Horst Leps writes:

> % Created 2024-01-16 Tue 20:00
> % Intended LaTeX compiler: pdflatex
> \documentclass{scrartcl}
> \usepackage[utf8]{inputenc}
> \usepackage[T1]{fontenc}
> \usepackage{graphicx}
> \usepackage{grffile}
> \usepackage{longtable}
> \usepackage{wrapfig}
> \usepackage{rotating}
> \usepackage[normalem]{ulem}
> \usepackage{amsmath}
> \usepackage{textcomp}
> \usepackage{amssymb}
> \usepackage{capt-of}
> \usepackage{hyperref}
> \usepackage[germanb]{babel}
> \usepackage[utf8]{inputenc}
> \usepackage[LGR,T1]{fontenc}
> \usepackage[greek,german]{babel}
> \author{HL}

The document loads babel twice:

\usepackage[germanb]{babel} <==
\usepackage[utf8]{inputenc}
\usepackage[LGR,T1]{fontenc}
\usepackage[greek,german]{babel} <==

Hence the 'option class for package babel' error. You have loaded babel
in your org document with the [greek,german] option and (probably, in
the class you are loading) babel is already loaded as well.

Try:

#+LaTeX_Header: \PassOptionsToPackage{greek,german}{babel}

Best regards,

Juan Manuel 

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