I have discussed this in the past with Jukka and he indicated
(as I expected) that the current limitations come from the
choice of ingredients that is used for these cells, to be used
mainly in moderate Western climates.
I was inquiring about the life in Asian (especially central India)
temperatures and the whole issue is a matter of having a battery
engineer choose a different combination of ingredients so that the
temp specs are shifted up. The record low temp in Hyderabad, India
on a cold winter night is 8 deg C above freezing, so there is no
problem when all temp specs are shifted up by 20 deg Celcius.
(Incidentally, 86 Fahrenheit is exactly 30 deg Celcius, so my
guess is that this test was done using the Celcius notation, which is
common in the Scientific world. Even in the USA. The reporter will have
needed to "translate" this for the US audience.)
Having a battery that works without degradation between +10 and +50 deg
C
will be beneficial in the context of warmer areas - the +30 deg C limit
as found in this study is just a choice during the formulation of the
batteries that are common today and investigated here.
Batteries that are targeted to work in Siberia, Alaska, north- and south
poles will better be designed to shift their normal temp range down by
20 deg, so that you can address different environments with different
products like it is done always if the market gets big enough to
diversify.

Regards,

Cor van de Water
Chief Scientist
Proxim Wireless Corporation http://www.proxim.com
Email: [email protected] Private: http://www.cvandewater.info
Skype: cor_van_de_water Tel: +1 408 383 7626


-----Original Message-----
From: [email protected] [mailto:[email protected]] On
Behalf Of Bill Dube
Sent: Wednesday, April 10, 2013 9:29 PM
To: Electric Vehicle Discussion List
Subject: Re: [EVDL] Ambient temperature & Lithium Ion Battery Life

With few exceptions, all chemical reactions happen faster at higher 
temperature. Thus, all batteries, including lithium-ion, age more 
quickly at elevated temperature.

         There is no magic about 86 degrees. The hotter they are, the 
quicker they age. Chemical reactions are (generally) governed by 
the  Arrhenius equation.
http://en.wikipedia.org/wiki/Arrhenius_equation


Bill D.

At 07:12 PM 4/10/2013, you wrote:
>I came across this article today mentioning that Lithium Ion battery 
>life starts to degrade faster above 86 degrees Fahrenheit.  This was 
>delivered by a Dr. Cugnet at the 245^th National Meeting & 
>Exposition of the American Chemical Society (ACS).  I am skeptical 
>that this applies to all Lithium ion chemistries.  Does anyone know 
>of Dr. Cugnet and what he is espousing??
>
>http://www.sciencedaily.com/releases/2013/04/130410103921.htm?utm_sourc
e=feedburner&utm_medium=feed&utm_campaign=Feed%3A+sciencedaily+%28Scienc
eDaily%3A+Latest+Science+News%29
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