Hi Erik,
A couple of things to consider:
1. Begin the N-terminus from helix "initiating" residues (i.e. one residue
overhang might not be sufficient)
2. If not done already, add the 6-carboxy-fluorescein moiety at C-terminus
of the peptide
Good Luck,
Partha

On Wed, Mar 20, 2024 at 6:03 AM Erik Debler <[email protected]> wrote:

> Hi everyone,
>
> Sorry for the off-topic question, but I thought I may get some
> advice/pointers about the design of a stable alpha-helical peptide. I would
> like to obtain a peptide mimicking a 13-residue alpha-helix that was
> identified in a protein to mediate a protein-protein interaction, which is
> completely abolished by three spatially adjacent point mutations in the
> helix of the protein. I designed a peptide with a 1-residue overhang on
> each side and a 6-carboxy-fluorescein moiety on one end, but the peptide
> did not bind to the interaction partner probed by fluorescence
> polarization. The peptide easily dissolves in water, so solubility does not
> seem to be an issue. Any suggestions or pointers to relevant literature
> would be greatly appreciated.
>
> Cheers!
> Erik
>
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