Dear ConsDist list members
I have an inlaid blotting book composed of ivory, possibly jet, and some form 
of black material, as well as a small amount of coloured intaglio pieces (?), 
all adhered to a wooden backing. The black material looks a bit like niello, 
and is degrading badly (crystallizing, expanding,  and crumbling away from the 
support). I tested it with our handheld XRF and it showed peaks for tin, but 
not for silver or sulphur, and only a tiny possible peak for copper and zinc, 
as well as iron (and maybe a hint of lead), which is probably just dirt. The 
only other peak of significance is likely calcium. When looking at the 
corrosion crumbs alone, the only peaks were tin, with a smaller peak for 
calcium.
I did a quick scan with Dr. Google and our library of books, and couldn't find 
any reference to a niello/inlay substances composed of just tin. Regular niello 
might contain small amounts of tin, but I should be detecting Ag, Cu, and S 
with it, and I'm not.  I also found reference to a mercury amalgam material 
(like what's in our teeth) that can spontaneously decay. It sounds like it 
might give the crumbling and disintegration that I'm seeing in the object, but 
I'm not detecting any mercury. Metallic tin might be used in inlay, but it is 
not black.
The acquisition record for the object gives no indication of artist, origin, or 
materials. Visually the object looks similar to images of Visagapatam inlayed 
wooden objects from India, or perhaps a bit like Bidri niello, or inlay work 
from Iran, Turkey, or India, where coloured lac might have been used, but there 
is no mention of tin with this. Under the microscope the material and its 
degradation looks more mineral and crystalline than organic anyway.
Does anyone have any experience with this type of material? Can you give me any 
information of composition or degradation of the materials? I can send images 
of the object and microscope images of the degradation if you are interested.

Thanks,
Valerie Tomlinson


Valerie Tomlinson | Conservator | Auckland War Memorial Museum | Tamaki Paenga 
Hira | The Domain, Private Bag 92018, Victoria Street West, Auckland 1142, New 
Zealand | www.aucklandmuseum.com | M | P +64 9 306 7070 ext7304 | F | E 
[email protected]

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