Dear Lea and Andreas,

given the excellent resolution, it might be possible to check the densities to 
decide if hydrolysis is the more likely cause. If the negative density starts 
more or less sharply after the C-terminal carboxylate group of the cleaved 
terminus (i.e. after the peptide nitrogen in the uncleaved part), this would 
favour cleavage as opposed to flexibility. I have never tried this, but maybe 
the refinement programs would allow for a refinement of the occupancies of the 
individual atoms of the last four residues to check if there is a clear drop 
right after the nitrogen atom.

Best wishes,

Norbert

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