It looks like that it is from ccp4 version 7 series. There, our programs may 
have changed HN2 with H2. 
However, you should check if the group name for this entry is L-peptide. If it 
is not L-peptide then coot will not recognise it as L-peptide (as far as I know)

Regards
Garib

> On 26 Oct 2022, at 00:18, Jiang Xu <[email protected]> wrote:
> 
> Hi Garib,
>    Thank you for your help. I looked for NLE in the coot monomer library and 
> found a file named NLE.cif at '/Applications/ccp4-7.1/lib/data/monomers/n'. I 
> then searched this file for 'HN2' but didn't find any line that contains this 
> string. So is it a typo or I was looking at the wrong file?
> Sincerely
> Jiang
> 
> On Thu, Oct 20, 2022 at 12:36 AM Garib Murshadov <[email protected] 
> <mailto:[email protected]>> wrote:
> If you import cif dictionary then in coot mutate residue should work. At 
> least it worked n one of our problematic cases. If it does not work then Paul 
> Emsley may be able to help. 
> 
> Regards
> Garib
> 
>> On 20 Oct 2022, at 02:06, Jiang Xu <[email protected] 
>> <mailto:[email protected]>> wrote:
>> 
>> Hi Garib,
>>    I deleted the Met residue and imported the nle.cif file into the 
>> dictionary and checked the "create a molecule" box.I then used "real space 
>> refinement" to align it correctly with the electron density. I then save the 
>> merged molecule as a new pdb file but when I reopened the new file, I found 
>> the NLE molecule's position was not aligned with the electron density and 
>> couldn't be corrected with "real space refinement" in Coot. So any 
>> suggestions?
>> Thank you,
>> Best,
>> Jiang
>> 
>> On Wed, Oct 19, 2022 at 12:44 PM Garib Murshadov <[email protected] 
>> <mailto:[email protected]>> wrote:
>> NLE is in the monomer library. However, it is marked as non-polymer. The 
>> reason why it is non-polymer is that one of the hydrogen atoms on N is 
>> called HN2 (in peptides they are H, H2 and H3). 
>> One easy way would be replace HN2 with H and save in a cif file. Then read 
>> it in coot using “import cif dictionary" and hope that coot will recognise 
>> it as peptide. I attach nle.cif just in case
>> 
>> Regards
>> Garib
>> 
>> 
>>> On 19 Oct 2022, at 20:34, Jiang Xu <[email protected] 
>>> <mailto:[email protected]>> wrote:
>>> 
>>> Hello Guys, 
>>>    I have a question regarding how to change the standard amino acid in my 
>>> structure to Norleucine. It turned out that the one Methionine should be 
>>> Norleucine. I tried to use the coot's mutation method but didn't find 
>>> NLE(Norleucine) there. Any suggestions?
>>> Thank you,
>>> Best,
>>> Jiang
>>> Lin Chen Lab
>>> University of Southern California
>>>   
>>> 
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