Sorry this is long, buuut ... 

I recommend going to 

http://www.northland.cc.mn.us/Terry_Wiseth/gas%20transport%20part%201/index.
htm 

Keep in mind that there are all sorts of hyperbaric chambers 
available.  There are others that are smaller but not capable 
of great pressures. The only one I was in was a large one on 
City Island NY which took us down to the equiv of 160 ft under 
the ocean. It was capable of going much deeper. Assuming 33 ft 
of depth in salt water for every 1 atmospheric pressure, 160 ft 
is roughly 4.8 atmospheres or 71 lbs/in^2. They were doing alot 
of work with fire fighters who had succumbed to smoke inhalation. 
Depending upon the medical case involved, they can go as high 
as 4 atmospheres.  One case there involved a motorcycle accident 
victim with a crushed knee.  Had he remained in the hospital, 
he would have lost his leg.  In the chamber, the partial pressure 
of O2 was high enough so that the little amount of blood that 
got around the injury managed to keep the tissue alive and 
eventually saved his leg. Oh, yea, the doc got stuck in there 
with the victim for the duration. 

On another note - 

Look up Pashen's Law to get a rough idea what you're up against. 
It goes roughly like this - 

Paschen's Law:  breakdown for uniform gaps

   V(kV)= 24.2Sh +6.1(Sh)^0.5  

where 

V is the breakdown voltage in KV
S=(293p)/760T
h is electrode spacing in cm.
p is pressure mm of mercury
T is temperature in degrees Kelvin

At STP, S = 1 so 30KV/cm is a pretty good approximation for 1 cm. 

At 1, 2, 3, and 4 atmospheres for 1 cm it goes something 
like this ... 

Atmospheres   separation (cm)  Breakdown voltage (KV) 
 
    1              1              30 KV 
    2              1              57 KV 
    3              1              83 KV 
    4              1             109 KV 

The reason for the increase in voltage threshold is due to 
more charge carriers being present for charge transportation 
across the gap.  Neon lights won't work at elevated pressures 
inside the tube.  The inside has to be evacuated to a partial 
vacuum get the light to glow. 

You may also want to check for the flammability of 
materials at elevated percentages of O2. 

Side Note:  The use of pure O2 during Apollo 1 and the earlier 
            space flights like Mercury was merely a copy of 
            using pure O2 in planes before the space program. 
            Up until that point in time, there was nothing 
            unique nor unusual about using pure O2. 


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