I don't have access to Office 2007 and OO.o can't write those files, but you 
can try the fifth result from this link (that's what I used):
http://www.google.pl/search?q=filetype%3Appsx

The file is recognized as application/zip, whereas it should be recognized as:
application/vnd.openxmlformats-officedocument.presentationml.slideshow
when the extension is changed to .pptx, this format is recognized as:
application/vnd.openxmlformats-officedocument.presentationml.presentation
and can be opened by OpenOffice 3.0 as Microsoft PowerPoint 2007 XML, although 
I have to manually select the filter.

This type of file should be opened by OpenOffice.org in presentation
mode, instead of in the editor (I heard this is the behaviour with
PowerPoint).

I'm using the current dev version of Ubuntu Jaunty.

-- 
.ppsx (Office 2007 slideshows) files not recognized
https://bugs.launchpad.net/bugs/344198
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