*It’s hard to see how the energy cost of the ocean alkalinity scheme can get
much below the cost of CaCO3 calcination .

*What about using power plant flue gases to dissolve carbonates? That seems
to be an ocean alkalinity scheme that has energy costs well below
calcination.



___________________________________________________
Ken Caldeira

Carnegie Institution Dept of Global Ecology
260 Panama Street, Stanford, CA 94305 USA

[email protected]
http://dge.stanford.edu/DGE/CIWDGE/labs/caldeiralab
+1 650 704 7212; fax: +1 650 462 5968




On Fri, Dec 11, 2009 at 11:33 AM, David Keith <[email protected]> wrote:

>  Greg,
>
>
>
> To me it’s just the common definition; I did not intend to say anything
> about relative merits. The topic was air capture and that seem enough for
> one article. I think the geochemical approaches that involve adding
> alkalinity to the oceans are worth serious work that’s why I wrote the
> article geochemical carbon management article. I have also pushed this idea
> onto agendas at various research planning meetings (e.g., the NAS advanced
> sequestration meeting), and we have considered adapting calcination
> technology we develop for air capture to the CaO or MgO scheme though we are
> not putting serious work into it.
>
>
>
> In my view there is no way to make a simple choice between them. There are
> significant technical and institutional and governance challenges with
> adding alkalinity to the ocean. On the other hand, restoring PH could be a
> direct local environmental benefit.
>
>
>
> It’s hard to see how the energy cost of the ocean alkalinity scheme can get
> much below the cost of CaCO3 calcination and the electrochemical schemes are
> expensive. One might argue, then, that air capture has lower theoretical
> energy cost (10’s of kJ/mol vs 100’s) but no one knows how to make the low
> energy AC work at low cost.
>
>
>
> Bottom line: real development work is needed on both; they should be linked
> where appropriate; and finally, it’s far too early to pick winners.
>
>
>
> I know about the APS work, but I will reserve comments until it’s out. The
> real test will be in a few years when serious end-to-end engineering cost
> estimates are made public.
>
>
>
> Yours,
>
> D
>
>
>
>
>
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