http://enn.com/news/enn-stories/2001/11/11272001/air_45660.asp
- 11/27/2001 - ENN.com
Clean air catalytic converters emit platinum pollutants

Tuesday, November 27, 2001

By Environmental News Network

Catalytic converter

The devices on cars that keep polluting emissions from reaching the 
air are spewing out other potentially toxic substances that are 
building up along U.S. roads. The culprits are catalytic converters.

Mark Schneegurt, an assistant professor in biological sciences at 
Wichita State University, and a four person team from the University 
of Notre Dame have conducted one of the most comprehensive U.S. 
studies of roadside contamination by catalytic converters. Their 
study was published in a recent issue of the American Chemical 
Society's journal "Environmental Science & Technology."

Catalytic converters have been used on U.S. cars since 1978 to turn 
toxic pollutants such as carbon monoxide and hydrocarbons into less 
harmful emissions through chemical reactions. The material used to 
speed up those reactions is filled with platinum, palladium and 
rhodium, known collectively as platinum-group elements or PGEs.

Platinum group metals have been dubbed the noble metals because of 
their high resistance to oxidation and corrosion.

These platinum-group elements are emitted as microscopic particles 
from a vehicle's tailpipe. The level and rate of PGE release vary 
according to how fast a vehicle is travelling and the type of engine 
that powers that particular vehicle.

Enough platinum-group elements are being throw off from vehicles with 
catalytic converters that they are building up to potentially harmful 
levels along roadsides as far as 55 yards from the roads, the study 
showed.

The researchers collected soil samples from urban roads and side 
streets in and around South Bend, Indiana, where Notre Dame is 
located. They also went to several sites along Interstate 80 between 
South Bend and Chicago, collecting roadside samples and soil samples 
at distances 16, 32 and 160 feet from the roadway.

"There's so much of it that it's almost worth it to mine the top inch 
of roadside dust" for the three elements, said Schneegurt.

Platinum is highly allergenic. If people are consistently exposed to 
certain allergens at even low levels they can develop allergies that 
can lead to asthma, or they can experience other symptoms such as 
sensitive skin. Not enough research has been done on palladium and 
rhodium to determine how harmful they are, Schneegurt said.

PGE buildup could lead to other problems, considering a number of 
U.S. roads cut through agricultural areas, Schneegurt notes. It is 
not known if these elements are getting into groundwater supplies or 
the wildlife and human food chains.

There is the potential for even more platinum-group elements to be 
emitted and in place far removed from highways. Catalytic converters 
must be attached to small gas engines such as those on lawn mowers 
and chain saws, according to the Clean Air Act of 1990.

Schneegurt hopes the study will cause manufacturers to consider 
making changes to the converters. "Catalytic converters do far more 
good than harm, but we don't want to replace one problem with 
another," he said.

Copyright 2001, Environmental News Network

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