Hi Xiao,

I have observed this phenomenon with two proteins I worked with: rubber-like 
crystals which you can bend without breaking. As others mentioned: if you have 
this rubber-like crystals it must be protein, since salt crystals behave very 
differently. Also I could not think of any reason why salt crystals would 
refuse to dissolve. Fresh crystals did not suffer from this phenomenon, so I 
suspect it is due to some (slow) crosslinking. I did not try myself, but you 
could consider adding reducing agents (glutathion, TCEP, DTT) to your 
crystallization setup to see if this helps.

Also try the freshest crystals you have for Xray diffraction since in my hands 
this “rubber-transition” led to a dramatic reduction in resolution of the data.

Good luck!
Herman



Von: CCP4 bulletin board [mailto:[email protected]] Im Auftrag von Xiao Xiao
Gesendet: Freitag, 26. September 2014 01:53
An: [email protected]
Betreff: [ccp4bb] off-topic;Crystal cannot dissolved in buffer

Hi everyone,

Sorry for an off-topic question.

I got a problem with crystal dissolving. Basically I got crystals of my protein 
in various conditions, most conditions contain PEGs but different salts. These 
crystals has very similar shape, so it should not be salt.

Now I am trying to dissolve the crystal to make sure it is my protein, by 
SDS-PAGE and N-term sequencing. I washed the crystals in its original 
crystallization buffer few times then transfered them into regular buffer 
(500mM NaCl, 50mM HEPES 7.5) with or without 10mM DTT, however the crystal 
didn't dissolve.

I then tried to heat it then add SDS loading buffer to run a gel, I did see 
very small amount of protein on the gel, at the correct position, but it's not 
enough for N-term sequencing.

Is it normal for a protein crystal? And does anyone have any suggestion for 
dissolving such crystals?

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