Agreed, one has to consider a time period, so assume one takes a day that
when injected there is no decay over this period‹so it might as well be a
second of time one takes‹so virtually instantaneous. And I¹ll assume
linearity on methane absorption and logarithmic for CO2.

So, for methane, humans have caused an increase of roughly 1000 ppb which
converts to about 3 GtCH4, and this causes a forcing of about 0.5 W/m**2 (at
the tropopause) per IPCC.

For CO2, we know that a doubling (so we¹ll say from 300 to 600 ppm so we are
in the range of interest) causes a forcing of about 3.6 W/m**2 (at the
tropopause). So, 300 ppm of CO2 in the atmosphere is roughly 600 GtC or 2200
GtCO2 (and global warming potential is done for CO2, I believe.

So, if we take the ratio of forcing to mass for CH4 divided by the ratio of
forcing to mass for CO2, we get a rough estimate of the instantaneous GWP,
so

[0.5/3]/[3.6/2200] equals roughly 100

for the ratio at t=0 (so allowing for no decay) of the radiative forcing
caused by a unit mass of CH4 added to the atmosphere to a unit mass of CO2
added to the atmosphere.

Not exact, but plausible.

Mike




On 11/16/09 3:42 AM, "Peter Read" <[email protected]> wrote:

> John, Andrew
> Re "BTW, does anybody know the _immediate_ warming potential of methane?"
> Someone will correct me no doubt but my understanding is that warming is a
> rate process measured in W/m^2
> So "instantaneous" [[== "immediate"?]] warming is an incorrect concept
> Unless it continues for a second, a week, a year, 25 years, for whatever, no
> warming takes place.
> So it is necessary to multiply by a duration to get joules/m^2
> It's how many joules get into the low albedo meltwater on top of Greenland's
> ice that decides how much gets melted each year to fall down crevasses and
> lubricate the eventual collapse of large areas of ice into the oceans.
> Meaning that the integral [[roughly]] under the CO2 level curve is what
> matters [multiplied by the warming potential over that period]  when it comes
> to measuring threats of Greenland's collapse
> So the key issue is duration - how long elevated greenhouse gas levels last
> and how to get them down.
> Think that's right
> Peter
>>  
>> ----- Original Message -----
>>  
>> From:  John Nissen <mailto:[email protected]>
>>  
>> To: [email protected]
>>  
>> Cc: geoengineering <mailto:[email protected]>
>>  
>> Sent: Monday, November 16, 2009 6:18  PM
>>  
>> Subject: Re: [geo] Re: Rejected - a  simple argument for SRM geoengineering
>>  
>> 
>> 
>> Hi Andrew,
>> 
>> You say:  "I don't oppose John's argument, but the evidence on the severity
>> of the  problem is far from conclusive."  I disagree.
>> 
>> The methane presents  a very real risk - because of the uncertainty on timing
>> combined with the  potential size of methane discharge - perhaps even enough
>> to cause thermal  runaway due to positive feedback, as is thought to have
>> happened in the past  [1].  Risk management involves identifying events and
>> assessing them in  terms of their likelihood and magnitude of impact [2].
>> Thus something  with a small likelihood (such as rapid massive methane
>> excursion) can have a  high risk, if the magnitude of impact is sufficiently
>> large (and you can't get  much larger than thermal runaway).
>> 
>> It is possible that much or most of  the methane trapped in frozen structures
>> has built up over hundreds of  thousands of years.  There is little sign of
>> massive methane discharge in  the ice record. In fact methane seems to track
>> the temperature even better  than CO2 [3].
>> 
>> But of course methane discharge is not the only high risk  event - there is
>> also the Greenland ice sheet disintegration.
>> 
>> BTW, does anybody know the _immediate_ warming potential of methane,  as
>> opposed to the 20 year value (72), 100 years (25) or 500 years (7.6)?   The
>> lifetime is only 12 +/- 3 years.  See  [4].
>> 
>> Cheers,
>> 
>> John
>> 
>> [1] http://en.wikipedia.org/wiki/Clathrate_gun_hypothesis
>> 
>> [2]  http://en.wikipedia.org/wiki/Enterprise_risk_management
>> 
>> [3] http://answers.yahoo.com/question/index?qid=20090329215018AAxqYFk
>> 
>> [4] http://en.wikipedia.org/wiki/Greenhouse_gas
>> 
>> ---
>> 
>> Andrew Lockley wrote:
>>> At present the likely methane excursion is far from clear.   Further, it is
>>> also unclear how quickly the total excursion will  occur.  The excursion
>>> rate is highly significant due to the short life  of methane in the
>>> atmosphere.  The methane ends up as CO2, in itself a  major issue.  However,
>>> the CO2's likely effect is nothing compared to  the devastating temperature
>>> spike which may result from a sudden methane  excursion.
>>> 
>>>  
>>> I don't oppose John's argument, but the evidence on the severity of the
>>> problem is far from conclusive.  We need much more research into:
>>>  
>>> 1)  The methane reservoir in clathrates and permafrost
>>>  
>>> 2) The size of potential methane sources currently frozen as organic
>>> detritus
>>>  
>>> 3) The likely changes to the GWP of methane in future atmospheres, as  the
>>> levels of hydroxyl radicals etc. shift over time and as a direct result  of
>>> methane excursion.  Recent research on this asks more questions than  it
>>> answers.
>>>  
>>> 
>>>  
>>> My personal feeling is that the range of likely outcomes is from a
>>> significant amplification of AGW, right up to a 'Great Dying' sized
>>> mass-extinction event when we come within a sneeze of sterilising the entire
>>> planet.  I'd be tempted to bet on the latter, but I wouldn't be around  to
>>> collect the winnings, so I'll keep my wallet in my pocket.
>>>  
>>> 
>>>  
>>> My suggestions is that geoengineers look at ways to clean up the  methane
>>> from the atmosphere, and then lock down the resulting carbon.   My guess is
>>> we've got about 50 years to do this, but virtually no time  at all if the
>>> methane can't be dealt with once it's in the atmosphere.  Therefore, I'd
>>> support John out of precautionary principle-based  reasoning.
>>>  
>>> 
>>>  
>>> A
>>> 
>>>  
>>> 2009/11/15 jim woolridge <[email protected]>
>>>  
>>>> Nice one, John; the train of argument is clear (of  limpid clarity, in
>>>> fact!)  The problem is that the people and  institutions addressed are
>>>> in the business of politics, the art of the  possible, rather than in
>>>> the business of logical evaluation.  They  hear what you are saying and
>>>> must see the validity of it. But  politically what is true and what is
>>>> doable do not always coincide, as  we all know from as many examples as
>>>> one cares to ennumerate.
>>>> 
>>>> We  have to keep hammering away at the arguments, to the point at  which
>>>> they are generally understood and accepted, and also keep  on
>>>> politicking in the sure and certain hope that eventually  the
>>>> acceptance of the arguments and the cowardice/caution/horse  sense/
>>>> opportunistic careerism of the politicos will achieve the right  kind
>>>> of intersection.  In the next year or so (& wouldn't it  be a great
>>>> help to have the environmental NGOs on board.)
>>>>  
>>>>  
>>>> 
>>>> On Nov 12, 10:51 pm, John Nissen <[email protected]> wrote:
>>>>> > It is  incredible. It is so obvious.
>>>>> >
>>>>> > 1. Global warming is driven  largely by atmospheric CO2 according to the
>>>>> > concentration above  its pre-industrial level; and
>>>>> >
>>>>> > 2. After emissions are  stopped it could take millenia for the
>>>>> > concentration to fall back  to that level, because the effective
>>>>> lifetime
>>>>> > of some of that  excess CO2 is many thousands of years.
>>>>> >
>>>>> > Therefore:
>>>>> >  3.  Drastic emissions reduction, even to zero overnight, cannot and
>>>>> will
>>>>> > not stop the Arctic continuing to warm for  decades.
>>>>> >
>>>>> > Therefore:
>>>>> > 4. The Arctic sea ice will  continue to retreat, accelerating the
>>>>> warming
>>>>> > due to the albedo  effect.
>>>>> >
>>>>> > Therefore:
>>>>> > 5.  The permafrost will  continue to thaw releasing increasing
>>>>> quantities
>>>>> > of methane, a  potent greenhouse gas, potentially adding many degrees to
>>>>> > global  warming; and
>>>>> >
>>>>> > 6.  The Greenland ice sheet will become  increasingly unstable,
>>>>> > potentially contributing to an eventual sea  level rise of 7 metres.
>>>>> >
>>>>> > Therefore:
>>>>> > 7.  To  avoid these two catastrophes, we need to cool the Arctic quickly
>>>>> >  enough to save the Arctic sea ice; and
>>>>> >
>>>>> > 8.  Probably  the only feasible way to do this is through solar
>>>>> radiation
>>>>> >  management (SRM) geoengineering.
>>>>> >
>>>>> > 9.  SRM is not a  last resort, it is needed now to cool the Arctic.
>>>>> >
>>>>> > It is  incredible that people do not seem to follow this train of logic
-
>>>>> >  it is so obvious.
>>>>> >
>>>>> > Yet when I challenged a panel of  geoengineering experts to refute this
>>>>> > argument, the response was  that geoengineering (even just to cool the
>>>>> > Arctic) was too  dangerous - not that the argument was false! [1]
>>>>> >
>>>>> > So we  continue to hear politicians and their advisers claiming that
>>>>> >  emissions reduction alone can be sufficient to keep the planet safe.
>>>>> [2]
>>>>> >
>>>>> > And we continue to hear geoengineering experts saying  that
>>>>> > geoengineering should only be used as a last resort.  [3]
>>>>> >
>>>>> > How can this mindset be changed quickly, to avoid  leaving
>>>>> geoengineering
>>>>> > too late?
>>>>> >
>>>>> >  John
>>>>> >
>>>>> > P.S. Apologies to those who have heard this all  before and accept the
>>>>> > logic as self-evident.
>>>>> >
>>>>> > [1]   This challenge was put to the panel at the launch of the  Royal
>>>>> > Society geoengineering report, on September 1st, with  response from the
>>>>> > team leader and panel chairman, Professor John  Shepherd.
>>>>> >
>>>>> > [2]  For example at the geoengineering  hearing at the House of Commons,
>>>>> > November 2008.
>>>>> >
>>>>> >  [3] For example at the congressional hearing on geoengineering,
>>>>> November
>>>>> > 2009.
>>>> 
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>>>> 
>>> 
>>>  
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