I haven't used spotify, but it should be nearly impossible to tell the
difference between 320 kbps lossy and lossless.  I think it might be
possible, but only for people that know exactly what compression
artifacts to listen for.

If you check out hydrogenaudio.com, there have been some extensive
tests done on audibility at various compression levels (by some of the
people that designed the lossy codecs in the first place).  At least
for LAME MP3 128 and below is very easy, 192 is possible, 256 is very
hard, and 320 would require very, very careful listening if it's
possible at all.

So if there's really a significant difference, something is wrong
somewhere.  The first thing to do is try it blind, making sure volume
levels are matched.  If you can still tell them apart, it's time to
take a look and make sure the stream really is 320, that there's no
nasty transcoding going on, etc.


-- 
opaqueice
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