Two methods I didn't mention that this group might already be familiar with:

1) They still distribute time via telephone.   Call 303-499-7111 to hear
the WWV (colorado) broadcast or 808-335-4363 for WWVH (hawaii)

2) You can dial in with your dialup modem and get time codes.  300 baud up
to 9600 baud.

Beyond that they have a range of services, some of which are not on the
website to distribute time and frequency to various other entities which
need a NIST-traceable and/or highly accurate time system.

Not sure how much detail you really want, but there are three main
additional methods I'm aware of:

1) Two-way-satellite time and frequency transfer.   Essentially they buy
time on a commercial satellite to be able to do full duplex two way
satellite communication.   Because of the symmetric nature of the
simultaneous two-way path they are able to cancel out any satellite delay.
 Lots more information at
https://www.nist.gov/pml/time-and-frequency-division/time-distribution/two-way-satellite-time-and-frequency-transfer

2) Common view GPS.   Essentially you measure the time you receive a
certain part of the signal from a single GPS satellite at two different
locations, and compare it to the time produced by the atomic clocks at that
location.   If the path to the GPS satellite is the same length at both
sites because you picked a time that the GPS satellite was in that
position, you can be pretty certain that any difference in time of arrival
you measure between the sites is an inaccuracy of the atomic clocks at each
site.  This method doesn't depend on the accuracy of the GPS clocks on the
satellites as you're just comparing time of arrival of the signal and not
decoding GPS time.   Of course, the devil is in the details here as there
is often propagation delay differences, and you need very precise satellite
orbital data to make this work.   Oh, high accuracy GPS satellite orbit
data is also available from NIST.     See
https://www.nist.gov/pml/time-and-frequency-division/time-services/common-view-gnss-time-transfer
.   Apparently they're also experimenting with comparing the phase of
received GPS signals as well to get even more accuracy.

3) They also do experimental fiber-based time and frequency transfer.
 Doesn't take much imagination about how this works, other than to say that
apparently you have to take into account the fact that light propogates
down different fibers at different speeds (even in the same bundle).

4) If you need nist-traceable time at your site they also sell a service
where they drop a rack of equipment in your site and manage it.   You get a
highly-accurate frequency and time standard that is NIST traceable with all
of the reports to prove it, from NIST.   Think all of the atomic clocks you
need, along with NIST scientists handling the time transfer to that rack.
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