[biofuels-biz] California Senate oks emissions bill targeting SUVs

2002-05-07 Thread Keith Addison

http://www.planetark.org/dailynewsstory.cfm/newsid/15809/story.htm
Planet Ark :
California Senate oks emissions bill targeting SUVs

USA: May 6, 2002

SACRAMENTO - California's state Senate approved a controversial bill 
to limit greenhouse gas emissions, a measure automakers say is aimed 
at choking off sales of sport utility vehicles through tighter fuel 
economy standards.

Gov. Gray Davis has not taken a position on the bill, which is 
strongly opposed by the auto industry. Officials in his office said 
the Democratic governor was working with the bill's author, 
Democratic Assemblymember Fran Pavley, seeking to make it more 
palatable to all parties concerned.

The proposal has been attacked by representatives of the automotive 
industry, who have called it a driving tax intended to drive a 
wedge between Californians and their beloved SUVs - a big source of 
greenhouse gas emissions.

Some 47 percent of passenger vehicles sold in the nation's 
most-populous state are SUVs, minivans or light trucks, a percentage 
that has tripled over the last 30 years.

The Senate passed the bill, AB1058, by a vote of 22-13. It now 
returns for a concurrence vote in the Assembly, which first passed 
the measure in January.

The bill would require the state's Air Resources Board to adopt 
regulations that would achieve the maximum feasible reduction in 
emissions of greenhouse gases, including carbon dioxide (CO2), 
emitted by cars and light-duty trucks, the category that includes 
SUVs.

The regulations, which should be completed by 2005, would not take 
effect until at least Jan. 1, 2006. An amended version of the bill 
would give automakers until 2009 to come up with technological 
changes or modifications to comply with the new standards.

Because California's Air Resources Board was established before the 
U.S. Environmental Protection Agency was formed under the Clean Air 
Act of 1970, California is unique in its ability to impose air 
quality standards independent of federal regulation.

The federal government last month rejected a proposed 50-percent 
boost in fuel-efficiency for gas-guzzling cars and SUVs. Existing 
federal Corporate Average Fuel Economy standards require passenger 
cars to average 27.5 miles per gallon, while SUVs, along with 
mini-vans and other vehicles in the light truck category, need only 
achieve 20.7 mpg.

REUTERS NEWS SERVICE


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[biofuels-biz] FTC says it is turning ADM ethanol price probe over to DOJ

2002-05-07 Thread Keith Addison

http://enn.com/news/wire-stories/2002/05/05072002/reu_47136.asp
- 5/7/2002 - ENN.com
FTC says it is turning ADM ethanol price probe over to DOJ

Tuesday, May 07, 2002

By Soo Youn, Reuters

NEW YORK - U.S. trade regulators said on Monday they will send a 
price-fixing investigation of Archer Daniels Midland and other 
producers of the gasoline additive ethanol to the Department of 
Justice, in a sign the case could turn into a criminal probe.

After reviewing these materials, staff of the FTC's Bureau of 
Competition has transmitted them to the Antitrust Division of the 
Department of Justice, the Federal Trade Commission's General 
Counsel William Kovacic wrote in a letter to Doug Ose, the head of 
the House Subcommittee on Energy Policy, Natural Resources and 
Regulatory Affairs.

Late last month, Ose, a California Republican, introduced internal 
memoranda by ADM and other ethanol producers indicating collusion to 
set prices for alcohol originating from surplus European wine to 
finish into the gasoline additive. During the April 23 hearing, Ose 
asked the Federal Trade Commission (FTC) to investigate the 
allegations. After an initial review, the FTC turned the probe over 
to the Department of Justice, which is authorized to investigate 
criminal matters.

Ose, an opponent of an ethanol mandate passed as part of the broader 
Senate energy bill, said the transferring of the investigation 
implied illegal activity. The fact that the FTC referred these 
documents to the Department of Justice raises a new set of concerns 
regarding criminal violations by the ethanol industry, Ose said. 
Although the FTC and the Justice Department can both investigate 
antitrust violations, the Justice Department is primarily responsible 
for investigating criminal violations, he added.

ADM, which produces 41 percent of ethanol in the United States, has 
long touted the benefits of ethanol as a boon to U.S. farmers and 
U.S. energy security because most of the product is made from 
American corn.

However, the documents under review suggest that the company has been 
rigging bids to buy European wine alcohol before processing it into 
ethanol in the Caribbean. In doing so, the company appears to have 
benefited from advantage of subsidies both in Europe and the United 
States, Ose said.

There still is not any allegation of impropriety regarding the sale 
of ethanol, said Larry Cunningham, the company's senior vice 
president of corporate affairs. It has to do with purchases of wine 
alcohol in the European Union 8 or 10 years ago. We are doing 
fact-finding at ADM to determine what the facts are, Cunningham 
added.

In 1996 ADM pleaded guilty to fixing prices of two other products and 
paid a $100 million fine, and three of its executives were convicted 
of criminal charges and sent to prison.

Copyright 2002, Reuters

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[biofuels-biz] US appeals court upholds EPA cut in diesel emissions

2002-05-07 Thread Keith Addison

http://www.planetark.org/dailynewsstory.cfm/newsid/15804/story.htm
Planet Ark :
US appeals court upholds EPA cut in diesel emissions

USA: May 6, 2002

WASHINGTON - A federal appeals court last week cleared the way for 
the U.S. Environmental Protection Agency to require diesel trucks and 
buses to cut emissions by 90 percent by 2007, rejecting an attempt by 
engine makers and fuel refiners to gut the rule.

The U.S. Court of Appeals handed environmentalists a major victory by 
rejecting arguments from giant diesel makers like Cummins Inc. and 
International Truck and Engine Corp. They complained the EPA acted 
arbitrarily and capriciously in its demand for engines to reduce 
emissions by over 90 percent by 2007.

Cummins has not shown that the EPA acted arbitrarily or 
capriciously, the court wrote in its opinion, which dealt an 
across-the-board rejection to petitioners' complaints.

The EPA rules, unveiled in the waning days of the Clinton 
administration and later affirmed by the Bush administration, will 
force firms to produce cleaner-burning diesel engines, and compel 
refiners to make the fuel for them.

The new fuel will go into use in mid-2006, and auto makers are 
expected to begin rolling out new models next year to burn the new 
gasoline in 2004.

The EPA and Justice Department applauded the decision.

The court's opinion ratifies EPA's conclusions that dramatic 
reductions in the emission of pollutants are technologically 
feasible, said Tom Sansonetti, a Justice Department assistant 
attorney general.

Green groups said the tough rule will help make the air cleaner for 
Americans who suffer from asthma and respiratory illnesses.

These standards will dramatically clean up new trucks and buses that 
use diesel engines, said Frank O'Donnell at the Clean Air Trust.

Hundreds of thousands of Americans will live longer and healthier 
lives as a result of these new truck and bus standards, said Emily 
Figdor at the U.S. Public Interest Research Group.

The standard requires diesel engines to cut particulates and nitrogen 
oxides by over 90 percent.

The EPA has estimated the rule could prevent 8,300 premature deaths 
annually, thousands of cases of bronchitis and other respiratory 
ailments, and cost about $4 billion a year to implement.

The Alliance of Automobile Manufacturers, a group of 13 firms 
including Ford Motor Co, General Motors and DaimlerChrysler, said the 
ruling could open the door for them to sell cleaner, diesel-powered 
light-duty cars.

The availability of clean diesel fuel is a critical step toward 
clean diesel technology, said Julie Becker, a lawyer for the group.

The National Petroleum Refiners' Association, part of the lawsuit 
against the rules, said it objected to EPA's deadlines.

This case has never been about whether the sulfur content of highway 
diesel fuel will be substantially reduced; it will be, said Bob 
Slaughter, president of the refiners group. This case was about 
whether sulfur reductions should occur in a reasonable timeframe.

Slaughter said it was too early to say if the refiners group would 
appeal the new ruling.

Still unsettled is a portion of the case dealing with remote sensing 
devices the EPA wants engine makers to install to measure emissions - 
the so-called not-to-exceed provision of EPA's rule.

Story by Chris Baltimore

REUTERS NEWS SERVICE


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Re: [biofuel] Digest Number 936/isopropanol

2002-05-07 Thread mark fire

The reason that we use isopropyl alcohol in the
titration portion of the biodiesel prpcess is that
isopropyl will not react substantially with the
vegetable oil or the indicator, thus giving you a
repeatable result.If you want to see what a titration
yields with an alcohol that does react, use ethanol-
you'll see the pH values move all over the place as
the ethanol reacts with the vegetable oil (I think)).
 So, I think the answer is no.


__
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Re: [biofuel] Heating value of RDF

2002-05-07 Thread Harmon Seaver

On Mon, May 06, 2002 at 08:00:49PM -0700, di chua wrote:
 Hi all,
 
 Does anybody have information/references on the
 Heating Value of Sludge Derived Fuel (solid)? Or any
 other fuel that can be derived from sludge?
 
Are you talking about biosolids from sewage treatment?


-- 
Harmon Seaver   
CyberShamanix
http://www.cybershamanix.com

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Re: [biofuel] Religion ( was More free energy )

2002-05-07 Thread JOSEPH . MARTELLE


The basic problem is religion itself. Religions are sets of rules made by
man and have very little to do with a personal relationship with the
almighty God. Islam and Christianity are both children of Judaism, only
with different messiahs (Mohammed or Yeshua). I'm sorry I don't have time
to go into a detailed dissertation about the Creator and religions. There
is too much misinformation and bias to overcome. I'll get off my soap box
now. Joe


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[biofuel] California Senate oks emissions bill targeting SUVs

2002-05-07 Thread Keith Addison

http://www.planetark.org/dailynewsstory.cfm/newsid/15809/story.htm
Planet Ark :
California Senate oks emissions bill targeting SUVs

USA: May 6, 2002

SACRAMENTO - California's state Senate approved a controversial bill 
to limit greenhouse gas emissions, a measure automakers say is aimed 
at choking off sales of sport utility vehicles through tighter fuel 
economy standards.

Gov. Gray Davis has not taken a position on the bill, which is 
strongly opposed by the auto industry. Officials in his office said 
the Democratic governor was working with the bill's author, 
Democratic Assemblymember Fran Pavley, seeking to make it more 
palatable to all parties concerned.

The proposal has been attacked by representatives of the automotive 
industry, who have called it a driving tax intended to drive a 
wedge between Californians and their beloved SUVs - a big source of 
greenhouse gas emissions.

Some 47 percent of passenger vehicles sold in the nation's 
most-populous state are SUVs, minivans or light trucks, a percentage 
that has tripled over the last 30 years.

The Senate passed the bill, AB1058, by a vote of 22-13. It now 
returns for a concurrence vote in the Assembly, which first passed 
the measure in January.

The bill would require the state's Air Resources Board to adopt 
regulations that would achieve the maximum feasible reduction in 
emissions of greenhouse gases, including carbon dioxide (CO2), 
emitted by cars and light-duty trucks, the category that includes 
SUVs.

The regulations, which should be completed by 2005, would not take 
effect until at least Jan. 1, 2006. An amended version of the bill 
would give automakers until 2009 to come up with technological 
changes or modifications to comply with the new standards.

Because California's Air Resources Board was established before the 
U.S. Environmental Protection Agency was formed under the Clean Air 
Act of 1970, California is unique in its ability to impose air 
quality standards independent of federal regulation.

The federal government last month rejected a proposed 50-percent 
boost in fuel-efficiency for gas-guzzling cars and SUVs. Existing 
federal Corporate Average Fuel Economy standards require passenger 
cars to average 27.5 miles per gallon, while SUVs, along with 
mini-vans and other vehicles in the light truck category, need only 
achieve 20.7 mpg.

REUTERS NEWS SERVICE


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[biofuel] FTC says it is turning ADM ethanol price probe over to DOJ

2002-05-07 Thread Keith Addison

http://enn.com/news/wire-stories/2002/05/05072002/reu_47136.asp
- 5/7/2002 - ENN.com
FTC says it is turning ADM ethanol price probe over to DOJ

Tuesday, May 07, 2002

By Soo Youn, Reuters

NEW YORK - U.S. trade regulators said on Monday they will send a 
price-fixing investigation of Archer Daniels Midland and other 
producers of the gasoline additive ethanol to the Department of 
Justice, in a sign the case could turn into a criminal probe.

After reviewing these materials, staff of the FTC's Bureau of 
Competition has transmitted them to the Antitrust Division of the 
Department of Justice, the Federal Trade Commission's General 
Counsel William Kovacic wrote in a letter to Doug Ose, the head of 
the House Subcommittee on Energy Policy, Natural Resources and 
Regulatory Affairs.

Late last month, Ose, a California Republican, introduced internal 
memoranda by ADM and other ethanol producers indicating collusion to 
set prices for alcohol originating from surplus European wine to 
finish into the gasoline additive. During the April 23 hearing, Ose 
asked the Federal Trade Commission (FTC) to investigate the 
allegations. After an initial review, the FTC turned the probe over 
to the Department of Justice, which is authorized to investigate 
criminal matters.

Ose, an opponent of an ethanol mandate passed as part of the broader 
Senate energy bill, said the transferring of the investigation 
implied illegal activity. The fact that the FTC referred these 
documents to the Department of Justice raises a new set of concerns 
regarding criminal violations by the ethanol industry, Ose said. 
Although the FTC and the Justice Department can both investigate 
antitrust violations, the Justice Department is primarily responsible 
for investigating criminal violations, he added.

ADM, which produces 41 percent of ethanol in the United States, has 
long touted the benefits of ethanol as a boon to U.S. farmers and 
U.S. energy security because most of the product is made from 
American corn.

However, the documents under review suggest that the company has been 
rigging bids to buy European wine alcohol before processing it into 
ethanol in the Caribbean. In doing so, the company appears to have 
benefited from advantage of subsidies both in Europe and the United 
States, Ose said.

There still is not any allegation of impropriety regarding the sale 
of ethanol, said Larry Cunningham, the company's senior vice 
president of corporate affairs. It has to do with purchases of wine 
alcohol in the European Union 8 or 10 years ago. We are doing 
fact-finding at ADM to determine what the facts are, Cunningham 
added.

In 1996 ADM pleaded guilty to fixing prices of two other products and 
paid a $100 million fine, and three of its executives were convicted 
of criminal charges and sent to prison.

Copyright 2002, Reuters

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[biofuel] US appeals court upholds EPA cut in diesel emissions

2002-05-07 Thread Keith Addison

http://www.planetark.org/dailynewsstory.cfm/newsid/15804/story.htm
Planet Ark :
US appeals court upholds EPA cut in diesel emissions

USA: May 6, 2002

WASHINGTON - A federal appeals court last week cleared the way for 
the U.S. Environmental Protection Agency to require diesel trucks and 
buses to cut emissions by 90 percent by 2007, rejecting an attempt by 
engine makers and fuel refiners to gut the rule.

The U.S. Court of Appeals handed environmentalists a major victory by 
rejecting arguments from giant diesel makers like Cummins Inc. and 
International Truck and Engine Corp. They complained the EPA acted 
arbitrarily and capriciously in its demand for engines to reduce 
emissions by over 90 percent by 2007.

Cummins has not shown that the EPA acted arbitrarily or 
capriciously, the court wrote in its opinion, which dealt an 
across-the-board rejection to petitioners' complaints.

The EPA rules, unveiled in the waning days of the Clinton 
administration and later affirmed by the Bush administration, will 
force firms to produce cleaner-burning diesel engines, and compel 
refiners to make the fuel for them.

The new fuel will go into use in mid-2006, and auto makers are 
expected to begin rolling out new models next year to burn the new 
gasoline in 2004.

The EPA and Justice Department applauded the decision.

The court's opinion ratifies EPA's conclusions that dramatic 
reductions in the emission of pollutants are technologically 
feasible, said Tom Sansonetti, a Justice Department assistant 
attorney general.

Green groups said the tough rule will help make the air cleaner for 
Americans who suffer from asthma and respiratory illnesses.

These standards will dramatically clean up new trucks and buses that 
use diesel engines, said Frank O'Donnell at the Clean Air Trust.

Hundreds of thousands of Americans will live longer and healthier 
lives as a result of these new truck and bus standards, said Emily 
Figdor at the U.S. Public Interest Research Group.

The standard requires diesel engines to cut particulates and nitrogen 
oxides by over 90 percent.

The EPA has estimated the rule could prevent 8,300 premature deaths 
annually, thousands of cases of bronchitis and other respiratory 
ailments, and cost about $4 billion a year to implement.

The Alliance of Automobile Manufacturers, a group of 13 firms 
including Ford Motor Co, General Motors and DaimlerChrysler, said the 
ruling could open the door for them to sell cleaner, diesel-powered 
light-duty cars.

The availability of clean diesel fuel is a critical step toward 
clean diesel technology, said Julie Becker, a lawyer for the group.

The National Petroleum Refiners' Association, part of the lawsuit 
against the rules, said it objected to EPA's deadlines.

This case has never been about whether the sulfur content of highway 
diesel fuel will be substantially reduced; it will be, said Bob 
Slaughter, president of the refiners group. This case was about 
whether sulfur reductions should occur in a reasonable timeframe.

Slaughter said it was too early to say if the refiners group would 
appeal the new ruling.

Still unsettled is a portion of the case dealing with remote sensing 
devices the EPA wants engine makers to install to measure emissions - 
the so-called not-to-exceed provision of EPA's rule.

Story by Chris Baltimore

REUTERS NEWS SERVICE


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Re: Religion - was [biofuel] More free energy (maybe)

2002-05-07 Thread MH

 I was pleased to hear of inter faith based
 stewardship of the environment.  This example is more
 US bible based but there are others on the web
 if you care to share -- consensus willing  


 GLOBAL WARMING: A RELIGIOUS ISSUE
 Questions and Answers about Science, Public Policy, and Faith
 http://www.webofcreation.org/ncc/climatechange/faith.html  

 - What is global warming and how does it relate to climate?
 Climate and warming
 - What do scientists know about global warming, its causes and effects?
 - What do scientists project about future warming and its effects?
 - Why is global warming a religious issue?
 Psalm 24 tells us and
 - What has happened about global warming in international diplomacy?
 UN Framework Convention on Climate Change 1992-3, Kyoto, USA,
 European Union (EU), President Bush.
 - Can the Kyoto Protocol work if the developing countries don't participate?
 - What is happening in national policy and politics?
 President Bush and US Congress.
 The Global Climate Coalition, a lobby for certain
  coal, oil, and auto interests.
 - What are the alternatives to our present energy system?
 - Will complying with the Kyoto Protocol cost jobs and hurt the economy?
 National Academy of Sciences,
 Eight Nobel economists and 2,400 of their colleagues concluded...
 - Also see these websites
 - What can you do?

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Re: [biofuel] California Senate oks emissions bill targeting SUVs

2002-05-07 Thread Greg and April

I can't help but wonder at what would happen if all automakers chose to
boycott CA for 2 weeks to a month?  I'm thinking that bill would not go very
far.

Greg H.

- Original Message -
From: Keith Addison [EMAIL PROTECTED]
To: biofuel@yahoogroups.com
Cc: biofuels-biz@yahoogroups.com
Sent: Tuesday, May 07, 2002 06:12
Subject: [biofuel] California Senate oks emissions bill targeting SUVs


 http://www.planetark.org/dailynewsstory.cfm/newsid/15809/story.htm
 Planet Ark :
 California Senate oks emissions bill targeting SUVs

 USA: May 6, 2002

 SACRAMENTO - California's state Senate approved a controversial bill
 to limit greenhouse gas emissions, a measure automakers say is aimed
 at choking off sales of sport utility vehicles through tighter fuel
 economy standards.

 Gov. Gray Davis has not taken a position on the bill, which is
 strongly opposed by the auto industry. Officials in his office said
 the Democratic governor was working with the bill's author,
 Democratic Assemblymember Fran Pavley, seeking to make it more
 palatable to all parties concerned.

 The proposal has been attacked by representatives of the automotive
 industry, who have called it a driving tax intended to drive a
 wedge between Californians and their beloved SUVs - a big source of
 greenhouse gas emissions.

 Some 47 percent of passenger vehicles sold in the nation's
 most-populous state are SUVs, minivans or light trucks, a percentage
 that has tripled over the last 30 years.

 The Senate passed the bill, AB1058, by a vote of 22-13. It now
 returns for a concurrence vote in the Assembly, which first passed
 the measure in January.

 The bill would require the state's Air Resources Board to adopt
 regulations that would achieve the maximum feasible reduction in
 emissions of greenhouse gases, including carbon dioxide (CO2),
 emitted by cars and light-duty trucks, the category that includes
 SUVs.

 The regulations, which should be completed by 2005, would not take
 effect until at least Jan. 1, 2006. An amended version of the bill
 would give automakers until 2009 to come up with technological
 changes or modifications to comply with the new standards.

 Because California's Air Resources Board was established before the
 U.S. Environmental Protection Agency was formed under the Clean Air
 Act of 1970, California is unique in its ability to impose air
 quality standards independent of federal regulation.

 The federal government last month rejected a proposed 50-percent
 boost in fuel-efficiency for gas-guzzling cars and SUVs. Existing
 federal Corporate Average Fuel Economy standards require passenger
 cars to average 27.5 miles per gallon, while SUVs, along with
 mini-vans and other vehicles in the light truck category, need only
 achieve 20.7 mpg.

 REUTERS NEWS SERVICE



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 http://journeytoforever.org/biofuel.html

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[biofuel] SVO vs emissionsdiesel engine

2002-05-07 Thread srshb

Hi,

 I was helping to analyse an inedible oil grown in India,
 localy known as Karanj, Honge oil. In India the scietists
 are using this oil directly to run diesel engines. They
 heat this oil upto 175 degree F, to reduce the viscosity
 to 15 centipoise. 

 I was told that using unesterified oils causes long term engine damage,
  including varnishing of the cylinder walls, coking, pitting of the
  fuel injectors, creation of deposits in the engine cylinder, the 
  formation of gums, and other problems.

 Now my question is how people are using SVO's if there are so
 many problems ? Are there any feasible work arounds for these
 problems ? 

 Another important question - does the exhaust from engines
 using SVO are worse than a esterified oils ??

 About the Karanj/Honge oil, it looks very promising as this
 comes from a tree and can grow in a moderate soil..

Best Regards,
Suresh.



 



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Re: [biofuel] SVO vs emissionsdiesel engine

2002-05-07 Thread Keith Addison

Hi Suresh

Lots about SVO here, should answer most of your questions:
http://journeytoforever.org/biodiesel_svo.html
Straight vegetable oil as diesel fuel

This is a good study on using SVO:
http://www.nf-2000.org/secure/Fair/F484.htm

Here's more about Honge oil
http://www.goodnewsindia.com/Pages/content/discovery/honge.html
Pongamia Pinnata

http://www.hort.purdue.edu/newcrop/duke_energy/Pongamia_pinnata.html
Pongamia pinnata

Best wishes

Keith


Hi,

 I was helping to analyse an inedible oil grown in India,
 localy known as Karanj, Honge oil. In India the scietists
 are using this oil directly to run diesel engines. They
 heat this oil upto 175 degree F, to reduce the viscosity
 to 15 centipoise.

 I was told that using unesterified oils causes long term engine damage,
  including varnishing of the cylinder walls, coking, pitting of the
  fuel injectors, creation of deposits in the engine cylinder, the
  formation of gums, and other problems.

 Now my question is how people are using SVO's if there are so
 many problems ? Are there any feasible work arounds for these
 problems ?

 Another important question - does the exhaust from engines
 using SVO are worse than a esterified oils ??

 About the Karanj/Honge oil, it looks very promising as this
 comes from a tree and can grow in a moderate soil..

Best Regards,
Suresh.


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[biofuel] ethanol and carburetors

2002-05-07 Thread John Blackmer

I've got a carbureted 86 Ford E-150 v6 and I'm looking into what I could do
to help its emissions (this is in California)  Would a significant
proportion of ethanol as an oxygenate present a problem for the carburetor,
since the air/fuel mixture would have to change?  That would clean up the
emissions, right?

John


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[biofuel] Price of Ethanol

2002-05-07 Thread [EMAIL PROTECTED]

For several years now I have been saying on HIPC, and now here, that I
think a major failure of ethanol proponents, including the RFA (who
have done a decent job on some things), has been a failure to make
ethanol pricing available to the general public, to make it *freely*
available, as are the prices of major commodities, such as oil.  How
can ethanol proponents pretend they are ready to compete in some way
as a transportation fuel if they are so friggin small-time they can't
be bothered to get their product out there and have it traded in a
transparent way.

I now realize that part of the resistance to this idea has probably
been that those with a vested interest in not seeing the pricing made
transparent (ADM, et. al.) brought influence to bear.  In other words,
I was right (hypothetically) and there was no particular good reason
that the price of ethanol should not be made more widely available.

While these are hypotheses at a distance (I have no way of researching
these matters, as I have nothing to do with the industry), I haven't
met with any particularly helpful reaction, in agreement or
disagreement.

A webmaster could get a few hits by posting daily pricing or
every-fifteen-minute pricing.

MM

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[biofuel] Important notes

2002-05-07 Thread Christian

I was chatting today with a chemical engineer who happened to write his final 
thesis (the paper you write in order to graduate) on the methyl esters and 
transesterifications. As a chemical engineer, he studied che kinetics of the 
reaction and the reaction speeds, and he designed a production facility for a 
continuous process. He made all sorts of tests using IR spectrography at 
different points of the reaction, and made a very thorough work from the 
chemical point of view. He did not want to show me his thesis (maybe he was 
afraid of me copying methods still not patented), but he did give me some hints 
and opinions, which I try to summarize here, and which you might want to have a 
look at: (This guy used soy oil)

.- Strange enough, he pointed out that some thorough investigations were not 
100% right, but he didn«t say where they were wrong: he just added do the 
experimentation yourself, and you«ll see

.- He said that 50¼C for the reaction was waaay too much. He said he carried 
out his continuous process at room temperature. Besides this, he pointed out 
that the glycerin was very easily decomposed into acrolein and things like 
that, which make it dark brown. I was so curious that just now, when I got 
home, I made a 100ml batch at room temp (now around 18¼C), and mixed for only 
15 minutes. This guy said that they had achieved a 98% conversion after this 
time period. Now I«ve let it settle, and I can see after about an hour settling 
that the glycerin DOES show up much clearer (pure glyc is transparent). He also 
said that in his continuous process he had designed a three stage evaporator to 
remove the water from it, after distilling it to get out the MeOH (I suppose 
he«d do this under vacuum, so as not to heat the glyc and turn it into the 
mentioned brown acrolein). I found this point most interesting.

.- He mentioned they used sulphuric acid (say, 4ml per liter of WVO) to cut 
the reaction and stop the NaOH (this forms sodium sulphate, Na2SO4, which is 
washed with the water). I said I added some drops of vinegar in the washing 
stage and he almost whent crazy: he said tha any ammount of vinegar capable of 
modifying pH would produce great problems with the injectors. He said motors 
are very sensitive to those acid conditions.

.- He also pointed out that I should remove the sulphates (which came from the 
sulphuric acid / lye reaction) from the glycerin, and added that the glycerin 
was full of impurities: sulphates, MeOH, water...

.- He also added that boiling off the MeOH was not a very eco-friendly thing to 
do, and that you«d never be able to boil off 100% of it (eve with a 
distillation column)

.- He said a continuous centrifugue was not har to get, but reaction velocities 
had to be carefully measured when designing a continuous process. He fancied 
this method and said that settling the BD was not a good option, specially 
after vigorous mixing, which always (according to him) brought emulsification 
problems of some kind.

.- Regarding the fact I am an environmental engineer, he pointed out the 
washing stages use a damn great ammount of water (I can«t recall having heard 
of an alternative to this from him). Also, than no reaction is 100% efficient 
and that if I was to measure exhaust gases, then I *should* be checking for 
unburnt traces of methanol, which could produce nasty emissions.

Everything he said sounded most interesting, but presented me with a whole new 
set of questions to be answered. I«m very eager to hear the opinion of those 
with experience in BD making, specially those who use it regularly in their 
cars.

Best to you all,

Christian



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[biofuel] lab supplies

2002-05-07 Thread studio53

https://www.consolidatedplastics.com/acbnew/webpage.cfm?DID=14

Interesting industrial  laboratory supply house. If you are into industrial
stuff, order the catalog. I got mine today and it's better than the website.

(I have no affiliation with this company)

Jesse Parris  |  studio53  |  graphics / web design  |  stamford, ct  |
203.324.4371
www.jesseparris.com/Portfolio_Jesse_Parris/


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[biofuel] glycerin (Long but interesting)

2002-05-07 Thread Christian

Pasted from: 
http://www.ibiblio.org/herbmed/eclectic/kings/glycerinum.html


Glycerinum (U. S. P.)-Glycerin.
Preparations: Glycerita.-Glycerites - Suppositories of Glycerin - Glycerin 
Lotion - Preparations
Related entry: Sapo (U. S. P.)-Soap
Other tomes: Cook - Felter - Ellingwood - Petersen - BPC - AJP Mar 1871 
(Glycerin quality) - AJP Dec 1871

FORMULA: C3H5(OH)3. MOLECULAR WEIGHT: 91.79.
A liquid obtained by the decomposition of vegetable or animal fats or fixed 
oils, and containing not less than 5 per cent of absolute glycerin (C3H5[OH]3= 
91.79)-(U. S. P.).
SYNONYMS: Glycerina (U. S. P., 1870), Glycerine, Glycerol, Propenyl alcohol.

History and Preparation.-Glycerin was discovered, in 1779, by Scheele in the 
saponification products of olive oil by means of litharge, and later recognized 
by him as a common constituent of other oils and fats, and therefore named the 
sweet principle of fats. Chevreul gave it the name glycerin, and cleared up 
the nature of its combination in the fats. Glycerin, or glycerol, as it is now 
preferably called to indicate its alcohol character, is a trihydric alcohol 
(C3H5[OH]3), containing the trivalent radical glyceryl (C3H5). It exists in 
oils and fats, combined with palmitic, stearic, and oleic acids in the form of 
glycerylesters of these acids (tripalmitin, tristearin, triolein; also see 
under Adeps). In some oils and fats it is combined partially with other 
acids-e. g., in butter-wherein 5 per cent of the total fat is 
glyceryl-tributyrate, or tributyrin; in cod-liver oil it is said to exist in 
part combined with acetic acid, as glyceryl triacetate, or triacetin, etc. 
Glycerin also exists in the yolk of eggs and the human brain in the form of 
phospho-glyceric acid. Pasteur's researches have also established its 
occurrence as a regular constituent among the products of fermentation (see 
Alcohol).

On a small scale glycerin may be obtained in the process which led to its 
discovery, viz., that of making lead plaster (see Emplastrum Plumbi). The late 
Mr. Robert Shoemaker prepared by this method probably the first Commercial 
glycerin in the United States, in 1848, at $4.00 a pound (Amer. Jour. Pharm., 
1879, p. 289). The article became official in the U. S. P., in 1850.

Large quantities of glycerin are now obtained as a by-product in the 
manufacture of soaps and candles. This was formerly thrown away as useless. The 
principle involved is simply that of splitting the fat into its constituents 
(fatty acid and glycerin) by adding the elements of water (see Emplastrum 
Plumbi). The process of saponification is being carried out in several 
different ways: (1) With alkalies; the fatty acids thereby combine with alkali 
and form soap (see Sapo); the glycerin in diluted form is contained in the 
aqueous layer below the soap. (2) With milk of lime (old process of Campbell 
Morfit, see this Dispensatory, previous revision), or with milk of lime and 
water in closed vessels under a pressure of 10 atmospheres and a temperature of 
172¡ C. (242.6¡ F.) (Milly's Autoclave Process, see Prof. S. P. Sadtler, 
Handbook of Indust. Org. Chem., 1895, p. 56). The glycerin water separates from 
the layer of lime soap and fatty acids; glycerin is obtained therefrom best by 
evaporation in vacuo. (3) With superheated steam (aqueous saponification) and 
subsequent redistillation of the raw glycerin. This method was introduced, in 
1855, by Messrs. Wilson and Paine, and marked a great step forward in the 
problem of obtaining a pure article. In saponifying the fats with superheated 
steam, the temperature must not exceed 300¡ C. (572¡ F.), or else decomposition 
products will be formed. Both the fatty acid and the glycerin distill over. In 
redistilling the raw glycerin by superheated steam, the liquid is heated to 
about 180¡ C. (356¡ F.), and the steam has a temperature of about 110¡ C. (230¡ 
F.). For details regarding the manufacture of glycerin, consult the various 
works on chemical technology.

Description.-Glycerin is officially described as follows; A clear, colorless, 
liquid, of a thick, syrupy consistence, oily to the touch, odorless, very sweet 
and slightly warm to the taste. When exposed to the air, it slowly abstracts 
moisture. Specific gravity, not less than 1.260 at 15¡ C. (59¡ F.). Soluble, in 
all proportions, in water or alcohol, also soluble in a mixture of 3 parts of 
alcohol and 1 part of ether, but insoluble in ether, chloroform, carbon 
disulphide, benzin, benzol, and fixed or volatile oils. Glycerin is slowly 
volatilized from an aqueous solution, at or above 100¡ C. (212¡ F.), with the 
vapor of water. Heated by itself to a higher temperature, it yields acrid 
decomposition products, boils at a temperature at or above 165¡ C. (329¡ F.), 
and is finally entirely decomposed and dissipated-(U. S. P.). The exceedingly 
irritating decomposition products are chiefly due to the formation of acrolein 
(allyl aldehyde, C2H3.CHO), which is also formed when 

[biofuel] OILS (Long but interesting)

2002-05-07 Thread Christian

Pasted From:
http://www.ibiblio.org/herbmed/eclectic/kings/olea.html

Olea.-Oils.
Related entries: Olea Infusa (N. F.)-Infused Oils - Index of Oils - Sapo (U. S. 
P.)-Soap
Other tomes: Cook (volatile oils) - Cook (fixed oils) - Potter (volatile oils) 
- Potter (fixed oils)

The term Oil applies to a number of unctuous bodies not miscible with water, 
from both the vegetable and animal kingdoms, which are fluid at ordinary or 
slightly elevated temperature. When placed upon paper they render it 
translucent, or impart to it a greasy stain. Oils may be conveniently divided, 
with reference to their volatility, into two great classes: Fixed or fatty oils 
and fats, to which also belong the waxes (see Cera), and volatile or essential 
oils. Intermediate between the two, although chemically unlike either, stand 
the mineral oils and mineral waxes, or paraffins (see Petrolatum).

Olea Fixa.-FIXED or FATTY OILS (Olea pinguia). Fixed oils derive their name 
from not being volatilized by the vapors of boiling water. The difference 
between fatty oils and fats is merely one of consistency, the former being 
liquid, the latter solid or semisolid at ordinary temperatures. In the 
vegetable kingdom, fixed oils are mostly derived from the seeds of 
dicotyledonous plants, although monocotyledonous plants, such as the palm 
trees, furnish several of the technically important fixed oils. The oil often 
constitutes a large proportion of the seeds, e. g., not less than 25 per cent 
in linseed, 50 per cent in walnuts, about as much in almonds, as against about 
2 per cent in cereals. It is obtained from the crushed oil-bearing material, 
either by cold or warm pressure, in hydraulic presses, or by extracting with 
such solvents as carbon disulphide, or by boiling the crushed material with 
water, whereby the oil floats on top and may be conveniently collected. The 
residual press-cakes, obtained in the first process (oil cakes), are valuable 
feed material for cattle, since they contain much nitrogenous and fatty matter 
(see table in Prof. S. P. Sadtler's Handbook of Indust. Org. Chem., 2d ed., 
1895, p. 70).

The oils and fats derived from the animal kingdom, are obtained from various 
organs of the animal; thus, bone-oil from bones, by boiling with water, or 
extraction with solvents; neat's-foot oil from the feet of oxen by boiling with 
water; cod-liver oil and shark oil, from the respective livers, by spontaneous 
exudation and gentle expression; tallow and lard from the internal abdominal 
fat of sheep and hogs (see Sevum and Adeps), etc. The crude oils and fats as 
obtained in the manner alluded to, are mostly of a yellow, brown or even black 
color, and frequently require more or less purification. This is often effected 
by mechanical treatment, such as filtration with or without charcoal, etc., but 
more frequently, by chemical processes, especially treatment with 1 or 2 per 
cent of strong sulphuric acid (applicable, for example, to linseed oil), or 
with zinc chloride, or alkalies, tanning materials and oxidizers, such as 
potassium bichromate, hydrogen peroxide, etc.

The fatty oils of marine animals, and those from most vegetable sources, are 
fluid at ordinary temperature; palm oil, cacao-butter, nutmeg butter, cocoanut 
oil, and others, are semisolid like butter. When exposed to cold, fixed oils 
solidify at temperatures varying with the oil. Fatty oils are insoluble in 
water, rendering that fluid milky when agitated with it, but the oil finally 
rises upon the surface; if a mucilaginous substance, or alkaline carbonate be 
added, the oil is prevented from rising., and a permanent milky mixture called 
an emulsion is formed. With the exception of castor oil and croton oil, fatty 
oils are nearly insoluble in cold alcohol. They dissolve readily, however, in 
ether, carbon disulphide, chloroform, benzol, petroleum benzin, amyl alcohol, 
acetone, and oil of turpentine, and freely mix with one another, as well as 
with resins and volatile oils. They are all lighter than water, their specific 
gravities ranging from 0.879 to 0.968. Fatty oils are not volatile as such, but 
can be heated to boiling (at about 315¡ C., or 600¡ F.) whereby decomposition 
takes place, acrid fumes of acrolein (see Glycerin) being evolved, together 
with carbonic acid gas, some volatile organic acids and inflammable 
hydrocarbons. Upon condensing the vapors, an empyreumatic oil is obtained. When 
in the state of vapor, fixed oils take fire upon the approach of an ignited 
body; the products of combustion are water and carbonic acid gas.

As to their chemical nature, most fatty oils are mixtures of salts of the 
trivalent alcohol glycerin (C3H5[OH]3), with the saturated palmitic (C16H32O2) 
and stearic acids (C18H36O2), both higher homologues of acetic acid, of the 
general formula CnH2nO2, and the unsaturated oleic acid (C18H34O2), which 
represents the series CnH2n-2O2. The salts are called glycerin esters, or 
glycerides, and are 

[biofuel] Acrolein 2

2002-05-07 Thread Christian

Regarding the message I just sent:

At: http://www.inchem.org/documents/icsc/icsc/eics0624.htm

 (A Chemical safety data sheet) it sais the glycerin decomposes below it«s 
boiling point at 171¼C. (For pure glyc).

Christian


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[biofuel] Acrolein («twas illegible)

2002-05-07 Thread Christian

I«m a bit concerned with the glycerin/acrolein topic (glycerin thermally 
decomposes into this dangerous substance). I found little on this topic (Keith 
and Todd) in the archives. From a not-so-thorough search in google, acrolein 
forms when heating Glycerol to 290¼C, but that happens when the glycerin is 
pure. The water/glyc mixture boils at a lower temp, near 164 ¼C. A chemical 
engineer told me today that the dark brown colour in the glyc could have to do 
with the formation of acrolein (even at 60¼C). I want to run an IR 
spectrography on my glyc to see if that«s so. Besides, I thought acrolein was a 
gas. But still, it«s a carcinogenic substance you don«t want to mess with. Does 
anyone know more about the subject? I am also concerned with the fact some of 
you are using it as a detergent/grease remover. I«d suppose it will contain at 
least traces of methanol, methoxide, maybe even acrolein, neither of which you 
want on your hands. Please let me know what you think.

Best to you all,

Christian


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