On 17/05/2019 17:10, Hannah Bridges wrote:
>
>
> I am using coot 0.9-pre (ccp-em) with a protein that contains Fe-S
> clusters. Although the bonds are now drawn between the Fe and S atoms
> (thanks Paul!) and the clusters no longer explode when you real space
> refine without adding your own restraints, when you do real space
> refine in coot, the default settings appear to make the 4Fe-4S
> clusters pretty much cubic.
>
> A recent article by Nigel Moriarty and Paul Adams has looked at all
> the hi-res pdb structures with FeS clusters and found out the average
> angles:
>
> https://onlinelibrary.wiley.com/iucr/doi/10.1107/S205979831801519X


Yes, that was interesting.


>
> I was wondering if it would be possible for the coot default
> restraints to be updated to reflect this? If not we will just continue
> adding our own restraints, but there may be people out there who don't
> know that their 4Fe-4S cluster isn't supposed to be a cube!
>
Coot uses the CCP4 Monomer Library. I believe that the CCP-EM
distribution of Coot does the same (although possibly a more recent
version). Many ligands have been updated with new restraints from
Acedrg, but not ligands with metals. I understand that ligands with
metals are being considered - I don't know the current status. It seems
unlikely (to me) that the CCP4 Monomer Library will use Phenix
restraints. I suppose that it's possible that one could write a script
to create a Frankensteinian library where the dictionaries from Phenix
replace or fill the gaps in the CCP4 Monomer Library. Seems like a good
idea, but not high on my priority list.

TLDR: SEP.


Paul.

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