Re: [Biofuel] Basic Questions, Major Problems: Biofuel Batches

2011-09-25 Thread Pagandai Pannirselvam
 Helo  Seth  and  Keith

 One master thesis done in our  chemical engineering regarding KOH and NaoH
. I was examiner of this work .Even though KOH  is more costlier , not
readily  avilable  compared to NaOH , we found it can work even at room
temperture , more  active as catlayst compared  to NaOH , even lesser amount
, in the work done with cater and other oil.Thus  our results confirm too
the  the work of Keith.

Yours truly
Pannirselvam
Natal, RN,Brazil


2011/9/24 Keith Addison [EMAIL PROTECTED]

 Hi Seth

 Thanks for posting, some sound advice there, but I have to make a
 couple of comments.

 No way is NaOH a better catalyst than KOH (not just my opinion). With
 that in mind, I somehow wasn't surprised to read further down that
 you've had hundreds of failed batches, in only two years.

 There just isn't any good reason to have failed batches. We made an
 average of one batch a week for seven years and didn't have a single
 failed batch. There's nothing special about us, if we can do it
 anyone can. And yet you're teaching workshops?

 All best

 Keith


   Hi Chris, I've had all the problems you are having and more.
 Titration is an essential part of the process though! You cannot
 skip this step, even with new oil. Accurate measurements? Is the
 murky water white? If it is, you are doing it right(as long as you
 have the biodiesel separated from it.) Remember that the biodiesel
 will be a murky yellowish color after the first wash
 
 It sounds as if you are being very methodical and careful with your
 process. For the record, I have found that I have had better results
 with Naoh than KOH  Lye. It is possible that your chemical is
 inferior.
 
 Remember that Lye immediately absorbs moisture from it's environment
 and that would tend to mess with your results. Is the Lye stored in
 a sealed container? Are you sure the Lye is completely dissolved in
 the methanol?
 
 I have had fairly consistent results using a blender for test
 batches. Consistent temperature is important, but I have found that
 too much heat is even worse than not enough If the batch overheats,
 a percentage of the alcohol tends to evaporate and the result is
 jelly. Remember that Methanol evaporates at 67.4 celcius.
 
 I've been making bio-diesel now for 2 years with the majority of my
 batches working out awesome. Don't feel bad though, I've had
 hundreds that haven't. There have been times I have had to take
 apart my entire 200 litre processor and blow out every piece with an
 air compressor to clean out the congealed crap fro a jelly reaction.
 I have made soap, mayonnaise and all manner of things besides
 Bio-diesel. Bears have trashed my shop and gone after the glycerin
 and oil. I have contaminated batches of bio-diesel accidentally and
 broken down on the side of the highway at -30... The list goes on,
 but once you start, you can't give up! I have also driven almost
 100,000 km on my own fuel, sold it and given it to farmers, taught
 workshops, powered music festivals and much more on my fuel.
 
 However much of a pain in the ass making bio-diesel can be, it's not
 a petroleum product!!!
 
 
 Seth-Dredneck' Macdonald
 Dunster BC
 CANADA
 
 
 
 
 From: C Pinelli [EMAIL PROTECTED]
 To: sustainablelorgbiofuel@sustainablelists.org
 Sent: Friday, September 23, 2011 4:57:10 PM
 Subject: Re: [Biofuel] Basic Questions, Major Problems: Biofuel Batches
 
 
 Again, I have not tritrated because it is virgin oil. Should I?
 
   From: [EMAIL PROTECTED]
   To: sustainablelorgbiofuel@sustainablelists.org
   Date: Thu, 22 Sep 2011 00:06:00 -0500
   Subject: Re: [Biofuel] Basic Questions, Major Problems: Biofuel Batches
 
 
   what's the titration of your oil? even if it's new doesn't mean
 its clean, or even dry.
 
 
From: [EMAIL PROTECTED]
To: biofuel@sustainablelists.org
Date: Wed, 21 Sep 2011 10:55:31 -0400
Subject: [Biofuel] Basic Questions, Major Problems: Biofuel Batches
   
   
Hi all,
   
my name's Chris, I've been an avid ethanol brewer for a couple
 years and I'm shifting into biodiesel now with the help of the
 amazing Journey To Forever site. I've been trying for about 6
 months in my spare time but have had almost no success with test
 batches. and I'm just about at my wit's end. I need some help. I
 thought if I laid out my proceedure and questions someone might be
 able to point out something that I'm doing wrong.
   
I start by filling an old pot with water, and placing a 4L HDPE
 jug in it. I use that jug to mix the oil. I pour the vegetable oil
 (usually Canola) into the jug, and heat to 55'C.

While that is heating, I measure out 200mL of 100% Methanol and
 5.454g of 90% KOH. Mixing them together quickly in a glass jar to
 avoid air contamination.
   
I add the methoxide to the oil and begin mixing. I use an
 electric drill on a homemade stand and a small steel paint mixer
 that attaches to the drill for mixing. Usually on low settings
 because it 

[Biofuel] Cross post from bioenergy list :Ruralization of Urban Area using Biomass Car and bio char using wastes

2009-04-11 Thread Pagandai Pannirselvam
 Helo  Keith and  list members

This is an very  imporatant topic  about small biomass  car from wastes
Posted in Bioenergy list .
As this toic is also relevant as biogas need to compete with pyrogas or
syngas , let us also have debate  here too

Yours truely
Pannir selvam P.V



Prof  Pagandaia . V  Pannir wrote

Hi Jim

You wrote  :i'm fearing
our entry is creating technical difficulties for the committee to relate to
more
typical entries.

  Most of the people  who are doing project development are  engineering  or
technical people . As  I am an university engineering Research oriented
Professor , UFRN, Natal , Brazil ,teaching project development subject to
engineering students as as well as the subjects rrelated to the
environmental impact of the technology , can understand  well why   they
only  bother about technical problems  as well as difficulties, not the
whole sustainable problems , which  I wish to bring here your  attention
.Let us as  have  a  look at the past what All big AUTO  Industry had been
in the case of biomass based bio ethanol fuel car project In Brazil.  The
Auto industry has rejected to make a car adopted to hydrated ethanol  mainly
due to technical problems as  useless , The Brazilian government  need to
make this car , making possible technological change . This  is an critical
event   bio fuel project for the survival  Brazilian ethanol projects , as
even the Auto industry yet ignore these bio fuel  project for technical
reasons , but the projects made  Brazil more sustainable Bio Energy producer
of the world today ,  even the rich country  who has biomass resource  such
as  Australia is not able to implement ethanol bio fuel project because of
the the Auto industry technical difficulties concepts, making it impossible
as  you correctly identified the problems  as  they have limited vision
and  just  the look only for the  free energy , free money , not understand
yet  the problem of  technological innovation and sustainable problem , and
also they need to make  some risk too .

  Thus several  innovations  were made possible , as approved  by many of
the list members here about technical problems , they do not even want to
know and I am sure as you point out that they are  on the  way on the other
end of things from the image of a sleek electric car where discussions of
future transport usually start. Here is the place a lot of research and
development money  usually had been spent with little output or innovation ,
not for useful project one that of biomass car

 I like  very much  your final consideration note about  that what they like
is free energy scheme  as if biomass very  cheap  , is waste ,so all can
make free  money from free biomass waste.

Some one  even giving comment there that what you are doing is  pyrolysis
and  bio char , not gasification , then  giving a note  that you are making
CO2 problems , as if there no such problems now.
Latter they may ask you pay for  the  co2 credit too  from you , as the one
do not considered biomass resource are renewable , as the co2 is not same as
the non renewable

Jim , as you  who has made several technical innovations , as you correctly
pointed  out the opportunity  of the technological change , can see the
opportunity is   there much in the rural areas, as this one is for rural
transport , where we all know here in this list , there  can not  be  any
free energy   , or any free money   for the Free prosperity  made  possible
freely , but  the whole system involves , the   outcome from Bio char , the
bio oil  as well as the the wood Tar too even a small quantity  of these
products , during long time  operation  can make or break the biomass car
project as well the risk involved

   Those  who develop  the car , like microsoft window  mouse   tied with
the software  has  no idea that they are involved in the making of  the
hardware  that need to be  different than the car  of hybrid , hydrogen and
electrical. I agree with you that  what they really need to understand is
that the technology change can be made possible  using the open source ,
such as the google approach,  making the car  using waste , showing that not
as an free energy  , very low operating cost  alone , but has several  real
byproducts too . This new technological change is an urgent need  not only
for rural area  but also urban  as the ruralization of urban are can be made
possible from waste from urban .Every where in the planet  , particular in
Europe and North  , we all have destroyed the biomass resource in urban  to
the extent  of  more than 80 percent , where as this is only y less than 60
in Brazil .
The biomass powered car  from waste  using bio char need to take into the
these several new opportunities  in all dimension so  that all the
byproducts  from the this  project make this project to be  more economical,
environmentally correct one , socially desirable .This can be well
understood  from live  example , if one carefully look into the fact 

[Biofuel] Cross post Fwd: [Gasification] MICROWAVE HEATING TO PRODUCE BIOFUELS

2008-07-24 Thread Pagandai Pannirselvam
 Helo, Keith and list memberbers

  As high temperature short time heterogenios catalyst with very cheap
sodium carbonate can work , will this mico oven can make possibe home made
biodiesel as this can simplify the fuel seperation which is more than 50
porcent of the whole cost and also the quality of the product as the
process  outlind below  is claimed to be

*Microwave heating has been shown to be advantageous by decreasing the
energy requirements for a number of reactions in the production of biofuels,
and decreasing the time involved in the process.The team will also study the
use of a heterogeneous, or solid, catalyst, which can potentially save about
50% of the current costs

see below more information
*


-- Forwarded message --
From: Benjamin Domingo Bof [EMAIL PROTECTED]
Date: Thu, Jul 24, 2008 at 12:52 PM
Subject: [Gasification] MICROWAVE HEATING TO PRODUCE BIOFUELS
To: Discussion of biomass pyrolysis and gasification 
[EMAIL PROTECTED]



LATEST NEWS
Biofuels to get microwave treatment
24th July, 2008



Microwave heating decreases the energy requirements for a number of
reactions in the production of biofuels in a shorter period of timeA team of
researchers from the University of Massachusetts Amherst has received a
$440,000 (€280,000) grant from the National Science Foundation for research
that will speed up the production of biofuels using microwaves.

The research will focus on converting natural products, such as vegetable
oil, wood and grasses, to liquid fuels.
The grant will support the Microwave Enhanced Catalytic Production of
Biofuels project, which will study two key improvements in the process of
making sustainable fuels. The first is microwave heating, which can
potentially save approximately 80% of what it now costs to produce biofuels.
'Production of biofuels must be a highly efficient process to be
economically competitive with fossil fuels,' William Conner, a professor of
chemical engineering and the principal investigator on the grant, explains.
'Therefore, it is critical that conversion processes be developed that
consume minimal amounts of energy. We expect some of the production
processes we're studying to be at least twice as efficient as current
methods.'
Microwave heating has been shown to be advantageous by decreasing the energy
requirements for a number of reactions in the production of biofuels, and
decreasing the time involved in the process.
The team will also study the use of a heterogeneous, or solid, catalyst,
which can potentially save about 50% of the current costs. 'The idea is to
make the process more efficient by using a heterogeneous catalyst, meaning
you don't have to neutralise the fuel to make it less corrosive, as you
would normally have to do if you used a homogeneous catalyst,' Conner adds.
Conner is also involved in acquiring a biodiesel pilot plant for UMass
Amherst that would produce 600,000 gallons of biodiesel fuel a year from
used vegetable oil recycled from institutional kitchens.
Since vegetable oil is one of the feedstocks the research team will be
studying, the pilot plant would become an integral part of the research. The
pilot plant would also help to establish UMass Amherst as a centre for
studying renewable fuels



 

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-- 
Pagandai V Pannirselvam
http://pannirbr.googlepages.com
Universidade Federal do Rio Grande do Norte - UFRN
Departamento de Engenharia Química - DEQ
Centro de Tecnologia - CT
Programa de Pós Graduação em Engenharia Química - PPGEQ
Grupo de Pesquisa em Engenharia de Custos - GPEC

Av. Senador Salgado Filho, Campus Universitário
CEP 59.072-970 , Natal/RN - Brasil

Residence :
Av Odilon gome de lima, 2951,
Q6/Bl.G/Apt 102
Capim Macio
EP 59.078-400 , Natal/RN - Brasil

Telefone(fone ) ( 84 ) 3215-3769 Ramal210
32171557
Telefone(fax) ( 84 ) 3215-3770
residencia 32171557

Cellular 84 88145083

www.ecosyseng.wetpaint.com



-- 
http.www.ecosyseng.wetpaint.com
http://partnerpage.google.com/biomassa.eq.ufrn.br

Grupo de Pesquisa em Engenharia de Custos e Processos
DEQ – Departamento de Engenharia Química
CT – Centro de Tecnologia / UFRN, Lagoa Nova – Natal/RN
Campus Universitário. CEP: 59.072-970
http://pannirbr.googlepages.com/gpecufrnhomepage

3215-3769 ramal 210
casa 3217-1557
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Re: [Biofuel] WVO in Diesel Generators ; VO ou BD or Blend:Small System MODEL

2008-01-15 Thread Pagandai Pannirselvam
 can be  economic problem as the price are
 expensive..The use of  ethanol and BD extraction vegetable seed Principal
 the castor and cashew nut  oil as well as the biol oil can be pratical
 method tommake biofuel .However  in our system design  approach  we are
 limited to approach . Surely who uses the system need to do the home work
 experimenting the method.


 Thus practical  work alone without undersatanding what one do  , can be
 good for big biofuel as  they wish to sell the products.

Several  public and private  oil company have their patent related with
 BD as additives.I am sure som of our list members also knows , do  Phd
 work .They will not make this open as  they do not care for  small systems
 and also small farmer.

  Our system analysis group wish  one understand the system , the use it ,
 not the block box ,practical ready made things. thus our approach
 compliments several hand made , self made biofuel project published in JTF
 by Keith. In recent work in our wiki http://www.ecosyseng.wetpaint.com/(
 www.ecosyseng.wetpaint.com)we make  system analysis of BD processes so
 that our students and also  all the new one can understand well the systems
 .
 Once you understand,learned well , you need to reflect and  practice it
 and  can be very creative to make inovative small system . Yet  our system
 are not real proven one , as our work is  an part , and i wish the other can
 make other part too.

 With India making the cheapest car , you can see , there will the food and
 fuel conflict , we need systems work to get the both in decentralized
 village level energy production.

   I am going to present two International Paper on IAW Expert conference
 in , in Coimbatore , TN India about fuel, food and water problems , and
 about the use of small bio gas and integrated biosystems too in the 6 FEB ,
 2008. and wish to share indian experience also of the biofuel here.

 This will be the topic of  my future post here to share more about
 biofuel  and as you have told , in 2007 I contributed very less here and  I
 am sure in 2008 , as we are getting  very good results  The 2008 will the
 new year of  bio oil, pyrolysis gs , biogas  based on CNSL and  VO, surely
 biofuel blend  will  be the hot topic The new biofuel blend can be invented
 , to  make underdeveloped  farmers can  make this globalized word much more
 good place ,as they can also feed well  all the world   and them too .

 Thanking for you the good question you have made  and wish happy 2008 for
 biofuel list members .The number of post are reducing a bit , we all the old
 and new member  need to make this list as the best which used to be ., which
 is  and surley will be too .

 I wish too reply of Keith for all the post as he used to do always  to
 make the list much dynamics with new  useful data and sure he is doing the
 best for a long time  , yet the new list young list  members can make
 questions too , as the future of the global energy are in their hands to mak
 it more just and sustainable for all not for few.



 With kind regards

 Pannirselvam P.V
 North East (semi Arid)  BRAZIL








 experimental verification?

 Thanks and regards.

 Chandan
 Chandan Haldar [EMAIL PROTECTED] para sustainablelor.
 mostrar detalhes
  11 jan (4 dias atrás) Pannirselvam,

 Happy New Year to you from India.  Good to see your mail after
 a long time, but I'm quite confused by it.

 I thought Keith only reported what YOU wrote earlier on 9/25/2006
 (regarding mixing ~20% BD and 5-10% ethanol into (fresh/used) VO
 to reduce viscosity).

 Could you please specifically clarify if you or your associates
 have actually made this kind of mixture work or if you have seen
 this being done or if you are making a hypothesis that needs
 experimental verification?

 Thanks and regards.

 Chandan


 Pagandai Pannirselvam wrote:
  snip
  Based on what Keith has reported recently,  castor oil  20 % can be used
 to
  80 % ethanol hydrated ,I am sure  again a  significant amount
 of  ethanol
  can be replaced  using SVO  with  viscosity as the limit,thus there will
 not
  be no need for  BD in rural areas to run generator.
 
  Milled Castor beans can be used  extract ethanol from water  , then
 pressed
  ,  mixed with the SVO , so taht the engine can run  with out engine
  modification and also without the expensive BD .
  snip
   Yours truely
 
  Pagandai V pannirselvam
 
 
  2008/1/7, [EMAIL PROTECTED] [EMAIL PROTECTED]:
  Hello Tom
 
  Hello All,
 On 9/25/06 Pagandai Pannirselvan wrote:
  The small co generation of electrical energy based on the bio
  diesel  can
  make possible the use of pure used vegetable  oil and  also some e 5
  porcent hydrated ethanol , making possible to lower the viscosity of
  used
  vegetable oil  in deiesel engine, removing  dependence with
  Conventional deisel.
  Thus the blend of used vegetable oil 70 percent, hyrated ethanol 10
  percent  and biodeisel 20 porcent   can be used with less problem for
  motor

Re: [Biofuel] WVO in Diesel Generators

2008-01-10 Thread Pagandai Pannirselvam
 Helo  Thomas


We are experimenting to use  cashew nut shell liquid and spent  SVO as
additives  to alcohol for gasoline engien .if we want we can suply from
Brasil  to you

With regards
pannirselvam

2008/1/7, Thomas Kelly [EMAIL PROTECTED]:

 Keith,
  Thanks.
  Not only will your reply be helpful in the matter of the diesel
 generator, but may help me in my quest to run a gasoline car, legally,
 on
 homebrewed ethanol.
  If the water in 95% ethanol will not cause problems when I denature
 the
 ethanol with gasoline (2 gallons per 100 gal of ethanol), I can, with a
 permit, legally produce ethanol and run cars on it.

  I will pass on the information you have provided, and attempt to
 digest
 it all myself.
 Best to You,
  Tom
 - Original Message -
 From: [EMAIL PROTECTED]
 To: biofuel@sustainablelists.org
 Sent: Monday, January 07, 2008 10:34 AM
 Subject: Re: [Biofuel] WVO in Diesel Generators


 Hello Tom

 Hello All,
 On 9/25/06 Pagandai Pannirselvan wrote:
 The small co generation of electrical energy based on the bio
 diesel  can
 make possible the use of pure used vegetable  oil and  also some e 5
 porcent hydrated ethanol , making possible to lower the viscosity of
 used
 vegetable oil  in deiesel engine, removing  dependence with
 Conventional deisel.
 Thus the blend of used vegetable oil 70 percent, hyrated ethanol 10
 percent  and biodeisel 20 porcent   can be used with less problem for
 motor maintainence in rural areas.

 He says with less problem, I'm not sure if that means without problem
 but it might do.

  I've recently been contacted by a former student who would like to
 generate his own electricity for his woodworking business. He is
 considering a diesel generator and asked about biodiesel. I
 suggested he look into using a BD/WVO blend rather than processing
 it all into BD, as he would be using about 3 gallons (11.4 L) per
 hour (120+ gal/week).
1.  Does anyone have experience using a  blend such as that suggested
 by Pagandai Pannirselvan in a diesel generator?

 No experience, sorry, but some thoughts might help, FWIW.

2.  Hydrated ethanol:  What % water would be tolerated?
  In the U.S. it is possible to get a permit to distill ethanol. Only
 that which leaves the premises must be denatured to prevent human
 consumption. 85-90% ethanol is do-able, and used on premises would
 not have to be denatured

 The maximum purity you can get straight from the still is about 96%,
 190-proof (95%) should be doable.

 This is from David Blume's excellent book Alcohol Can Be a Gas!:

 There is a myth that anything less than 200-proof alcohol will separate
 from gasoline due to the small amount of water in the alcohol. Gasoline,
 alcohol, and water are miscible (stay dissolved in one another), depending
 on temperature and on water and alcohol content. In fact the bottled
 additive to combat water in your tank, generically known as Dry Gas, is
 nothing more than 200-proof alcohol, which causes the water to blend with
 the gasoline.

 In Brazil, they pump alcohol that contains about 4% water. In warm
 climates there is absolutely no problem in mixing wet alcohol with
 gasoline, but all of Brazil is not warm and balmy. When I visited there, a
 General Motors engineer showed me a study that accurately outlined the
 physical limits of mixing water, alcohol, and gasoline. According to the
 paper, published by the Society of Automotive Engineers, at about 68 deg F
 [20 deg C], alcohol with as much as 45% water will mix with gasoline and
 not separate. At 4% water, alcohol will form a stable mix with gasoline
 down to about minus 22 deg F! [-30 deg C] This means that those of you who
 live in milder climates don't have to go through the extra step of
 producing dry 200-proof alcohol to get it to mix properly with gasoline.
 And if you do live in minus 22 deg F, you would generally only have to use
 200-proof during the winter and only if you were going back and forth
 between alcohol and gasoline in a non-flexible-fuel vehicle. Flexible-fuel
 vehicles will simply adjust to phase-separated fuel.

 Pagandai was probably referring to 96% ethanol, 4% water, but I guess 95%
 would do just as well.

 David Blume also refers to farmers' tests in the US using blends of
 petro-diesel, biodiesel and dry ethanol in diesel engines. Most used 50%
 ethanol, and 25% each of biodiesel and petro-diesel, but Blume says they
 only used the petro-diesel because it was cheaper than biodiesel at the
 time and 50-50 alcohol and biodiesel should be fine. He thinks a minimum
 of 20% biodiesel and 80% alcohol would also be fine, but says it needs
 testing (with a dynamometer and a knock-meter).

 What % water would be tolerated? Water in the fuel can be a Good Thing,
 it improves combustion efficiency and reduces emissions - just as long as
 it stays in the fuel and doesn't separate.

 This EPA 

Re: [Biofuel] WVO in Diesel Generators or BD or Blend

2008-01-10 Thread Pagandai Pannirselvam
   Happy new year for all the list members

 I am Pagandai  Pannirselvam  from Brazil.

   Very glad  that after some 2 years of my post about blended biofuel , we
have now come agian to make the debate. When I wrote  about hydrated ethanol
is E 96  azeotropic mixture as correctly pointed out by Keith.

Recently I had made english translation of Brazilian practical experience
in the page below  which do not bring some practical experience  of the use
of fuel blend , instead of BD , in the  Ecological system design wiki

http://ecosyseng.wetpaint.com/page/Ecological++Biofuel+%3ABrazilian+Experiencehttp://ecosyseng.wetpaint.com/page/Ecological++Biofuel+%253ABrazilian+Experience




The following is the text of Sylmar, CATI, SP Brasil

Adopted resume of the translated text from Sylmar sited origional work in
http://www.cati.sp.gov.br/_Cati2007/_produtos/SementesMudas/biodiesel.php


From May 2003 until the second half of 2005, all tractors of Core Production
of Seeds of Aguas de Santa Bárbara, CATI,SP ,BR with the jet engines direct
or indirect, one of the unit Ataliba Leonel (MF235 said previously ) came
to be moved with a mixture of vegetable oil (30%) more diesel oil (65%) and
solvent (5% of petrol common). This mixture, called a biofuel, has very
close viscosity of the oil diesel oil. A Mercedes-Benz truck, model 1313,
year 1978, was also tested, running 6,000 kilometers with a mixture biofuel.


The summary of the final results of these evaluations is transcribed below:
Tractor / Truck

* Manufacturing Year /Duration Test /Consumption average /Problems
identified *

Ford 5610 (ID) 1986 /1,000 hours 4.2 liters / hour no
MF 65x (ID) 1972 /500 hours 3.5 liters / hour no
MF 50x (II) 1972 /300 hours 2.5 liters / hour no
CBT 2105 (ID) 1978 250 hours 8.7 liters / hour no
MF 235 (II) 1978 1,000 hours 2.5 liters / hour no
Mercedes-Benz 1313 (ID) 1978 6,000 km 3.5 km / liter none

Final considerations:

- The use of 100% vegetable oil as a fuel in place of diesel oil, it is
possible to run , but also depends on appropriate technology of jet engines
and systems to prevent potential problems caused, mainly, by non-combustion
total of such oils because of high viscosity of them.

The biofuel mixture consisting of 30% of vegetable oil + 65% of diesel oil
from oil + 5% of gasoline with alcohol anhydrous (75% + 25%), used to
replace the diesel oil from oil, appears to be a very interesting option for
both direct injection engines and indirect, allowing the reduction of
dependence on non-renewable fossil fuel and opening a significant market for
the production of oil. This option must be considered and evaluated
scientifically to obtain safe and definitive conclusions. The mixture
biofuel cited in the period and the conditions in which it was tested, not
shown any of the inconveniences caused by the total replacement of diesel
oil by oil vegetable oils, in all cases evaluated. We must also highlight
that for the tractor Ford 5610, strong indications of significant reduction
of consumption were obtained during the period, which used the mixture.

- Because of the possibility of: a) production of various oilseeds in all
regions of Brazil, including in the semi-arid regions, b) obtaining and
extraction of vegetable oils by pressing the cold and filtering directly by
the severity level of rural property c) use of technology already available
in European countries that allows the direct use of vegetable oils as fuel;
feel the urgent need for that in our country, also devotes special attention
to the alternative use of renewable fuel, in addition to the others who
already are being used and encouraged, such as alcohol and biodiesel.

For more information please contact and Regional Office of Andradina e
SYLMAR , CATI ,SP, BR tel: 55 (18) 3722-3040.





The amount  much  water can be  good for   IC  motor , however the fuel
efficiency  willl be low.

The role of Biodisel is more as an additive as same as castor oil use with
hydrated ethanol , as solubility and miscibility of the only oil with
ethanoo is castor oil, also having good lubricant  additive properties .

There is problems with  blending of SVO and ethanol , as they do not mix
well.several  years experince to find cheap additive based on perfural ,
isoamyl alcohol can solve the problems  in small quantity , but are found to
be expansivos.

The max amountof SVO found  to be  maxium 50  porcents petro deiesel  , ,
other is there is problem of  viscosity.The other need to be  some fuel
diluente  petro diesel , kerosene, gasoline , alcohol and now also BD too.
   As mentioned in the following Brazilian experience and reports
   Gasoline  poved to be better than alcohol to be miixed with with SVO  as
75 porcent gasoline and 25 porcent ethanol

 However the use of BD  can make possible the  use of hyrated alcohol with
hiher level as it is surfactant  with hydrophilic and  hydrophoic  oil water
phase   miscibility , alcohol as co solvents.But as small amount as pointed
out

Re: [Biofuel] (BIOFUEL)-- Future World leader in biodiesel production , Social Technolgy and Netwok .

2007-07-18 Thread Pagandai Pannirselvam

Hi , Vivek , Keith and all the beloved list members,


   Well  and wish the  the good debate here about the  great green future
wit decentalized small biofuel project around the world

Vivek wrote

I have been reading a lot on the list since I' ve joined it a couple of
weeks back.

But could not get the information i was looking for. So i thought to write
my perspective and get every body's input on the issue.


 *Vivek , the  every one input is very important also. There used to be
very high input here for several  topics earlier , as our list was one  of
the big ,and the best  . I am sure that all  members of the list like  wish
to deeply understand the biofuel but  few only  wish  to  give input and
colaborate  about the the small scale biofuel production for the farmer of
the world. There come  the question of world  leader of exporters ? or  for
self  use ? Do not feel unhappy because some big  business sponsored
members may not give input to your questions.*


As far as my knowledge is concerned the cost of  production of biodiesel is
not competitive to the  petrodiesel and companies depend on the government
support for their profits. EU though leading the race, presently,  in  the
production of bio- diesel, but this growth is mainly on the back of
government subsidies and tax holidays. But it may be very soon when other
countries will take over EU . Primarily because raw material( rapeseed
oil) is very expensive  here.


  *There  are globalized international cost and local cost , and surely
what you mean by  the cost is dependent variable on local . Some isolated
area in Amazonian forest as well as other remote place ,  the diesel is
sold  8 time more costlier than  world globalised price. Any  who  can  help
and solve this energy problem eliminating this gap can be the world leader,
but this is not going to be  only by the big blue companies one , as  the
solar biomass energy is decentralised , need to involve .The big world
leader planning to  eliminate the small one will be not be sustainable , may
be possible for short time victory and  big profit ,but  long time  total
failure.This had been the history for the seveal bioenergy  big thermal
energy project where the peoplles are excluded and small farmar were not
included , not able to survive , as the model is not based on ecological
sustainability.

 The cooperative of small farmerfrom Indian  in west Bengal  using
Internet  can buy  Palms from Brazilian farmer cooperatives ,  simple hand
operating low cost press  made from Australia  by a small company , can
obtain  the proven best high quality  of two stage process from JTF ,Japan ,
without paying money for the the best technology , but I hope and wish they
give donation afterwards after thet  get benefits  to make JTF sustainable
),  get trained by fresh university students again based on the photos ,
step by step  easy how to make low cost equipments.They   can  find where
the market is there  nearby  them by social network  to sell  with the
low  price
to Bangladesh poor Farmer using micro credits facility as this has already
made a big world level success  for irrigation to make their food  as power
cut is not yet solved problem  there and India.. Who can be the world leader
both India , Australia  and Brazil , where  money has come for the
investments  by the community who had the social capital.Here all is leader
, but alone no one go to any where .

  For examples , even though , the cashew  big industrial processing , and
also business product marketing are in the  hand of very few  rich Brazilian
and Indian merchants  , but   I am  not sure this  will survive , after web2
, second life social revolution , I am sure no one will be leader alone  .
Many  country  can  help and make  Microsoft as the leader , which  is now
not a leader in Internet world, but wish and try to be , which  I am sure
will be never   in future  as the leader  as in the past , as  web2 and
google  is  coming over there, the web3 social net  based  face book ,
social web service  in next web3, the third life changing can will win the
the leader now but again not alone , but collective  social intelligent net
work   , as the model for the big single leader one , if not socially
justified  will not be  sustainable .Yet many rich business people  all
trying to make  Brazil as the world leader in cashew industrial  production
as the only big leader  with big automated machinery , yet  India  and South
Africa together is the world leader in future  with growing social network
of web2 , as  both  uses solar energy , small scale appropriate technology ,
surviving  now the big battle of the large company   wih the help of the
government  money .Thus making  the war of eradication of  the small scale
industries is  not good  and not just  ,but all this  go  in  the name of
modernization , nationalization  , to become world leader as if the single
world leader is the the only key issue , goal for all the 

Re: [Biofuel] home made ice cream ou home made biodeisel

2007-07-05 Thread Pagandai Pannirselvam

Hi  Kirk

  The  raw cream is not available in many areas .

   Natural ice cream is made in  India  based on the use of coconut milk in
the the place of  raw expensive cream. Ice cream can be poisonous  depending
upon the people, due to the very sensation it make , leading to food memory
in the Brain, leading people who eat crazy.In this sense , natural ice cream
can have less effect in this context , with more natural fruits , less
having more funcional nutrients and has less junk.Surely this product from
coconut can be  more competitive  compare to home made Biodiesel as  most of
the people can bebe  crazy  to this ice cream than biofuel making .
Biodeisel operated natural ice cream  production can be  the real solution
for many sea shore area  in developing country, where rich people
travelers  can  enjoy this  delicious ,making possible  real globalized
world.

   Thanking  Keith , for not put this message  as off topic ,.and also
thanking  kirk bring about a magazine  which make debate on controversial
opinion .

Yours truely
Pannir Selvam



2007/7/4, Kirk McLoren [EMAIL PROTECTED]:


By Joanne 
Hayhttp://editor.nourishedmagazine.com.au/articles/author/jojo/November 16th, 
2005
http://editor.nourishedmagazine.com.au/articles/home-made-ice-cream
Some families have the rule, eat everything on your plate or you don't
get dessert. In our family, if anyone doesn't like the dinner (as long as
they actually taste it) there's no problem because dessert is just as
nourishing as the meal. With whole raw eggs, raw cream and natural
sweetening, our ice cream is a delicious, nutritionally dense wholefood.
Since most ice cream is 
poisonoushttp://www.nourished.com.au/articles/ice-cream-lies,
I ask the kids to say no to all other forms of ice cream, and promise to
feed them this recipe til the cows come home.
We use raw cream which is very expensive, but worth it. Using real cream,
you won't need to eat much at once. A couple of tablespoons is enough to
satisfy most adults.

   - 3 egg yolks
   - maple syrup or 
rapadurahttp://www.nourished.com.au/articles/sweet-sustenance/2/to taste.
   - 1 tablespoon vanilla extract
   - 3 cups heavy cream (raw is best)
   - optional: a splash of raw milk to make a soft serve version using
   an ice cream maker.

Beat egg yolks and blend in remaining ingredients. Pour into an Ice Cream
Maker
http://www.amazon.com/exec/obidos/redirect?tag=nourisnaturah-20%26link_code=xm2%26camp=2025%26creative=165953%26path=http://www.amazon.com/gp/redirect.html%253fASIN=B000AMDNXO%2526tag=nourisnaturah-20%2526lcode=xm2%2526cID=2025%2526ccmID=165953%20and
process according to instructions. If you don't have an ice cream maker:
blend and freeze, take it out after 1 hour and beat by hand vigorously,
repeat every hour until complete (usually 5-6 hours).
Of course there are variations like, chocolate (using organic fair trade
cocoa), chocolate chip (rapadura chocolate), and adding berries or coconut.

--
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pocket:http://us.rd.yahoo.com/evt=48253/*http://mobile.yahoo.com/go?refer=1GNXICmail,
 news, photos  more.

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Re: [Biofuel] Valuable chemical from glycerol and Biofuel waste

2007-07-04 Thread Pagandai Pannirselvam

Hi, GMSEURO

 As Brazil's having  almost 46 percent of the best land that are very
good for irrigation as well as have very good water resource distributed,
the  world bio fuel  business  is  very keen on Brazilian biofuel project  ,
as this country is now world leader  about bio fuel at present. However this
position is disputed now also by USA, the future is uncertain about the same
who will  win .As the  two country business model is different, where micro
distillery of Brazil can produce  about half of the price of etanol and
Biodiesel, the small  one  is competting well with the bigger on , as  the
micro ethanol distillary  can make rapadura , animal feed , liquid
fertilizer , without problem of distribution  of these far way .The same
model is also  true for biodiesel

 Thus the  big company  can also accommodate small one.Thus we hope the
glycerine waste need to be for internal market  for local comunity as
everything is imported  in the area where  biofuel glycerine is now  mostly
lost only very less is used.

Eventhoug  these waste can be used for compost and biogas very
successfully  our research  is sure that biodegrable plastics, some
protective films for the fruits can be more viable  due  to local market.

We wish to have decentralized  market oriented products development from
glycerol waste .

 In the same direction of thinking of the most of the list members here ,
we wish the  intermediate  and social oriented technology .Any green
investments , Eco business venture for the benefit of the several farmers ,
who  are responsible for the bio fuel production are more welcome  , as the
Brazilian central government is now  giving green seal and certificate ,
financial loan independent of brazilian or foriegn investor . Any
collaboration , foreign investment are welcome .We will be happy to support
any project for the benefit for the small farmer  based on waste glycerol.

Please feel free to contact us , as this business model will have great
impact on future Bio fuel .

Thanking You

Yours sincerely
Pannirselvam







2007/7/1, GMSEURO LTD [EMAIL PROTECTED]:


*We will be interested to look at this project more carefully to make it a
into production process. Will it be possible to provide us with more
information on your exact direction on this project.

* On 27/06/07, Pagandai Pannirselvam [EMAIL PROTECTED] wrote:

  Dear list members

   A very large quantities  of liquid effluents (all acid, catalysts,
 glycerol) , after producing biodiesel are  disposed  as waste in one of the
 the big projects  which had been given social green seal  from Federal
 Government of Brazil.

 The  JTF  and this list have very extensively  given importance to this
 topic  focusing on  biogas , fuel and  soap production .
 Is any one have other biodegradable plastics, solid biofuel and simple
 polymer products  that can be produced in a decentralised , ecologically
 sustainable way for employment generation form this huge amount of
 waste.possible to make wealth for many .
 Any help in this regard are very welcome .

 sd
 Pannirselvam

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[Biofuel] Valuable chemical from glycerol and Biofuel waste

2007-06-27 Thread Pagandai Pannirselvam

Dear list members

 A very large quantities  of liquid effluents (all acid, catalysts,
glycerol) , after producing biodiesel are  disposed  as waste in one of the
the big projects  which had been given social green seal  from Federal
Government of Brazil.

The  JTF  and this list have very extensively  given importance to this
topic  focusing on  biogas , fuel and  soap production .
Is any one have other biodegradable plastics, solid biofuel and simple
polymer products  that can be produced in a decentralised , ecologically
sustainable way for employment generation form this huge amount of
waste.possible to make wealth for many .
Any help in this regard are very welcome .

sd
Pannirselvam

--
Grupo de Pesquisa em Engenharia de Custos e Processos
DEQ – Departamento de Engenharia Química
CT – Centro de Tecnologia / UFRN, Lagoa Nova – Natal/RN
Campus Universitário. CEP: 59.072-970
http://pannirbr.googlepages.com/gpecufrnhomepage

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Re: [Biofuel] New Green bio process for Bidiesel :Coconut oil in your Car without catalyst and energy:

2007-05-13 Thread Pagandai Pannirselvam

  From   Pannirselvam P.V,  Brazil

  Hi Bruno, all other TOM,KEITH list members

  Thank you very much to bring here the very simple process to make bio
fuel from coconut.

  After intensive search  I am able to see the free well made
videointerview of
Matthias Horn   German migrant and an engineer  interesting interviews. One
can see in this video how  the cocoon oil is  made  as well  how the  oil is
is stored 20 days , then used  after sedimentation , in the engine as 100
porcent , which one can get very easily via google search.All rural area
can  develope fast  as  the energy cane  made  using simple press , not even
mini oil  plant may not be needed. The simple  hand operated hydraulic press
outlined  in JTF used by us for small comunity in Brazil  to make oil  as
well the  more costlier stainless steel  two tube similar press in
Australia  all working well to make  oil from seeds in small scale
level.Thepure coconut oil has 5 times much value than  diesel fuel,
yet can very
cheap in many rural palce as  diesel is 8 times much costlier now in Brazil

Nearly 20 days are used   with water  to make the biofuel , so that the
unwanted impurities including water is decanted and  separated without
machines .

 Keith replied earlier that  simple process, catalyst can also work to make
biofuel   regarding  the  new catalyst preparation from spent biomass ash.
I  as chemical engineer , not much belief in natural ecological  process can
hardly believed this ,as not knowing well that the biological and ecological
are always low energy , simpler rather than the man made  methods , but
surely  , I do believe and agree with Keith that  this process  so simple ,
but does  not need any catalyst at all as wel as a need to heat up .
 I am sure  Matthias Horn  really do not have recourse's  and hence do not
invent the things like  what big companies do , yet  his  process need a lot
of  debate , as  understanding of the same can be the true ecological
process what we we all need as the process involve biotechnological natural
process, even there is no need to inoculate  the microbes .

 I expect Tom , Keith and  other  bring  more information .One may wonder
how 100 coconut  oil after fermentation  and separation  of impurities , is
found to be a great  success, not  mixed anything alcohol etc
Certainly some problems  may be there  due to fatty acid,glycerin , but
making job for mechanics are also good way , where everything is very
difficult.Here in Brazil , the cost of petrol diesel is  8 times more in
isolated islands.

 If we can use this biological methods  as pretreatment before we can use
the KOH liquid catalyst, we may simplify  the biofuel making process.

 Banana leaves  and stems  are reported to contains very high amount of K
and KOH can obtained from  this em plenty .

Some  small amount of water ,liquid soap , fatty acids are better components
biofuel  than oil, or petroleum , thus no need to separate if used minimum
amounts .

  This simple two stage biological and KOH process yet need to be
optimized  based on the raw material available in rural areas. Thus real
rural development is not an Utopia , can be  possible.But sharing this
knowledge all the place is yet another problem, but  our list has very good
 list members spread all   over the world.We can do better work too, even
before big blues  make huge profit by buying their oil  and ten making fuel
, selling them with huge profit  with  small farmer, who are all always  the
good market place for big blues  such as the Wallmart ,Carrefour and other

Surely the reported work is not the mad man work , but a novel new process
with perspective  for us change the way make biofuel.

Twenty years before nobody could have believed  in micro computers , even
Bill Gate  may not believed that  the open software  such as Mozilla firefox
can be success, but today they are reality making our social network can
happens. Thus , I  believe the small scale biorefinary can be  possible to
reduce the wastes , making wealth for all , naturally competing with mini
and macro refinery .Brazilian bio ethanol is the examples  where micro
distilleries do coexist with mini and macro


   Best wishes and regard

sd Pannirselvam


2007/5/9, Bruno M. [EMAIL PROTECTED]:


 This news article is about Bougainville, an Island of Papua New Guinea,
where all fuels has to be imported by ship.
So fuel is expensive, that makes coconut oil as SVO or BD quicker
economical feasible.

Gr
Bruno M.

FYI:
~~

Coconut oil powers island's cars

By Phil Mercer BBC News, Sydney

*People on the island of Bougainville in Papua New Guinea have found their

own solution to high energy prices - the humble coconut.

*They are developing mini-refineries that produce a coconut oil that can
replace diesel.
From police officers to priests, the locals are powering up their vehicles
and generators with coco-fuel.
Inquiries for the coconut power have come in from 

Re: [Biofuel] Fwd: Producing Ethanol--and Conserving the Soil

2007-04-26 Thread Pagandai Pannirselvam

Hi ,
Keith

  Thank you bringing here the very important report

Residual biomass = Food+Fiber+Feed+Fertilizer+Fuel

Brazilian sugarcane distillery  is  also exploring very well the use of a
byproduct effluent of ethanol fermentation as an organic additive to soils.
This is also an example of the
innovations very well  to support residue removal , integrated very well
with the feed  , not yet for fiber, where as the solid residues India are
used for paper production.More recycling of the solid residues incorporated
with the effluent in Brazilian sugar cane field  is more  sustainable
compared to  India, where 10 times more chemical fertilizers , and also very
significant amount of the toxic chemicals , well promoted by the very big
blue companies, are used  and thus less sustainable, thus raw very less
green technology.The inoculated  microbes  as bio fertilizer also the other
approach well applied in Brazil, thus making very sucess for the sustainable
Brazilian biofuel project.

 Thus , the natural farming  is no more  out dated , yet  the best way
.This method need more recycle of solid residues for the soil , thus the
system can be more productive and also more sustainable.Thus  the recycle
can be more easy as fertilizer rather than the fuel production .

sd
Pannir, Brasil

2007/4/25, Keith Addison [EMAIL PROTECTED]:



From: ARS News Service [EMAIL PROTECTED]
Subject: Producing Ethanol--and Conserving the Soil
Date: Wed, 25 Apr 2007 08:01:25 -0400

STORY LEAD:
In Producing Ethanol, Some Cornstalks Should be Left in the Field
___

ARS News Service
Agricultural Research Service, USDA
Don Comis, (301) 504-1625, [EMAIL PROTECTED]
April 25, 2007
--View this report online, plus photos and related stories, at
www.ars.usda.gov/is/pr
___

If conservation of soil organic matter is taken into account, the
United States at best has to cut in half the amount of cornstalks
that can be harvested to produce ethanol, according to an
Agricultural Research Service (ARS) study.

Jane Johnson, a soil scientist with the ARS North Central Soil
Conservation Research Laboratory in Morris, Minn., found that twice
as many cornstalks have to be left in the field to maintain soil
organic matter levels, compared to the amount of stalks needed only
to prevent erosion.

This doesn't mean harvesting cornstalks for cellulosic ethanol isn't
feasible--just that when you add soil organic matter concerns to
erosion concerns, it slashes the amount of cornstalks available for
conversion to ethanol. For example, 213-bushel-per-acre corn yields
leave farmers an average four tons per acre of cornstalks after
harvest. Farmers could then harvest about two tons of cornstalks per
acre for conversion to ethanol--but only from land with low erosion
risks, using little or no tillage.

If the same farmers rotate with soybeans as recommended, they can
only remove half again as much biomass for ethanol production, or
just one ton per acre, to compensate for the lower biomass left by
soybeans.

Johnson's estimates are part of the Renewable Energy Assessment
Project (REAP), formally created in 2006, although she and a core
group of colleagues have worked on these measurements for several
years prior.

REAP was formed to ensure that cellulosic ethanol programs will be
sustainable. Most participants work with corn, but others work on
switchgrass for cellulosic ethanol. When cellulosic ethanol is made
from corn, it uses cornstalks as well as grain.

There are nine ARS locations participating in REAP in eight states,
from Alabama to Indiana to Oregon.

The new program also aims to compare the economic value of biomass
for bioenergy versus its value for storing soil carbon. REAP will
provide guidelines on harvesting biomass to corn farmers, land
managers, the biomass industry and action agencies.

Johnson also explored the use of a byproduct of ethanol fermentation
as an organic additive to soils. This is an example of the
innovations needed to support residue removal.

ARS is the U.S. Department of Agriculture's chief in-house
scientific research agency.
___

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Re: [Biofuel] Biodiesel New Process

2007-04-17 Thread Pagandai Pannirselvam

   Respected  Keith

   I am sure  about the  the use of ethanol, wish to send all the
relevant work available from  Brazil so that your experiences will be reall
sucessful.


Thanking you

sd
Pannirselvam P.V



2007/4/17, Keith Addison [EMAIL PROTECTED]:


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Re: [Biofuel] Biodiesel New Process

2007-04-14 Thread Pagandai Pannirselvam

Hi, Keith, Ken and Tom

   Tom there is no for your apology, as we can have different views.

We, Acadamics , engineers , researchers  need to learn a lot from all the
people like
Keith and  Tom who are very practical  always work very  near to the process
problems.
What always happens to all the new and old engineers  who are good in
process synthesis , but   lack always
and also  very bad in critical analysis of the project with regard to
materials used, the complexity and viability.
Thus several millions money spent by university research  are all going as a
waste such as supercritical extraction for BiD good results at laboratory ,
but no use for largescale use.
The combination of practical and concepts based on the theory need to go
together in this list to evolve a better catalysts, prcoessos, equipments,
process seperations.

The reactive distillation means  doing  the  reaction together with the
distillation and I agree with Keith that, yet this
can be only research level.

  After Keith explanation about mixing by recirculation is an effective
way to  reduce the product revers reaction of glycerol , moreover , the
sediment ion  of glycerol , made possible means a better  way to filter out
the glycerol , thus preventing unwanted byproducts.

 Thus understanding of the process is vital to operate the plant.


At the beginning mixing can favour the reaction , the can be slow so that
the  product can be pulled out of reaction.


I also agree with Keith , there is no point to bother about glycerol
recovery as this can be easily used as liquid soap , sold soap , combustible
, , for bio gas production , even as the source for rural wood energy  and
hence  the high cost of recovery to get ultra purity glycerol is out of
question as far as the small scale process are concerned.


Yet  I have one  one question to Keith regarding the use of Methanol
instead of ethanol.

Will this two stage process can be possible with ethanol only or the mixture
of  methanol and ethanol can be possible as methanol is not ready avaialable
in several developing countries.

let us again wish others do participate actively in our list, as  this list
used to be very dynamic , let us come back all again to make this as leading
one .

Kind regards to all

Pannirselvam


2007/4/12, Keith Addison [EMAIL PROTECTED]:


Hi Tom, Pannir and all

Pannirselvam P.V
 My apologies to the authors of the study. My criticisms
Sounds like a poorly written science project and it doesn't seem
to make any sense sprouted from my own ignorance.
 I am doing my homework on the subject of reactive distillation.

 I must admit to a bias that may compromise my acceptance of any
new process. I like the idea of being able to make what I believe
to be high quality biodiesel, myself, on my own spot of land, using
little more than what I can scavenge from my local scrap metal dump.

I think that's the main point. It's accessible to virtually anyone
anywhere.

A new process that goes beyond the reach of an average Tom and
puts control back into the hands of big business may be new, but not
necessarily better.

It looks like an unholy marriage of the acid-base process and the
famous supercritical methanol process (Saka et al) that was getting
everyone excited a few years back - methanol at 5080 PSI and
350-400C. Um, no thankyou, I don't want big business doing that
anywhere near me, let alone backyarders. High temperature + high
pressure + lots of methanol as with this new process is likely to
kill someone, I fear.

As you said:
 The new generation biofuel is like the new wave  social web2 , the
free open  process for several  billions farmer  to be free and
independent of the big blues globalised market .This the natural way
for  green future for all , where all are included to have the
sustainable green fuel .

 You may be right when you say  ... some novel modification can
be possible to make more environmentally friendly our old two  stage
proven JFT BioD process.

I think so too, but not if it means trading in some of its many
advantages (KISS, for instance).

Thank you for your response and I look forward to discussion and
enlightenment by list members as this story unfolds.
  Best Wishes to
You,

Tom

- Original Message -
From: mailto:[EMAIL PROTECTED]Pagandai Pannirselvam
To: mailto:[EMAIL PROTECTED][EMAIL PROTECTED]
Sent: Wednesday, April 11, 2007 8:09 PM
Subject: Re: [Biofuel] Biodiesel New Process

 Dear  Cris,Thomas Kelly,Tom ,KEN ,

 From Prof Pannir,Ufrn, BRAZIL

2007/4/10, Thomas Kelly mailto:[EMAIL PROTECTED]
[EMAIL PROTECTED]:

Chris,
 I agree with you when you say
  I can't see anything new about their process and it doesn't seem
to
make any sense..



 PannirbrCertainly the  results compared to the conventional
process has merit and has more sense , as the cost of separation of
good grade  glycerol involve more than 50 percent the total cost

Re: [Biofuel] Biodiesel New Process

2007-04-11 Thread Pagandai Pannirselvam

Dear  Cris,Thomas Kelly,Tom ,KEN ,

From Prof Pannir,Ufrn, BRAZIL

2007/4/10, Thomas Kelly [EMAIL PROTECTED]:


Chris,
 I agree with you when you say
  I can't see anything new about their process and it doesn't seem to
make any sense..




PannirbrCertainly the  results compared to the conventional process
has merit and has more sense , as the cost of separation of good grade
glycerol involve more than 50 percent the total cost of the BioD
production.It  is the fact that  It reminds us to be  of a poorly written
science project as this is because the  information of the novel
technological process are  valuable   , but  the farming community  is one
who share the knowledge freely.Surely Keith know well how hard for him to
get the  new BioD process information published in JFT, but incomplete
information are always  available  and here too the same is true .However
the project has good future even for small scale production in farm scale
as very good results have been reported for the product quality of BiOD,
glycerol,recovered alcohol

The New Process appears to be the two stage acid/base process.

Stage One involves esterification of fatty acids   methyl esters.
Stage
Two is the transesterification of mono-, di-, triglycerides  methyl
esters.



Pannnir  The combined  reaction and separation known as reactive
distillation is an advanced novel innovative  system  of chemical
engineering  process engineering subjects.I  am sure that l the small scale
production in farm  can do benefit using this novel methods not as it is as
this is complex units , but can be modified if one wish to get recovery of
alcohol and glycerol


I don't know why filtration is included in each stage prior to washing.




Pannir  the product glycerol combine with ester  , making the
reverse reaction.If you can understand also the diverse  di  glycerol
byproducts  making the biofuel with less quality.The better the separation
as soon this is formed better the yield , product quality.


I'm also confused about Distilling the washed and dried Crude

Biodiesel to get Biodiesel. While it is possible to recover methanol
from
the glycerine mix and even from the unwashed biodiesel by distillation,
washing removes any excess methanol, so I can't imagine why one would
distill washed and dried BD.



 PannirbrReally we need more information and I can agree with you.
I think it is not a simple distillation , but extractive distillation to
recover back diverse  di ,tri esters formed.If you remember that this
process new , the co products need to be recovered as  the catalyst is yet
not an perfect one.

 The 30 minute reaction time referred (as an advantage of the New

Process to is only for Stage One (acid esterification). There is still a
1 -2 hour base catalyzed transesterification (Stage Two). It also claims
that there is no stirring  .   I suspect this is wrong.



Pannirbr  I think,this is possible , eventhough  not  enough
information is yet known , if one  understand well what is reactive
distillation  some patented related with the processare known one. If you
combine distillation and reaction,  the products , alcohol and  water are
separated simultaneously .Several patented process  does prove that it is
possible  to get results with out the use of  mechanical agitator's , but
thermal energy are used , which can be recovered , thus the process is
designed to be more energy  efficient

 It says that the Classic Process cannot use soy, rapeseed, palm,

coconut, sunflower, jatropa, recycled oil (WVO), or lard 
 Wrong again.



  The acid containing  oil  as well as the water content  are yet
still technical problems , as the transesterification reaction  using alkai
catalyst are  very sensitive  in terms of yield and quality .

It reminds me of a poorly written science project.


  The project has  merit surely , but have  very  poor content as they do
not wish to share the technical information. There are several innovations
especially the better quality of all the products , higher recovery , less
reaction time , more productivity , better energy  recovery less
environmental problems .But I agree with all the coments here  in the list
that this much advantage is needed for the farm scale production not worthy
considering the complexity
In this sense  our old  JFT two sage still  can be gold.Yet some novel
modification can be possible to make more environmentally friendly our old
two  stage proven JFT BioD process
We from Academic research  will always  wish to invent the process , so that
the farmer can also modify to be more productive , the better the quality of
the products totally diferent of academic one.

I wish also to get the comments  as our list has so many members from
several countries  , only very few members are involved here in recent
biofuel list discussions..The more younger list members views , our list
leader Keith  very balanced view 

Re: [Biofuel] small biodiesel plant

2007-02-06 Thread Pagandai Pannirselvam

Ola eduardo

   Temos muito empresa quem esta realizando o projeto  em pequena escala ,
tais como Erictech , Tech bio  e outros
  Bom voce veja busca em internet , muito facil vc ter acesso em insatnte .

  Nosso grupo de pesquisa pode fazer projeto preliminar e estudo de
viablidades.

sd
Pannirselvam
Brasil

2007/2/5, Eduardo Vallarino [EMAIL PROTECTED]:


Can anybody  help me find a small bio-diesel plant supplier ? Sort of a
Plant for Dummies

Also, so far the only source for Methanol is a plant in Chile. Can anybody
suggest another supplier willing to cater to a small plant ?

Eduardo
Panama

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Re: [Biofuel] new alcohol ideas

2006-10-13 Thread Pagandai Pannirselvam
Hello Jason Katie Yes , surely , glycerol can destroy the azeotropics ethanol water system , and has been proven industrial method to purify ethanol based on extractive distillation method of separation 
However the viscosity , high energy input related with cyclo hexane , this method is not that much economical in relation with preferred cyclo hexane method. There are some pataents made on the use of glycerol to recover and reuse the pure ethanol , as you believe , and this can be good approach to get pure ethanol
With regardsPannirselvam P.V2006/9/29, Jason Katie [EMAIL PROTECTED]:
i just had a bizarre idea. someone please argue with me on this, but ifglycerine is categorized as an alcohol, would it work to use castor oil topurify it, the same as ethanol? ideas?comments?JasonICQ#:154998177
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Re: [Biofuel] Sustainable Farming

2006-10-06 Thread Pagandai Pannirselvam
 Hi Mike 

 As bio fuel list has very
good people from different countries, it will be interesting to
bring the information on this sustainable integrated organic
farming here to this list .

 As sustainable biosystem development using
ecological engineering is our object , we do find lack of
information with respect to integrated fuel, food, feed , fiber and fertilizer (5F) using organic farming , some time called small bio refinery and organic farming
Thus natural , organic farming to need to integrated wit small biomass refinery too.
 In this context ,this is one reason that the
integrated approach of Keith , JTF has very good succes to be
the best biofuel site , still able to survive as the
in the globalized highly competitive Internet field as sevel new
are coming up rapidly.

Our research work involve the integrated sustainable of the
following systems by a small group in Norteast sem arid lands.

1.The hay farming system of ruminant animal production integrated with small organic food production.

2.Integrated novel aquaphonic horticulture with chicken farming.

3.Integrated fish and sprawn organic farming with earth warm biocompost .

4.Integrated biogas , micro algae , organic fish production.

5.Integrated Bio diesel , organic animal feed system 

6.Integrated small ethanol plants with organic aquaculture system .

See here some of our initial ideas about our projects : 

http://www.writely.com/View.aspx?docid=dfdhjswc_7g8rzmm

And I wish that other list members too bring some sucessful
organic system , from india , china are tradicionally
organic , can bring good information too.


 I expect Keith give some useful stories here from
Japan , so that we can follow the example to
bring here to this list the useful information in
every country about the state of art of Small
integrated dynamic bio system of organic
farming .

this can be surly ,more useful than about Bush and
USA , which I am sure are off topics , , as i am not
against the same posted here. Any excess is not good for the list .

Yous truly 
Pannirselvam P.V



Yours truely 




2006/9/29, MIKE BODAK [EMAIL PROTECTED]:

I am sending a request to the list. I cannot seem to find this on thewebsite.Maybe, this was something someone (Keith perhaps) had writtenoff the top of their heads, but I cannot find the information.I have

been planning an organic farm / homestead for some time now and have comea little closer by making arrangements to purchase 75 acres in the nearfuture.I have also been trying to spread the word of organics and their
possibilities and would like the information for that.Anyway, someonewrote a piece that discussed the growing of alfalfa, growing rabbits, andplanting a garden and the ability to do this harmoniously and have excess.
 The piece also discussed how it could be expanded to chickens, ducks,fish, cows, etc...A link to the info or article would be appreciated.Thanks,Mike BodakMike BodakExhibits Technician

Arizona Science Center 600 East WashingtonPhoenix, Arizona 85004602-716-2570HANDS-ON, EYE-OPENING FUN
www.azscience.org__
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Re: [Biofuel] From the BBC -- Biofuels: Green fuel, feed, fertilizer , feed

2006-09-25 Thread Pagandai Pannirselvam
Dear Tom , Jason and Keith  Clean technology using no waste from crop can be more sustainable providing not only bfuel , but also feed , food in rural areas.  Tom has correctly brought here how we can do this for many crops 
The bio refinery can separate oil , carbohydrate , and starch which using simultaneous malt enzyme hydrolysis and fermentaion can give the etanol in rural raes, ,The yeast byproducts from animal as well the proteins from oil crop can be good feed for for sustainable animal production manure micro alge fish production based on the effluents and biofertizer based on well estabilized biogas technology.
The small co generation of electrical energy based on the bio diesel can make possible the use of pure used vegetable oil and also some e 5 porcent hydrated ethanol , making possible to lower the viscosity of used vegetable oil in deiesel engine , removing dependence with Conventional deisel.
Thus the blend of used vegetable oil 70 percent, hyrated ethanol 10 percent and biodeisel 20 porcent can be used with less problem for motor maintainence in rural areas. The sixty porcent energy recovery from small cale cogeneration can be used for distillation of the etananol and heating for thr production of the biodeisel 
Some energy recovery can be made also during anaerobic or anaerobic compostings.I am sure biofuel can make sustainable economic growth only if they look for the independence of small remote areas from imported food and fuel .
Tom has very well desribed this interated biofuel prouction together so taht waste to get energy from biomass need  systematic approach fo the whole integrated use of natural resource to economically viable and ecologicaly sustianable , socially desired
 To make possivel biofuel and this biorefinary one as small as possible and make this information via JTF are the journey for the great green future of not only for the the biofuel , but also the only way possible several millions people who stive live without energy especially in poor countries.
2006/9/24, Thomas Kelly [EMAIL PROTECTED]:







Jason,
 When you say
 as for using fossil fuels 
to harvest ethanol crops, i would say it is a nessecary evil until the 
harvesting equipment can be fueled entirely by alternatives.

I wince a bit. 
 Why not run the tractors 
on alternative fuels?

 The cost of alternative 
fuels such as BD and ethanol, includes the fertilizers used to produce the 
feedstocks, the fuel used to run the tractors for tilling, planting, harvesting, 
the energy is processing/distilling, anf the cost of transportingand 
distributing the fuel.
 The cost is often based on 
the mistaken notion that the BD produced OR the ethanol distilled is the only 
valuable product of the harvest. I compare this to raising beef cattle only for 
rib eye steaks, or chickens only for theirwings, and throwing the rest out 
(paying to have it disposed of). If this were the case then the cost rib eye 
steaks and chicken wings would be prohibitive (even more 
prohibitive?)
 What if:
1.  Vegetable oils were 
extracted and used for cooking, then recycled and, with animal fats - BD 
to run the tractors/distill the ethanol, or use the WVO directly to run 
generators/burn in oil-fired burners to distill ethanol.
 2. The remaining starch from the plant 
after pressing for oil was fermented and distilled (w/o using fossil 
fuels).
 3. Stems, leaves, roots 
silage for grazing animals enriched by the protein that remains in 
the feedstock after it has been pressed for oil and fermented for 
ethanol.
 4. Use biogas (methane) from the 
animal manure to run generators, tractors, or burned for heat (including 
distillation).
 5. Methane gas (biogas) 
production does not compromise the value of manure as fertilizer. Use the manure 
for fertilizer after methane gas has been produced.
 6. Recycle the glycerin 
cocktail produced during BD production. If split w. phosphoric acid, the 
excess KOH in the mix forms potassium phosphate a valuable fertilizer that could 
be added to the manure. If split w. sulfuric acid the KOH forms potassium 
sulfate (Nitrogen in the manure + Potassium, Phosphorus, and Sulfur from process 
are the big 4 in fertilizer. The manure already contains the 
micronutrients).
 After recovering excess 
methanol, the glycerin from the mix not only composts well, but I've found that 
it actually stimulates decomposition.
 7. Do this onlocally to minimize 
transport costs/waste.

 I've been told that little 
is wasted in processing butchered animals. This mentality might be applied to 
our crops. A given crop might one day be viewed as part food and part 
fuels.

 I'll leave it toyou 
to factor in the cost tax payers already pay for fossil fuel subsidies, and what 
we all payfor health care, property damage, human suffering due 
to air pollution. What is the cost in tax dollars, insurance premiums  
human suffering for the disasters that global warming brings? Feel free to add 
other hidden costs associated 

Re: [Biofuel] diesel tree

2006-09-25 Thread Pagandai Pannirselvam
Hi Keith and Peter  Brasil is big country .we are in the norteast , the amozonian forest is inthe north about 4-5 hours air travel from our place.The seed of the native plants can be easily obtained as there are several natural products small business is there in several forest areas.
 The amazonian copia oil is avialble as , the medicnal value of this plant is well in the regioes.  As this natural seed coolection can really help the very poor people in the very lees deveoped are , we wish to help any one inthe list to get the seeds.
 Thanking to bringing very viable alternative biofuel plants that can make better life for many . This is how we can make use of the natural selection 2006/9/24, Keith Addison 
[EMAIL PROTECTED]:Hi Peter
Thanks for the updater and the url, by the way, very interesting!Why don't you post it onlist?Hi Keith ;Anyone know where to order seeds?BRPeter G.Thailand
No. Pannirselvam might know, or other Brazilian list members.Or try ECHO, maybe.http://echonet.org/ECHO: Networking Global Hunger SolutionsSeeds from around the world (marked excellent):
http://www.seedman.com/2006 Exotic Plant and Garden Seed CatalogThese from JtF's seeds page:SeedSaving Resources -- This comprehensive site is a one-stop-shop
of Web resources on plant genetic resources, seedsaving and seedswapping, and worldwide sources of organic, heirloom, open-pollinatedand non-GE seed and plants.
http://homepage.tinet.ie/~merlyn/seedsaving.htmlSeed Saving ResourcesThe Seed Exchange email list has nearly 700 members from around theworld, including university agriculture departments and research
stations. Moderated list, no advertising, members' email informationkept totally private. To subscribe send a blank email to:[EMAIL PROTECTED] with the word SUBSCRIBE as the subject of the
message.Maybe more information here:Lost Crops of the Incas: Little-Known Plants of the Andes withPromise for Worldwide Cultivation Board on Science and Technologyfor International Development, National Research Council, 1989, ISBN
0-309-04264-X.Detailed information on more than 30 different Incan crops thatpromise to follow the potato's lead and become important contributorsto the world's food supply. Some of these overlooked foods offer
special advantages for developing nations, such as high nutritionalquality and excellent yields. Color photographs of many of the cropsplus the authors' experiences in growing, tasting, and preparing themin different ways. Full text online at the National Academic Press:
http://www.nap.edu/catalog/1398.html(Anyone) let us know how you get along.All bestKeith___
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[Biofuel] Biofuel tree

2006-09-25 Thread Pagandai Pannirselvam
Hi Keith and Peter  Brazil is a very big country ,we are in the
Northeast , the Amazonian forest is in the north about 4-5 hours air
travel from our place.The seed of the native plants can be
easily obtained as there are several natural products small business
is there in several forest areas.
 The amazonian copaiba oil is available as , the medicinal value of this plant is well in the regioes. 
As this natural seed collection can really help the very poor people in
the very lees developed are , we wish to help any one in the list to
get the seeds.
 Thanking to bringing very viable alternative bio fuel plants that can make better life for many . This is how we can make use of the natural selection sdPannirselvam
-- Grupo de Pesquisa em Engenharia de Custos e ProcessosDEQ – Departamento de Engenharia QuímicaCT – Centro de Tecnologia / UFRN, Lagoa Nova – Natal/RNCampus Universitário. CEP: 59.072-970
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Re: [Biofuel] 2 new additions

2006-09-23 Thread Pagandai Pannirselvam
Ola Jason e Katie 


 Happy welcome to the new baby and wish the child to have better world than what we live.
 2006/9/23, Jason Katie [EMAIL PROTECTED]:
correction- 20:42 and 20:45JasonICQ#:154998177MSN:[EMAIL PROTECTED]- Original Message -From: Jason Katie 
[EMAIL PROTECTED]To: Biofuel@sustainablelists.orgSent: Friday, September 22, 2006 11:52 PMSubject: [Biofuel] 2 new additionsi have some fantastic news this week.
 on sunday, september 17th at 16:42 and 16:45 my small (yet excessively loud) twin sons Ryken and Xavier were born. katie is healthy, albeit tired, and the boys are on a steady track to coming home next week. (theyre in the
 nursery until they can regulate their own body temperatures) Jason ICQ#:154998177 MSN:[EMAIL PROTECTED] --
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Re: [Biofuel] ENZYMES

2006-09-07 Thread Pagandai Pannirselvam
Hi Juan e Javier 2006/9/4, CARVAJAL BARRIGA ENRIQUE JAVIER [EMAIL PROTECTED]:
Thanks Juan:I will be asking for enzymes and also I will try to use some fungus tohydrolysate the substrate.   I have done my Phd thesis making cellulase enzyme  using Fungus Trichoderma Verde ,  during 1977 and 1983, the best especie selected by very famous researcher Mary Mandel , US Natic Army research laboratory who is very kind to send the same for several resarch institute to all the world 
and latter renamed as Trichoderma ResseiI am not sure about the efficiency of using fungus, because I think they
are hydrolysating the woods for their own metabolism, and probably itwill diminish the amount of sugars to be converted into ethanol.  It is not practical one, eventhough can be used as pretreatmento for delignication before using enzymatic hydrolysis
 During fermentation , the operating conditions for the cell growth for extraceluar enzyme growth need to me maintained and this is not the ideal one for the enzymatic hydrolysis. Moreover the sugar will be consumed for the cell growth .
 The crude culture can be used with out the need for purification and concentration of the enzymes. The reuse of enzymes are possible using new substrates , making possible the reduced consumption. 
However the pretreatment need to be realized, as any impurities of the substarte can be inhibits enzymes.We can send useful information to any one of our group.Keith, has already longe before told me to write about ethanol from cellulose and some very useful information have been also available as post in this list 
sdPanniselvam  In thisaspect, probably the use of purified enzymes increases the yield of
ethanol and, also may reduce the time of hydrolysis.I'd like to know your opinion on that respect.
Kind regards,Javier-Mensaje original-De: [EMAIL PROTECTED][mailto:
[EMAIL PROTECTED]] En nombre de Juan BovedaEnviado el: Viernes, 25 de Agosto de 2006 15:19Para: 'biofuel@sustainablelists.org'Asunto: Re: [Biofuel] ENZYMES
Hola Javier.Check with your local industrial washing operators of stone washed denimjeans.Many of them might use stones and celullase. They might tell you thesupplier of those cellulases usually they are many times cheaper than
chemical reagents suppliers.There are some brands of hemicellulase and cellulase some are providedbyNovo from Denmark or from others companies.The cellulases are external enzymes from many sources, mainly from
fungalorigin and some you might find in your backyard, some good ones forlignocellulose are Pleurotus sp.some used in oriental dishes andothersfound in the white decay of woods, they might be cultivated immersed in
agitated liquid media with wood pulp and some others nutrients similarto adiluted fertiliser plus some yeast extract with a clean air pumpedinsidethe liquid.Best Regards.Juan-Mensaje original-
De: CARVAJAL BARRIGA ENRIQUE JAVIER [SMTP:[EMAIL PROTECTED]]Enviado el: viernes 25 de agosto de 2006 10:42Para: 
biofuel@sustainablelists.orgAsunto: [Biofuel] ENZYMESTo anyone who can help indicating me where can I find the appropriateenzymes to totally or partially hydrolysate lygnocellulosic materialsuch as spent grain from breweries to become fermentable sugars looking
to further bioethanol attainment. And also If anyone is involved in asimilar project to exchange experiences.Many thanks,Javier Carvajal Information from NOD32 
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Re: [Biofuel] Ethanol use

2006-08-23 Thread Pagandai Pannirselvam
 Hi Charles  There is a patented information about using the zeolites at the top of the reactor , which can be very selective to adsorb and return back pure alcohol see google search using free patent site.
Then you can recover the catalyst using solar energy to remove water.In the case of ethanol , the higher temperature , I am not sure that higher can fovour the reaction.Can any one have the experience to give more informatiion?
With kind regars to all biofuel members yours truelyPannirselvam P.V2006/8/21, Charles List [EMAIL PROTECTED]
:Hi allIt's slowly turning to spring down here in the southern hemisphere,
and a young man's thoughts turn to what he's going to get up to inthose long summer evenings. Me, I think only of biofuel! I am havinggood progress and results with methanol but my long term plan is tobe completely self- sufficient and ferment my own ethanol to use in
my reaction. I will first buy some denatured ethanol to practice on,and I have read what is on the JtF web-site and realise I will needto really dewater my oil, use more ethanol than methanol etc. I wouldlike to know, however, if I can increase the temperature of the
reaction mixture to cut down the time taken for the reaction asethanol boils at 78C rather than 65C, and if there are any otherhints/ tips people can give through their experience of this reaction.Thanks
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Re: [biofuel] Methane Digestor

2002-11-25 Thread Pagandai Pannirselvam

   Yes we have experience in Brasil

 --- Jack Kenworthy [EMAIL PROTECTED]
escreveu:Hello,
 We have a constructed wetland at our school that
 processes our sewage from roughly 70 people.  The
 system has a settling tank where solids are
 seperated out before sending the fluid waste into
 the wetland gardens.  Every year or so, the solids
 build up and need to be pumped out.  I am wondering
 if anyone knows if there is a way to build a
 digestor to be able to extract methane from the
 solid waste?  I have seen systems in Cuba using cow
 manure, but never with human waste.  Any ideas?
 thanks,
 jk
 Jack Kenworthy
 Sustainable Systems Director
 The Cape Eleuthera Island School
 242-359-7625 ph. 242-359-7697 fax
 www.islandschool.org
 
 
 [Non-text portions of this message have been
 removed]
 
 
  

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Dr.PAGANDAI.V.PANNIRSELVAM  Email: [EMAIL PROTECTED] / [EMAIL PROTECTED]
COORDINATOR RESEARCH BASE   Phone: 55 84 2153769 or 217 1557 - 207.7278
UFRN/CENTRO DE TECNOLOGIA   Fax  : 55 84 2153770 or Fax(phone) 217.1557
Chemical EngineeringCEP  : 59.072-970  
CAMPUS - UFRN/NATAL/RN  Brazil
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Re: [biofuel] biofuel progress in india

2002-11-18 Thread Pagandai Pannirselvam

hi
   We from brasil is also have good progress , we can
exchange the information.

sd
Pannirselvam


 --- Suraj Vinay [EMAIL PROTECTED] escreveu: 
Hi, I think this project is in its embryonic stage
 in INDIA so if 
 anyone can guide me into converting or using
 bio-fuel engines it 
 would be a step in progress in INDIA. If you havvent
 beeen here then 
 you will not know the vehicular congestion has
 created a zone for 
 diesel emissions and dark smoke on to the ecosystem
 . I think with 
 its large vehicular population especially deisel
 ones, we can profit 
 as well as progress in the right direction if on a
 semi large scale 
 we can bring out some kind of progress here. 
 Thank you
 SUraj VInay Mohan
 
 
  

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COORDINATOR RESEARCH BASE   Phone: 55 84 2153769 or 217 1557 - 207.7278
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Chemical EngineeringCEP  : 59.072-970  
CAMPUS - UFRN/NATAL/RN  Brazil
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