Because the atoms are in the crystal, one solution is to refine them with
occupancy = 1.0 and let the B factor reflect the disorder. That, to me,
seems to be the approach that makes the most physical sense.


Doesn't this ignore the use of B-factor restraints in the refinement
programs?  Because the B-factors are in most cases refined in this way,
modelling an atom in a position not supported by experimental evidence, and
allowing its B-factor to inflate, will artificially inflate others in the
residue as well, and correspondingly, will restrain its B-factor to a value
lower than it should be.

Furthermore, this practice would be expected to greatly increase user error
because there is no clear indication of the atoms that were positioned
arbitrarily according to non-experimental terms.  Hopefully the end-user
will look at the model in the context of the structure factor data, but as
we know this is not always done, and even worse, can't be done where the
structure factors haven't been deposited.  In this worse case scenario, how
can someone be sure that any surface interactions between sidechains with
middle-to-high B-factor is supported at all by the electron density?
Hopefully the crystallographer who models missing atoms in this way is
vigilant about depositing their structure factors!

I think building atoms in places not supported by the data without at least
an occ=0 is the wrong approach.  There are plenty of modelling programs out
there that can do that for you, even humble SwissPDB viewer will arbitrarily
reconstruct missing side chains and colour them differently to the rest of
the protein.

James



--
Dr. James Irving
NH&MRC C.J. Martin Fellow
Division of Structural Biology
Wellcome Trust Centre for Human Genetics
Oxford University
Roosevelt Drive,
Oxford OX3 7BN
UK
email: [EMAIL PROTECTED]
phone: +44 1865 287 550

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