I can take the D-PHE cif out and rename it to DPH.  But the peptide bonds at 
the N and C terminus of DPH are broken in COOT since COOT doesn't consider DPH 
as an amino acid.  Any way to circumvent that?  Thanks.

-- Jianghai




On Nov 23, 2011, at 7:51 AM, Paul Emsley wrote:

> On 22/11/11 23:25, Jianghai Zhu wrote:
>> I am building a cyclic peptide with a D amino acid in the middle.  First, 
>> how can I connect the N and C termini of the peptide and make it a peptide 
>> bond?
> 
> There is no way (in Coot) at the moment, sorry.  This is something I am 
> working on [1].  If you make a link between them, Coot will draw a link - but 
> that is not (all) that you want (AFAICS).
> 
>> Second, how do I make the PHE to a D amino acid?  I know there is a library 
>> of D-Phenylalanine in mon_lib.cif, but the code for that is PHE-D? I cannot 
>> use 5 letters for the residure, can I?
>> 
> 
> As I suspect you know, several D amino acids have specific three-letter 
> codes, but D-PHE does not.  Using a PDB file, Coot will not detect that you 
> mean PHE-D and not PHE for the restraints.  If you use mmCIF/pdbx then I 
> think it will work.
> 
> Paul.
> 
> [1] this is related to carbohydrate refinement and involves using LINKR 
> information (but I am having trouble extracting that using the current mmdb 
> libs - I'll poke Eugene about it again).
> 

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