-Caveat Lector-

http://www.fluoridealert.org/f-arsenic.htm

How Much Arsenic is Fluoridation Adding to the Public Water Supply?

pull-quotes:

Arsenic levels in fluoridation chemicals:

Over 90% of the fluoride which is used to fluoridate water is an industrial
waste product from the phosphate fertilizer industry. Being an industrial
waste product, these fluoridation chemicals (hydrofluosilicic acid & sodium
silicofluorides) contain a number of impurities, most notably of which is
arsenic.

...The problem with arsenic contamination of fluoridation chemicals has
recently been recognized by the American Water Works Association. According
to the October 2000 issue of the AWWA's Journal, "about 90 percent of the
arsenic...contributed by treatment chemicals is attributable to fluoride
addition."
----------
Fluoride Action Network

October 24, 2000

How Much Arsenic is Fluoridation Adding to the Public Water Supply?
by Michael Connett

Ninety percent of the fluoride we use to fluoridate U.S. water systems comes
directly from the pollution scrubbing systems of the phosphate fertilizer
industry. Recently, there has been a lot of concern amongst clean water
activists about the purity of this industrial grade fluoride, known as
hydrofluosilicic acid. As investigative journalist George Glasser has pointed
out, this hydrofluosilicic acid contains trace amounts of numerous heavy
metals such as lead, mercury, and arsenic.

Proponents of fluoridation, however, claim that while heavy metals are found
in the acid, they are at such low levels as to be of no concern. As Thomas
Reeves of the Centers for Disease Control and Prevention recently stated,
“the point I’m trying to make is it’s really not a problem” (Wenatchee
World, October 20, 2000).

After a quick look at the numbers, Reeves would seem to be right. After all,
the hydrofluosilicic acid is diluted down approximately 240,000 times when
added into the public’s drinking water. If, therefore, these heavy metals are
in concentrations of parts per million in the undiluted fluorosilicic acid,
they will be much lower after being diluted down 240,000 to 1.

However, while this argument sounds legitimate, a careful look at the numbers
reveals a different picture.

Take for instance, arsenic.

In a recent letter (July 7, 2000) to Congress, NSF International (National
Sanitation Foundation) submitted the results of tests it has conducted on
hydrofluosilicic acid over the past few years. According to the NSF, the most
common contaminant found was arsenic. (Arsenic was found about 5 times more
frequently than any other contaminant and at considerably higher levels).

While not all hydrofluosilicic acid was found to contain arsenic, the NSF
states that where found, the average level of arsenic in the acid would lead
to arsenic levels in water, after dilution, of 0.43 parts per billion (ppb).
(When the "non-detects" are factored in, the average arsenic level would be
0.1 ppb; see http://www.fluoridealert.org/NSF-letter.pdf ). The maximum
levels of arsenic found by the NSF would result in arsenic levels in water of
1.66 parts per billion.

Putting the numbers into Perspective

To the ordinary person, these numbers seem small and insignificant, which is
exactly what the NSF and the CDC’s Thomas Reeves claim. However, in examining
their arguments, one finds that the NSF and Reeves are basing their reasoning
on the fact that 0.43 parts per billion arsenic falls below the EPA’s Maximum
Contaminant Level (MCL). In other words, they are looking to the letter of
the law, and the letter of the law says adding this much arsenic to the water
is ok.

But the letter of the law on arsenic is currently under serious challenge.

According to a 1999 review done by the National Academy of Sciences, “it is
the subcommittee’s consensus that the current EPA MCL for arsenic in drinking
water of 50 µg/L (50 parts per billion) does not achieve EPA’s goal for
public-health protection and, therefore, requires downward revision as
promptly as possible.”

The Natural Resources Defense Council (NRDC) states that the EPA’s current
Maximum Contaminant Level for arsenic, “is grossly inadequate for protecting
public health.” The NRDC points out that the EPA’s Maximum Contaminant Level
was set in 1942, “before arsenic was known to cause cancer.” Arsenic, which
has since been classified as a Class 1 human carcinogen, is now known to
cause cancer of the skin, and cancer of the internal organs, particularly the
lung and bladder.

In light of the growing accumulation of scientific literature on arsenic, the
NRDC is currently calling on the EPA to set a new Maximum Contaminant Level
for arsenic at 3 parts per billion. However, the NRDC argues that even 3
parts per billion is not a satisfactory level. For as they state, “Based on
an extrapolation of NAS's risk estimates, even a relatively strict arsenic
standard of 3 ppb could pose a fatal cancer risk several times higher than
EPA has traditionally accepted in drinking water.”

In fact, based on risk estimates from the National Academy of Sciences, just
0.5 parts per billion arsenic in the water “presents the highest cancer risk
EPA traditionally allows in tap water” (see chart 1 below) (NRDC, 2000).
Using NAS data, and assuming a linear dose response, the Natural Resources
Defense Council estimates that drinking water containing just 0.5 parts per
billion presents the public with a 1 in 10,000 risk of developing cancer.

Recent epidemiological work from Finland (Kurttio, et. al, 1999) found that
people drinking water with 0.1 to 0.5 parts per billion arsenic, had an
approximately 50 percent greater risk of getting bladder cancer than their
countrymen drinking water with arsenic levels less than 0.1 parts per billion
(NRDC, 2000). The range 0.1 to 0.5 ppb is the range of arsenic we can expect
to add to the water from the use of hydrofluosilicic acid.

In conclusion: What do we know?

* 90% of the fluoride used to fluoridate US water systems comes from the
pollution scrubbing devices of the phosphate fertilizer industry. It is
industrial grade, not pharmaceutical grade.

* The most common contaminant found with the captured fluoride acid
(hydrofluosilicic acid) is arsenic.

* When detected, the average amount of arsenic found in the acid would lead
to levels of arsenic in drinking water of 0.43 parts per billion.

* If we include the samples that did not contain arsenic, the average amount
of arsenic fluoridation is adding to the water would be 0.1 ppb.

* The level of arsenic in hydrofluosilicic acid varies, reaching levels high
enough to produce concentrations of 1.66 parts per billion in water.

* According to risk estimates from the National Academy of Sciences, water
containing 0.5 parts per billion arsenic presents a 1 in 10,000 risk of
developing cancer.

* A study from Finland (Kurttio, et al, 1999) found that people drinking
water with 0.1 to 0.5 parts per billion arsenic had a 50% greater risk of
developing bladder cancer than people drinking water with less than 0.1 ppb.


------------------------------------------------------------------------------

--

Chart 1: Lifetime Risks of Dying of Cancer from Arsenic in Tap Water
Based upon the National Academy of Sciences' 1999 Risk Estimates*

>From the Natural Resource Defense Council's February 2000 Report "Arsenic &
Old Laws"

Arsenic Level in Tap Water
(in parts per billion, or ppb) Approximate Total Cancer Risk
(assuming 2 liters consumed/day)
0.5 ppb 1 in 10,000
(highest cancer risk EPA usually allows in tap water)
1 ppb 1 in 5,000
3 ppb 1 in 1,667
4 ppb 1 in 1,250
5 ppb 1 in 1,000
10 ppb 1 in 500
20 ppb 1 in 250
25 ppb 1 in 200
50 ppb 1 in 100
*See note 3 at http://www.nrdc.org/water/drinking/arsenic/chap3.asp for
details on how the NRDC calculated total cancer risk based on an
extrapolation of NAS's risk estimates, which assumed a linear dose-response
and no threshold.
------------------------------------------------------------------------------

--
References:

Gilstrap, Kathleen. (2000). Fluoride battle heats up: Vote is non-binding,
but that won't make this election any less volatile. Wenatchee World. 20
October 2000.

Kuttrio P, et al. (1999). Arsenic Concentrations in Well Water and Risk of
Bladder and Kidney Cancer in Finland. Environ. Health Perspect. 107:705-710.

Natural Resources Defense Council. (2000). Arsenic and Old Laws: A Scientific
and Public Health Analysis of Arsenic Occurrence in Drinking Water, Its
Health Effects, and EPA's Outdated Arsenic Tap Water Standard.
http://www.nrdc.org/water/drinking/arsenic/aolinx.asp

Executive Summary and Recommendations
Chapter 1: Arsenic Found at Levels of Concern in the Tap Water of Tens Of
Millions of Americans in 25 States
Chapter 2: An Overview of the Scientific and Health Issues Raised by Arsenic
Regulation
Chapter 3: Conclusions for Safe Regulation of Drinking Water
Bibliography
Hazan, Stan (2000). Letter to Florida Department of Health from Stan Hazan,
General Manager, Drinking Water Additives Certification Program, National
Sanitation Foundation International. 24 April 2000.
http://www.fluoridealert.org/NSF-Letter.pdf

Hazan, Stan. (2000). Letter to Rep. Ken Calvert from Stan Hazan, General
Manager, Drinking Water Additives Certification Program, National Sanitation
Foundation International. 7 July 2000.
http://www.citizens.org/Food_Water_Safety/Fluoridation/Materials/NSF_response.

pdf
------------------------------------------------------------------------------

--
A Note about Current Levels of Arsenic in US Water Systems

According to analysis of water conducted in 25 US states, approximately 70%
of the tap water tested was found to contain between 0 (non-detectable) to 3
parts per billion arsenic (see
http://www.nrdc.org/water/drinking/arsenic/chap1.asp).
------------------------------------------------------------------------------

--

ADDENDUM:

According to an article ("Treatment Chemicals Contribute to Arsenic Levels" )
in the October 2000 issue of the Journal of the American Water Works
Association ("Opflow"):

"Utilities should review and estimate the maximum possible arsenic
concentrations contributed by the chemicals they use in drinking water
treatment.  Even trace amounts add up and may contribute to a substantial
portion -- possibly up to 10 percent -- of a 3 or 5 [ppb] maximum contaminant
level." - (C. Wang, D.B. Smith, G.M. Huntly, "Treatment Chemicals contribute
to Arsenic Levels," Opflow (AWWA), October 2000.)
"90 percent of the arsenic that would be contributed by treatment chemicals
is attributable to fluoride addition." (C. Wang, D.B. Smith, G.M. Huntly,
"Treatment Chemicals contribute to Arsenic Levels," Opflow (AWWA), October
2000.)
------------------------------------------------------------------------------

--

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