Richard and Scott,

Interestingly, some years ago I worked on a 
project involving a reaction calorimeter. One 
use (for some customers) was to test battery 
chemistries for just this type of runaway 
condition.

The materials being tested were heated in a 
containment vessel until an exothermic 
reaction occurred. Temperature and pressure 
were both tracked throughout. The idea was 
to determine the conditions preceding a 
runaway reaction so that protection could be 
added to battery packs to keep them below 
the critical temperature and pressure.

I suspect the Li-ion failures involve a flaw in 
the protection scheme  implementation rather 
than a lack of understanding the mechanism 
of failure. In the meantime I would advise 
anyone using Lithium-ion batteries to avoid 
recharging heavily discharged ones until they 
have cooled for a while. The same goes for 
drawing high current immediately after a 
charge.

Scott B. Lacey

On 7 Jul 2008 at 22:29, Scott Xe wrote:

> Richard,
> 
> If you want to prevent the battery pack from explosion/fire, compliance of
> those standards might not accomplish it for the time being.  UL 2054, UL
> 1642 and UL 60950-1 were prepared and published before Sony's battery
> recall.  All the standards are being revised to address the issue.  After a
> large scale of Sony's battery recall, the Li-ion battery pack continues to
> explode and catch fire in a smaller scale.  The users are awaiting the new
> replacement of battery pack or a firm solution to the probable explosion of
> existing Li-ion battery pack.
> 
> Regards.
> 
> Scott
> 
> -----Original Message-----
> From: [email protected] [mailto:[email protected]] On Behalf Of
> [email protected]
> Sent: Thursday, July 03, 2008 12:24 AM
> To: [email protected]; [email protected]; [email protected]
> Subject: RE: UL 2054 testing for lithium batteries
> 
> Also.....For end use systems seeking compliance with UL 60950-1, see
> Annex P.1 with reference to cl. 4.3.8
> 
> Kaz
> [email protected]
> 
> 
> -----Original Message-----
> From: [email protected] [mailto:[email protected]] On Behalf Of Ron
> Pickard, RPQ
> Sent: Wednesday, July 02, 2008 11:07 AM
> To: 'Brian O'Connell'; '[email protected]'
> Subject: RE: UL 2054 testing for lithium batteries
> 
> Richard,
> 
>  
> 
> IMHO, if the lithium batteries are user replaceable (such as a removable
> battery pack), then they would need to be separately approved to UL
> 2054. I
> say that because in my experience, UL has required it in past Listing
> efforts of products with them. And, if this is a cell phone application,
> please note that the CTIA has recently imposed requirements for lithium
> batteries.
> 
> Supporting this, from UL2054's scope:
> 
>  
> 
> - These requirements cover portable primary (nonrechargeable) and
> secondary
> (rechargeable) batteries for use as power sources in products. These
> batteries consist of either a single electrochemical cell or two or more
> cells connected in series, parallel, or both, that convert chemical
> energy
> into electrical energy by chemical reaction.
> 
> - These requirements are intended to reduce the risk of fire or
> explosion
> when batteries are used in a product. The proper use of these batteries
> in a
> particular application is dependent on their use in a complete product
> that
> complies with the requirements applicable to such a product.
> 
> - These requirements are intended to cover batteries for general use and
> do
> not include the combination of the battery and the host product which
> are
> covered by requirements in the host product
> 
> standard.
> 
> - These requirements are also intended to reduce the risk of injury to
> persons due to fire or explosion when batteries are removed from a
> product
> to be transported, stored, or discarded.
> 
> - These requirements do not cover the toxicity risk that results from
> the
> ingestion of a battery or its contents, nor the risk of injury to
> persons
> that occurs if a battery is cut open to provide access to its contents.
> 
>  
> 
> The battery manufacturer would quite likely be already aware of all of
> this.
> They would be the one to approach for getting this work done.
> 
>  
> 
> Also, in addition to what Brian stated about shipping, the US and
> international shipping authorities have specific testing and labeling
> requirements for lithium batteries or products containing lithium
> batteries.
> Testing involves the UN T1-T8 tests.
> 
>  
> 
> IHTH.
> 
>  
> 
> Best regards,
> 
>  
> 
> Ron Pickard
> 
> RPQ Consulting
> 
> 7372 West Luke Avenue
> 
> Glendale, AZ 85303
> 
> +623.512-3451 tel, +623.848-9033 fax
> 
> [email protected]
> 
> www.rpqconsulting.com <http://www.rpqconsulting.com/> 
> 
>  
> 
> -----Original Message-----
> From: [email protected] [mailto:[email protected]] On Behalf Of Brian
> O'Connell
> Sent: Wednesday, July 02, 2008 7:21 AM
> To: '[email protected]'
> Subject: RE: UL 2054 testing for lithium batteries
> 
>  
> 
> The following are personal opinions only.
> 
>  
> 
> In general, conformity to the applicable standard is always
> 
> "necessary"; but not always 'required'. In any case, note that UL
> 
> 1642 is scoped specifically for Li batteries
> 
>  
> 
> In particular, 'it depends'. Is the charger and end-use
> 
> installation a fire or shock hazard if a battery, dies a violent
> 
> death ? Is there any normal or abnormal operating condition in
> 
> the charger or the end-use install that could result in battery
> 
> damage/explosion/fire ?
> 
>  
> 
> Also, there are separate DOT requirements for the shipment of
> 
> some types of Lithium batteries.
> 
>  
> 
> luck,
> 
> Brian 
> 
>  
> 
> -----Original Message-----
> 
> From: [email protected] [mailto:[email protected]]On Behalf Of
> 
> Gartman, Richard
> 
> Sent: Wednesday, July 02, 2008 6:51 AM
> 
> To: [email protected]
> 
> Subject: RE: UL 2054 testing for lithium batteries
> 
>  
> 
> I am looking for when UL 2054 testing is necessary for
> 
> rechargeable lithium batteries?
> 
>  
> 
> Required on cell phone batteries?
> 
> Required on consumer electronic? 
> 
>  
> 
> All perspectives on rechargeable lithium batteries are welcome.
> 
>  
> 
> Thank you 
> 
> W. Richard Gartman, MS, CSP
> 
>  
> 
> -
> 
> ----------------------------------------------------------------
> 
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