I'd welcome an off-the-list discussion.

> From: John Woodgate
> Sent: Thursday, August 23, 2007 11:34 AM
> 
> Tarver, Peter writes:
> 
> > For accurate information on the underlying principles of how 
> >thermocouples work, perform searches on "Seebeck Effect."
> 
> There's a long tale about this, which is OT, so I'll 
> drastically précis. 
> Two physicists are trying to find out whether the voltage is 
> in fact generated at the junction. One shortens his wires 
> progressively and finds that the voltage goes down, so the 
> voltage must be generated in the wires. But the second argues 
> that the short wires are hotter at the ends away from the 
> junction, so that is why the voltage is less. He keeps those 
> ends at a constant temperature as he reduces their lengths, 
> even though when they get to 100 microns long, he needs 
> liquid helium for coolant. The voltage stays constant.

At 100 µm, the technique must have cost a small fortune to implement.  Ahhh! 
The heady sensation of a research grant!

> So does that mean that the voltage IS generated in the 
> junction? Or is it doe to the temperature GRADIENTS in the wires?

If T1 and T2 are maintained at constant temperatures and the voltage
difference between the wires at their 'free' ends is the same, regardless of
length, that provides no true guidance to the truth and the experiment was
doomed to fail from the start.  The Seebeck Effect predicts that a potential
difference is created in the metal, if the two ends are held at different
temperatures, without regard to length.  If we make the length of the metal
arbitrarily short, the voltage will appear to have been created in the
junction, but that doesn't tell us anything, because there is still a length
of conductor with each end at fixed, but different temperatures.

As I understand it, Seebeck noticed this phenomenon in single pieces of metal
bar.  This adds credibility to the proposition that the potential difference
is created in the metal and not at the junction.  I think this is correct.

The following is a simplistic explanation of how I understand the physics of
the Seebeck Effect.

In a metallic atom, freeing an electron from the valence band requires a
certain amount of energy (the work function).  For the same metallic species,
the energy to free an electron at one temperature is not the same as it is at
another temperature.  By holding a conductor's ends at two different
temperatures, a difference in work function between ends leads to a potential
difference, measurable in units of Joules per Coulomb.

If two dissimilar metals traverse the same path through space, thereby having
the same temperature at each end (and not having different temperatures at any
point along their lengths), two different potential differences are
established (one for each metal), the combination of which provide a more
readily measurable voltage.

In a thermocouple, the only reason to have the ends joined is to establish a
common "point" at the measurand and to establish an electrical "common."  If
you were to simply twist the wires together, you would still be able to
measure a voltage at the free end, though it is significantly more susceptible
to the effects of vibration and differing coefficients of expansion, making it
an unreliable junction forming method.


Regards,

Peter L. Tarver, PE
[email protected] 

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