Diesel emission technologies at the SAE Congress

Regardless of the ups and downs in the fortunes of the SAE World 
Congress and Exhibition, the diesel emission sessions have enjoyed 
considerable interest and high attendance for a number of years. It 
was also the case during this year's Congress, held in Detroit, MI on 
March 3-6.

Diesel particulate filter technologies, including both filter 
substrates and systems, were one of the main topics. A number of 
papers presented by authors from Ibiden and NGK discussed the 
improvements in silicon carbide (SiC) substrate technologies. 
Researchers attempted to improve the thermal shock resistance of SiC 
by either modifying the material properties (composite Si-SiC, paper 
2003-01-0384) or by developing of new assembling techniques for SiC 
filter segments (2003-01-0376). Another trend was to develop SiC 
materials of increased porosity, up to as much as 65%, to allow for 
coating with high catalyst/washcoat loadings, as may be needed in 
catalyzed DPFs or in combined DPF/NOx adsorber devices (2003-01-0377, 
2003-01-0383).

Silicon nitride, a new filter substrate material, was presented by 
Japan's Asahi Glass (2003-01-0386). The silicon nitride material was 
claimed to have temperature resistance and chemical stability 
comparable to those of SiC, while being endowed with superior thermal 
shock tolerance, thus potentially eliminating the major drawback of 
silicon carbide and the need for filter segmentation. Asahi developed 
a new manufacturing method using silicon metal as the raw material, 
resulting in costs allegedly comparable or lower than those for SiC 
parts. Another new material, named DuraTrap AT, was showcased by 
Corning, but no paper was presented. The DuraTrap AT, designed to 
combine high thermal capacity and low thermal conductivity, is 
currently tested with selected Corning customers.

Diesel filter systems papers dealt mainly with ongoing improvement 
and testing of existing concepts, such as those using cerium or iron 
based fuel additives for regeneration. A new configuration of 
passively regenerating catalytic filter, maximizing the effect of NO2 
regeneration, was suggested by researchers from the University of 
Delft, where a catalyzed wall-flow filter was proceeded by a 
catalyzed ceramic foam substrate (2003-01-0379).

In comparison to the last year Congress, more NOx adsorber papers 
were presented, highlighting the ongoing development in this 
technology, but also identifying many technical problems (such as 
durability and regeneration/desulfation strategies) that have to be 
solved before the commercial application of NOx adsorbers in U.S. 
2007 compliant engines can be possible. For the first time, some 
papers presented results from vehicle prototypes, as opposed to 
laboratory bench tests. For instance, AVL reported a 65% NOx and 90% 
PM emissions reduction over the FTP-75 test in a 1750 kg vehicle 
equipped with a NOx adsorber and a DPF (2003-01-0043). An interesting 
observation was made that the upstream NOx adsorber helped to 
regenerate the DPF, probably through increasing the NO2/PM ratio. 
Little new development was reported in the U.S. EPA NOx adsorber 
demonstration program. However, the EPA is expecting to start road 
tests of a NOx adsorber/DPF equipped vehicle (5.9 liter engine) in 
July.

The EPA has been also developing an alternative technology--a clean 
combustion diesel engine meeting the 0.2 g/bhp-hr NOx standard 
without the use of exhaust aftertreatment. An early prototype of the 
engine (with most vital organs replaced by dummies) was showcased in 
the FEV exhibit area, but no technical paper was presented. A NOx 
emissions map of the engine was shown, with NOx never exceeding 0.2 
g. The technology was developed in a 1.9 liter, 4-cylinder TDI 
engine, apparently not operated in the HCCI mode. The engine was 
equipped with "hydraulically intensified" high pressure (> 200 MPa) 
injection system. NOx emissions were controlled by high boost 
(turbocharger + boost assist device, intercooler) and a low pressure 
loop EGR. The engine would require exhaust gas aftertreatment for CO, 
HC, and PM. Technical details on the engine and the system cost vs. 
performance trade-offs are not known.

With the continuing opposition of the EPA against urea-SCR 
technology, there were fewer SCR reports. The most active company in 
this area was Siemens (Ceramics GmbH), who presented papers on 
integrated SCR-based NOx/PM control systems targeting both Euro 4/5 
and the US 2007 (2003- 01-0774).


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