Re: [Biofuel] Iodine value, polymerisation and oxidation

2005-08-22 Thread Jan Warnqvist
Marc,
it is true that the trans-esterification process will partly eliminate the
polymerization properties of highly unsaturated fatty acids.How did you
establish the iodine number ?
What kind of oil as raw material are you talking about ?
But there are still some things to attend to:
Highly unsaturated fatty acids can be quite aggressive to the material in
the fuel system. If you want to play it a little safer, mix the BD with BD
of a more saturated oil.
Jan Warnqvist
AGERATEC AB

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- Original Message - 
From: Marc Arends [EMAIL PROTECTED]
To: [EMAIL PROTECTED]
Sent: Sunday, August 21, 2005 8:06 PM
Subject: [Biofuel] Iodine value, polymerisation and oxidation


 Hello,

 My WVO consist of 80% polyunsaturated oil and i calculated that this has
an
 iodine value of 150. But when i look at the table  National standards for
 biodiesel,  found here
 http://journeytoforever.org/biodiesel_yield2.html#biodstds

 you  see the iodine value of BD should be on avarage less then 120. Which
 makes my BD not suitable for my car cause the BD will undergo
 polymerisation.

 You also read on the webpage that oil with a iodine number above 50 will
 damage your car. Found here
 http://journeytoforever.org/biodiesel_yield.html.

 On the other hand i red this article stating that Trans-esterifying
 triglyceride oils and fats with monohydric alcohols to form biodiesel
 largely eliminates the tendency of the oils and fats to undergo
 polymerisation and auto-oxidation and also reduces the viscosity of the
oil
 to about the same as petroleum diesel.

 Found here http://www.shortcircuit.com.au/warfa/paper/paper.htm

 My idea was to mix my high polyunsaturated BD with mineral diesel until
it
 does no demage to my car, but i now i don't know how much of each i should
 use.

 Can anyone help me please, i am very confused.

 Greetings,

 Marc



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[Biofuel] Iodine value, polymerisation and oxidation

2005-08-21 Thread Marc Arends
Hello,

My WVO consist of 80% polyunsaturated oil and i calculated that this has an 
iodine value of 150. But when i look at the table  National standards for 
biodiesel,  found here 
http://journeytoforever.org/biodiesel_yield2.html#biodstds

you  see the iodine value of BD should be on avarage less then 120. Which 
makes my BD not suitable for my car cause the BD will undergo 
polymerisation.

You also read on the webpage that oil with a iodine number above 50 will 
damage your car. Found here
http://journeytoforever.org/biodiesel_yield.html.

On the other hand i red this article stating that Trans-esterifying 
triglyceride oils and fats with monohydric alcohols to form biodiesel 
largely eliminates the tendency of the oils and fats to undergo 
polymerisation and auto-oxidation and also reduces the viscosity of the oil 
to about the same as petroleum diesel.

Found here http://www.shortcircuit.com.au/warfa/paper/paper.htm

My idea was to mix my high polyunsaturated BD with mineral diesel until it 
does no demage to my car, but i now i don't know how much of each i should 
use.

Can anyone help me please, i am very confused.

Greetings,

Marc



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