Personally I have never had a problem using pure(distilled) water.  Once a teacher 
told me that distilled water is very bad for human babies because they absorb it into 
their systems very fast and it goes to their brain. He also told me that it is alright 
for adults because we don't have the same problem. 
 If you are very worried about your gecko just put an ice cube on top of his cage 
before misting. Using tap water in the ice cubes make sure to place it where the drops 
will not hit the glass. If it is thirsty it will drink from the ice cube droplets and 
get the minerals.

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