I like nanodrop ultrafiltration:

concentrate your protein to the highest stable concentration possible

figure out what is the lowest possible robustly-detectable nadph signal on
your nanodrop

combine the two in such a way in the top of a microcon of appropriate MWCO
to acheive the highest possible protein concentration with the lowest
possible nadph concentration. Take a baseline spec reading before spinning.

spin long enough to get enough flowthrough to measure on the nano (~10uL is
plenty.) Flowthrough should be the free nadph concentration L. Total L
should be known, as well as total P, so you can figure out bound
concentrations PL easily.

you should probable do this in triplicate or so, with appropriate controls.
I found 50uL/microcon to be a good balance of pipette-ability and economy of
protein. If you want to get fancier, you can do more samples varying
concentrations (or do some other more sophisticated method.)

Jacob



On Wed, Aug 4, 2010 at 3:10 AM, Xuan Yang <[email protected]> wrote:

> Dear All,
>
> 3D structure modeling server I-TASSER predicts a binding site for NADPH and
> I want to test this prediction. What would be the nice quick way to tell
> whether this protein bind NADPH or not, when I have a lot of recombinant
> protein?
>
> Sincerely,
>
> Xuan Yang
>

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