environment. However, I don't think our soils are going to run out anytime soon. It becomes rather tightly bound in the humic acid component of topsoil. Hence it does not show up in most common soil tests. Green manures bring it out by feeding soil bacteria. Monocroppers will have a problem but organic ones should not.
Tom Irwin




From:Doug Woodard [EMAIL PROTECTED]Reply-To:biofuel@sustainablelists.orgTo:biofuel@sustainablelists.orgSubject:[Biofuel] Peak phosphorus and our food supplyDate:Tue, 14 Aug 2007 05:33:28 -0400  Be sure to read Bart's Editorial Notes at the end.   The question of phosphorous is especially important since most soils  seem to need added phosphorous to get the most benefit from nitrogen  fixing plants (legumes such as clover and alfalfa) which have been  the key to the post-medieval revolution in agricultural production  and wealth.   Teh necessity to conserve phosphorous has implications for the type  of agriculture, implying organic 
methods to prevent the leaching  away of minerals, and the return of human excremnt and its contents  including phosphorous and nitrogen to the land. Especially in an  energy-frugal future with limited resources for transportation, this  suggests a pattern of human settlement more dispersed over the land.   Doug Woodard  St. Catharines, Ontario http://www.energybulletin.net/33164.html   Published on 13 Aug 2007 by Energy Bulletin. Archived on 13 Aug 2007.   Peak phosphorus   by Patrick Déry and Bart Anderson   Peak oil has made us aware that many of the resources on which  civilization depends are limited.   M. King Hubbert, 
a geophysicist for Shell Oil, found that oil  production over time followed a curve that was roughly bell-shaped.  He correctly predicted that oil production in the lower 48 states  would peak in 1970. Other analysts following Hubbert's methods are  predicting a peak in oil production early this century.   The depletion analysis pioneered by Hubbert can be applied to other  non-renewable resources. Analysts have looked at peak production for  resouces such as natural gas, coal and uranium.   In this paper, Patrick Déry applies Hubbert's methods to a very  special non-renewable resource - phosphorus - a nutrient essential  for agriculture.   In the literature, estimates before we "run out" of phosphorus range  
from 50 to 130 years. This date is conveniently far enough in the  future so that immediate action does not seem necessary. However, as  we know from peak oil analysis, trouble begins not when we "run out"  of a resource, but when production peaks. From that point onward,  the resource becomes more difficult to extract and more expensive.   Physicist Déry applied the technique of Hubbert Linearization to  data available from the United States Geological Survey (USGS)[1] to  phosphorus production in the following:   The small Pacific island nation of Nauru, a former phosphate  exporter.   The United States, a major phosphate producer.   The world.   He tested Hubbert Linearization first 
on data from Nauru to see  whether he could have predicted the year of its peak phosphate  production in 1973. Satisfied with the results, he applied the  method to United States and the world. He estimates that U.S. peak  phosphorus occurred in 1988 and for the world in 1989.   Phosphorus - its role and nature   Phosphorus (chemical symbol P) is an element necessary for life.  Because phosphorus is highly reactive, it does not naturally occur  as a free element, but is instead bound up in phosphates. Phosphates  typically occur in inorganic rocks.   As farmers and gardeners know, phosphorus is one of the three major  nutrients required for plant growth: nitrogen (N), phosphorus (P)  and potassium (K). 
Fertilizers are labelled for the amount of N-P-K  they contain (for example 10-10-10).   Most phosphorus is obtained from mining phosphate rock. Crude  phosphate is now used in organic farming, whereas chemically treated  forms such as superphosphate, triple superphosphate, or ammonium  phosphates are used in non-organic farming.   Philip H. Abelson writes in Science:   The current major use of phosphate is in fertilizers. Growing crops  remove it and other nutrients from the soil... Most of the world's  farms do not have or do not receive adequate amounts of phosphate.  Feeding the world's increasing population will accelerate the rate  of depletion of phosphate reserves.   and  
 ...resources are limited, and phosphate is being dissipated. Future  generations ultimately will face problems in obtaining enough to  exist.   It is sobering to note that phosphorus is often a limiting nutrient  in natural ecosystems. That is, the supply of available phosphorus  limits the size of the population possible in those ecosystems.   More information:   Understanding Phosphorus and its Use in Agriculture from the  European Fertilizer Manufacturers Association.   Phosphate Primer by Florida Institute of 

Re: [Biofuel] Peak phosphorus and our food supply

2007-08-14 Thread Keith Addison
We dealt with that a month ago Doug. It's a red herring, unless you 
think CAWKI is doomed without bags of fertiliser bought from BASF 
or whoever (which doesn't work anyway, unless you're BASF's 
accountant).

 ... phosphorus deficiencies are for amateurs.

See:

http://www.mail-archive.com/biofuel@sustainablelists.org/msg70477.html
Re: [Biofuel] Magic Compost Enhancer
13 Jul 2007

  Be sure to read Bart's Editorial Notes at the end.
 
  The question of phosphorous is especially important since most soils
  seem to need added phosphorous to get the most benefit from nitrogen
  fixing plants (legumes such as clover and alfalfa) which have been
  the key to the post-medieval revolution in agricultural production
  and wealth.
 
  Teh necessity to conserve phosphorous has implications for the type
  of agriculture, implying organic methods to prevent the leaching
  away of minerals, and the return of human excremnt and its contents
  including phosphorous and nitrogen to the land. Especially in an
  energy-frugal future with limited resources for transportation, this
  suggests a pattern of human settlement more dispersed over the land.

A lot of other things have been suggesting that too for the last 60 
years or so - small, integrated, mixed, sustainable, organic family 
farms, the answer. It's happening anyway, all over the world, 
spreading like a weed.

Best

Keith



  Doug Woodard
  St. Catharines, Ontario
 
 
 
  http://www.energybulletin.net/33164.html
 
  Published on 13 Aug 2007 by Energy Bulletin. Archived on 13 Aug 2007.
 
  Peak phosphorus
 
  by Patrick DÈry and Bart Anderson
 
  Peak oil has made us aware that many of the resources on which
  civilization depends are limited.
 
  M. King Hubbert, a geophysicist for Shell Oil, found that oil
  production over time followed a curve that was roughly bell-shaped.
  He correctly predicted that oil production in the lower 48 states
  would peak in 1970. Other analysts following Hubbert's methods are
  predicting a peak in oil production early this century.
 
  The depletion analysis pioneered by Hubbert can be applied to other
  non-renewable resources. Analysts have looked at peak production for
  resouces such as natural gas, coal and uranium.
 
  In this paper, Patrick DÈry applies Hubbert's methods to a very
  special non-renewable resource - phosphorus - a nutrient essential
  for agriculture.
 
  In the literature, estimates before we run out of phosphorus range
  from 50 to 130 years. This date is conveniently far enough in the
  future so that immediate action does not seem necessary. However, as
  we know from peak oil analysis, trouble begins not when we run out
  of a resource, but when production peaks. From that point onward,
  the resource becomes more difficult to extract and more expensive.
 
  Physicist DÈry applied the technique of Hubbert Linearization to
  data available from the United States Geological Survey (USGS)[1] to
  phosphorus production in the following:
 
  The small Pacific island nation of Nauru, a former phosphate
  exporter.
 
  The United States, a major phosphate producer.
 
  The world.
 
  He tested Hubbert Linearization first on data from Nauru to see
  whether he could have predicted the year of its peak phosphate
  production in 1973. Satisfied with the results, he applied the
  method to United States and the world. He estimates that U.S. peak
  phosphorus occurred in 1988 and for the world in 1989.
 
  Phosphorus - its role and nature
 
  Phosphorus (chemical symbol P) is an element necessary for life.
  Because phosphorus is highly reactive, it does not naturally occur
  as a free element, but is instead bound up in phosphates. Phosphates
  typically occur in inorganic rocks.
 
  As farmers and gardeners know, phosphorus is one of the three major
  nutrients required for plant growth: nitrogen (N), phosphorus (P)
  and potassium (K). Fertilizers are labelled for the amount of N-P-K
  they contain (for example 10-10-10).
 
  Most phosphorus is obtained from mining phosphate rock. Crude
  phosphate is now used in organic farming, whereas chemically treated
  forms such as superphosphate, triple superphosphate, or ammonium
  phosphates are used in non-organic farming.
 
  Philip H. Abelson writes in Science:
 
  The current major use of phosphate is in fertilizers. Growing crops
  remove it and other nutrients from the soil... Most of the world's
  farms do not have or do not receive adequate amounts of phosphate.
  Feeding the world's increasing population will accelerate the rate
  of depletion of phosphate reserves.
 
  and
 
  ...resources are limited, and phosphate is being dissipated. Future
  generations ultimately will face problems in obtaining enough to
  exist.
 
  It is sobering to note that phosphorus is often a limiting nutrient
  in natural ecosystems. That is, the supply of available phosphorus
  limits the size of the population possible in those ecosystems.
 
  More information:
 
  

Re: [Biofuel] Glycerin as an Emulsifier (was GlycerineSettling Time)

2007-08-14 Thread Thomas Kelly
Hi Joe,

If the answers to questions 2 and 3 are yes then it would explain a lot.

I think so.

Then the answer to question one could be that although the BD did not pass 
the QT if it was settled long enough that there is no glycerol it would be 
consistent with the emergent theory. No? 

Let us be clear re:  The emergent theory.

Is it : Very small amounts of unreacted Mono- and Di- Glycerides combined with 
unsettled Glycerin Mix will produce emulsions, but the same amount of the 
Glycerides or the Glycerin, alone, do not? (There is an 
additive/multiplicative/? effect when both are present)

I think the results seem to indicate this.

Or is the emergent theory: 
The Glycerin Mix settles more slowly from the product of incomplete reactions?
Consistent, yes,  but not evidence for the hypothesis.

If it turns out to be the case it would be a good example of the old 
double-whammy effect. 
Incomplete reactions contribute the unreacted Mono- and Di -Glycerides needed 
for the emulsion which in turn slow the settling of the Glycerin Mix which also 
contributes to the problem.

The significance of whatever emerges may be dispelling a misconception.
 I know of people who view No problems with the wash as a sign that they 
achieved complete reactions. I've been told: I would have gotten emulsions if 
I had any unreacted oil. 
 A buddy of mine recommends letting the BD settle for a few days   a 
week if you can. It seems to take care of any problems.   ??   
 I tell him:  Do a QT try dissolving 25 ml of the BD in 225 ml of methanol.
(12.5 ml BD in 112.5 ml methanol).
 I don't know why homebrewers resist QT-ing their fuel.

   Good Day to You,
 Tom

P.S.  I think we will eventually get to the bottom of the effect of glycerides 
on settling time. I've stocked up on BD for my car (passed QT) in anticipation 
of a push to make heating BD. I'll be able to get settling times on quite a few 
batches of poor quality BD, but won't be running any 'good quality batches, 
for comparison, for a few weeks.



  - Original Message - 
  From: Joe Street 
  To: biofuel@sustainablelists.org 
  Sent: Monday, August 13, 2007 4:41 PM
  Subject: Re: [Biofuel] Glycerin as an Emulsifier (was GlycerineSettling Time)


  Hi Tom;

  If the answers to questions 2 and 3 are yes then it would explain a lot.  
Then the anwer to question one could be that although the BD did not pass the 
QT if it was settled long enough that there is no glycerol it would be 
consistent with the emergent theory. No? 


  Joe

  Thomas Kelly wrote:

On Friday 8/10, I noted that:

II. Glycerin Cocktail:   Time to 
Separate (wash test)
   good quality BD + water + glycerin cocktail2 hours* 
   poor quality BD  + water + glycerin cocktail2 hours*

It almost 2 days for the good quality BD to separate out. There was a 
very clear soap layer between the BD layer and the water layer.

It's almost three days now and the poor quality BD still has an emulsion 
layer. More than half of the BD layer is emulsion. 

My thoughts:
1. Glycerin, itself, separated from the cocktail, is not an effective 
emulsifier
2. Presence of just the glycerin cocktail lengthens the time needed to  
separate water from BD
3. The glycerin cocktail in combination with even small amounts of 
unreacted 
Mono- and Di- Glycerides forms emulsions during wash.

***Keep in mind that my poor quality BD failed the Methanol Solubility 
Test (the Warnqvist Quality Test), in that the resulting mix was cloudy, and 
given time, an observable, but difficult to measure, amount of residue 
(unreacted glycerides) dropped out. There were not globs of residue. This was 
not real bad BD. It is used in my home heating system.

Questions/Comments:
1. Unreacted Mono- and Di- Glycerides have a reputation as being very 
effective emulsifiers. They are present in the BD that I make to heat my house. 
Why don't they form emulsions when I stir wash this BD?

2. If glycerin cocktail (unsplit) is present, the same levels of Mono- and 
Di- Glycerides form emulsions, when they are only shaken . 
Does this represent a cumulative or synergistic effect?

 The cumulative/synergistic effect of glycerin cocktail and unreacted 
glycerides on emulsion formation would explain a couple of observations:
a. Incomplete reactions coupled with short (6 - 8 hour) settling times 
often produce emulsions in the wash. Longer settling times 2 days or more 
no emulsions. The glycerin has settled out
b. After breaking emulsions (1st and even 2nd wash), subsequent washes go 
well w/o emulsions forming. The Mono- and Di-Glycerides are still present, but 
the components of the glycerin cocktail have been, for the most part washed out.

3. Does the glycerin cocktail settle out of incomplete reactions 

Re: [Biofuel] I'm ready to settle this once and for all

2007-08-14 Thread Thomas Kelly
Mike,

 My thoughts:
1. Increased settling time (2 days or more) allows the soaps in the glycerin 
mix to settle out and results in easier washing of  BD whether from complete 
reactions or from incomplete reactions.
It does NOT remove unreacted glycerides.

2. Because increased settling time usually results in washes that do not 
produce emulsions, it is essential to do a Quality Test other than the Wash 
Test in order to assess whether we achieved a complete reaction.

Simple, quick, cheap QT:
Wanqvist QT:   Add 25 ml of BD to 225 ml of methanol. Shake mix. Allow to 
settle. Any residue at bottom indicates unreacted Glycerides
= Incomplete Reaction.
(see JtF   Quality Testing)

Resulting mix/solution can be added to methanol for next batch.

 Tom

- Original Message - 
From: Mike Weaver [EMAIL PROTECTED]
To: biofuel@sustainablelists.org
Sent: Thursday, August 09, 2007 7:27 PM
Subject: [Biofuel] I'm ready to settle this once and for all


 Thanks for the write up - has anyone mixed all this discussion up and
 settled out the most salient points?


 Joe Street wrote:

 Thanks a lot Tom for all that work in a short time.  You have really
 shed some light on this discussion.  Jumping to your questions at the
 end, it seems clear then that Jan and Andres were right on and it must
 be the soap and mono-diglycerides etc rather than the glycerine itself
 which is the culprit..  It also seems to confirm or at least not in
 conflict with the theory that glycerin settles more slowly from
 incomplete reactions.  I have never done anything with straight
 glycerol just the cocktail but it does contain soap al lots of other
 things.  Small amounts of it have a large impact and it appears that
 incomplete reactions result in a significant amount of it remaining in
 the fuel after a prolonged period.  I normally allow about 12 hours
 for settling (at least) and when the reaction is good an agressive
 pump wash is no problem.  One of the aims of my project was to reduce
 cycle time so I really don't want to wait 24 or more hours because
 sometimes time is not free as Keith had put it.

 Was going to add more but time's up and the door to my cage is OPEN!
 Have a good weekend

 Joe

 Thomas Kelly wrote:

 Andres, Jan, Joe, Keith, and anyone else who has been following the 
 saga,

  It would seem that glycerine, itself, is not an effective
 emulsifier.

 I've spent the morning experimenting in the kitchen. I did Wash
 Tests on BD that passed the QT and BD that failed the QT. I tested
 one group with glycerine split from the cocktail (using Phosphoric
 Acid) and another group with unsplit Glycerin cocktail.

 Volumes used:
 Biodiesel 150 ml
 Water 150 ml
 Glycerin (split and unsplit)  4 ml

 Temp:  70F  (~22C)

 I. Glycerin split from the cocktail (used Phosphoric Acid):
Controls:   Time for clear
 separation (min)
good quality BD +  water  1 - 2
poor quality BD  +  water  3 - 4

Experimental:
good quality BD + water + glycerine (split) less than 5
poor quality BD  + water + glycerine (split) less than 5

 II Glycerin Cocktail:
good quality BD + water + glycerine cocktail2 hours*
poor quality BD  + water + glycerine cocktail2 hours*

 * At 2 hours there is a thin layer of BD (1 - 2 mm) The rest appears
 to be an emulsion.

  Andres and Jan, you are correct. Glycerin, itself, did
 little to retard separation of BD and water.

  Something in the cocktail does seem to be an emulsifier. (The
 soaps??)

 Some questions remain:
 1. The BD that failed the QT (incomplete reaction) was obtained from
 a tank that feeds my heating system. It contains unreacted
 glycerides, but does not produce an emulsion when shaken in water,
 nor did it produce emulsions when it was stir-washed. Why not?
 2. At Joe Street's suggestion I took a sample of BD that had settled
 for about 10 hours. Twelve hours later, more glycerin had settled
 out. Today, still another 24 hours later, even more has settled out.
 Could this small amount of unsplit glycerine (with associated soaps)
 be the cause of the emulsions I got when I started making BD? It
 would explain why settling for a day or more seems to eliminate the
 problem.
 3. Does the glycerine mix (or soaps) settle out more slowly in BD
 from incomplete reactions?

  Tom





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Re: [Biofuel] $1-billion worth of water pouring out of leaking lines - Niagara Falls Review - 2007.07.12

2007-08-14 Thread Paul S Cantrell
Hey Doug,
Good point, the majority of coal plants are in the 40% ballpark, but I
was being generous and including the combined cycle coal-fired plants.
 I've been to one in Columbia, SC that achieves 50% from coal.  It
also uses cool water from the bottom of the lake for cooling, so that
increases efficiency, too.

http://www.sceg.com/en/about-sceg/power-plants/fossil-fired/mcmeekin-station/McMeekin-Station.htm

They burn 96 tons of coal per hour to generate 252 mWe.  At 18 million
BTU per ton, that works out to 50% at the power station bus.

On 8/14/07, Doug Woodard [EMAIL PROTECTED] wrote:
 You're over-optimistic. A really good, modern coal fired power plant
 gives 40% thermal efficeicnecy at a high power rating. The line and
 transformer losses come after that. A combined-cycle natural gas fired
 plant (gas turbiine with a steam turbine working off the turbine exhaust
 gases ) will give a maximum of 58%.

 Doug Woodard
 St. Catharines, Ontario


 Paul S Cantrell wrote:
  Funny thing, that's not funny is, about 50% of the energy contained in
  coal makes it to the power outlet.
 
  The rest is lost to heat loss, line losses and transformer losses.
 
 [snip]


-- 
Thanks,
PC

He's the kind of a guy who lights up a room just by flicking a switch

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[Biofuel] self sufficiency

2007-08-14 Thread Kirk McLoren

  http://www.growitalian.com

Imported heirloom seeds from a family owned Italian company founded in
the 1700s.

   
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Re: [Biofuel] Biodiesel in V6 diesel engine

2007-08-14 Thread fox mulder
Hello all,
Has any had experience with using Biodiesel in V6
diesel engine? If so, is there any adverse effect?
fox


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Re: [Biofuel] Beyond batteries: Storing power in a sheet of nanocomposite paper

2007-08-14 Thread fox mulder
Source: http://physorg. com/news10624516 4.html

 

 

Beyond batteries: Storing power in a sheet of
nanocomposite paper 


A sample of the new nanocomposite paper developed by
researchers at Rensselaer Polytechnic Institute.
Infused with carbon nanotubes, the paper can be used
to create ultra-thin, flexible batteries and energy
storage devices for next-generation electronics and
implantable medical equipment. Credit:
Rensselaer/Victor Pushparaj




Researchers at Rensselaer Polytechnic Institute have
developed a new energy storage device that easily
could be mistaken for a simple sheet of black paper. 

 

The nanoengineered battery is lightweight, ultra thin,
completely flexible, and geared toward meeting the
trickiest design and energy requirements of tomorrow’s
gadgets, implantable medical equipment, and
transportation vehicles. 



Along with its ability to function in temperatures up
to 300 degrees Fahrenheit and down to 100 below zero,
the device is completely integrated and can be printed
like paper. The device is also unique in that it can
function as both a high-energy battery and a
high-power supercapacitor, which are generally
separate components in most electrical systems.
Another key feature is the capability to use human
blood or sweat to help power the battery. 

Details of the project are outlined in the paper
“Flexible Energy Storage Devices Based on
Nanocomposite Paper” published Aug. 13 in the
Proceedings of the National Academy of Sciences. 

The semblance to paper is no accident: more than 90
percent of the device is made up of cellulose, the
same plant cells used in newsprint, loose leaf, lunch
bags, and nearly every other type of paper. 

Rensselaer researchers infused this paper with aligned
carbon nanotubes, which give the device its black
color. The nanotubes act as electrodes and allow the
storage devices to conduct electricity. The device,
engineered to function as both a lithium-ion battery
and a supercapacitor, can provide the long, steady
power output comparable to a conventional battery, as
well as a supercapacitor’s quick burst of high energy.


The device can be rolled, twisted, folded, or cut into
any number of shapes with no loss of mechanical
integrity or efficiency. The paper batteries can also
be stacked, like a ream of printer paper, to boost the
total power output. 

“It’s essentially a regular piece of paper, but it’s
made in a very intelligent way,” said paper co-author
Robert Linhardt, the Ann and John H. Broadbent Senior
Constellation Professor of Biocatalysis and Metabolic
Engineering at Rensselaer . 

“We’re not putting pieces together – it’s a single,
integrated device,” he said. “The components are
molecularly attached to each other: the carbon
nanotube print is embedded in the paper, and the
electrolyte is soaked into the paper. The end result
is a device that looks, feels, and weighs the same as
paper.” 

The creation of this unique nanocomposite paper drew
from a diverse pool of disciplines, requiring
expertise in materials science, energy storage, and
chemistry. Along with Linhardt, authors of the paper
include Pulickel M. Ajayan, professor of materials
science and engineering, and Omkaram Nalamasu,
professor of chemistry with a joint appointment in
materials science and engineering. Senior research
specialist Victor Pushparaj, along with postdoctoral
research associates Shaijumon M. Manikoth, Ashavani
Kumar, and Saravanababu Murugesan, were co-authors and
lead researchers of the project. Other co-authors
include research associate Lijie Ci and Rensselaer
Nanotechnology Center Laboratory Manager Robert
Vajtai. 

The researchers used ionic liquid, essentially a
liquid salt, as the battery’s electrolyte. It’s
important to note that ionic liquid contains no water,
which means there’s nothing in the batteries to freeze
or evaporate. “This lack of water allows the paper
energy storage devices to withstand extreme
temperatures,” Kumar said. 

Along with use in small handheld electronics, the
paper batteries’ light weight could make them ideal
for use in automobiles, aircraft, and even boats. The
paper also could be molded into different shapes, such
as a car door, which would enable important new
engineering innovations. 

“Plus, because of the high paper content and lack of
toxic chemicals, it’s environmentally safe,” Shaijumon
said. 

Paper is also extremely biocompatible and these new
hybrid battery/supercapcit ors have potential as power
supplies for devices implanted in the body. The team
printed paper batteries without adding any
electrolytes, and demonstrated that naturally
occurring electrolytes in human sweat, blood, and
urine can be used to activate the battery device. 

“It’s a way to power a small device such as a
pacemaker without introducing any harsh chemicals –
such as the kind that are typically found in batteries
– into the body,” Pushparaj said. 

The materials required to create the paper batteries
are inexpensive, Murugesan said, but the 

Re: [Biofuel] Biodiesel in V6 diesel engine

2007-08-14 Thread Zeke Yewdall
Ummm.  I don't know anyone who makes a V-6 diesel engine.  What's it
in, how old is it, and who manufactured it.

On 8/14/07, fox mulder [EMAIL PROTECTED] wrote:
 Hello all,
 Has any had experience with using Biodiesel in V6
 diesel engine? If so, is there any adverse effect?
 fox


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Re: [Biofuel] Biodiesel in V6 diesel engine

2007-08-14 Thread Doug Younker



Zeke Yewdall wrote:
 Ummm.  I don't know anyone who makes a V-6 diesel engine.  What's it
 in, how old is it, and who manufactured it.

Some of the Detroit 2 cycle diesels where, are? available in a V6 
configuration. I remember that my dad's first oil well servicing rig was 
power by a V6 71 DD.  Wikipedia reveals that the  V configuration was 
introduced in 1957.

Doug, N0LKK
Kansas USA inc.

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