I had the same issue.  Make sure you are using pdb 3 nomenclature 
versions of Reduce and Probe.  Current Mac versions are 212 and 313.  The 
313 reduce also requires a new HET dictionary file; 
reduce_wwPDB_het_dict.txt
The het dictionary should be setup like this in your .cshrc
setenv REDUCE_HET_DICT /Kinemage/reduce_wwPDB_het_dict.txt
and then in your .coot file you need the lines 
(define *reduce-command* "/Kinemage/reduce313")
(define *probe-command* "/Kinemage/probe212")
note; I changed the probe and reduce file names

Mark

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