Thanks Oliver.

I'm posting your comments to the geoengineering group with the questions you raise:

1. Could the CDM be used to fund, or help fund, our pilot project to trial various techniques for tackling the Arctic methane problem? Could it subsequently fund deployment of selected techniques?

2.  Is there any way to enhance HO hydroxyl in the atmosphere?

Cheers,

John

---

On 25/07/2011 17:52, Oliver Tickell wrote:
Certainly it makes sense to do something about large, concentrated methane emissions where it is realistic to capture the gas and burn it off, or use it for heat / power.

Does the CDM currently provide credits for methane projects of this type? I believe it does for methane from pig farms etc so there is no obvious reason why it should not.

Another approach would be to enhance HO hydroxyl in the atmosphere - the main destroyer of methane. I have no idea how to set about doing this. It could be helpful to reduce emissions that utilise existing hydroxyl, such as miscellaneous hydrocarbons. But the chemistry is complex and it is hard to strictly follow through any intervention to its end results!

Oliver.
--
Oliver Tickell
On 25/07/2011 15:09, Veli Albert Kallio wrote:
I think definitely that we can prevent on-shore methane explosions, and saturated methane laden water pockets that are approaching nucleating point.

There are 3 types of methane leaking:

1) generic leaking of methane from melting permafrost over large areas that provide widespread methane haze 2) spot type ongoing methane leaking from permaforst or onshore gas fields that are losing their subterranean gas compression due to ruptures. 3) explosive methane eruptions (methane clatrates, Lake Cheko's conical basin gas field failure in Tunguska 1908 as river fell into gas field and drove methane out).

No. 1 you cannot control. No. 2 depends on how big and focused the leaking is, there are vast bubbling spots, in Azerbaijan there are flaming mountains where gas comes out of rocks. These you can control. No. 3 can be controlled by method of Professor Michel Halbwachs. Often methane can be spotted as a very focused leak on sea floor which might be possible to cap. So, I think the idea is valid in certain cases, in other cases it may not be workable.


------------------------------------------------------------------------
Date: Mon, 25 Jul 2011 11:28:12 +0100
From: [email protected]
Subject: Re: Arctic methane workshop, London, 15-16th October CONFIRMED
To: [email protected]

John, I think you are on a hiding to nothing trying to trap or destroy the methane.

The reason is simple - the emissions are spread over such a vast area of many millions of sq.km. Even to trap and destroy the methane emissions from 1sq.km would be a fantastically difficult and expensive task.

So you can simplify things by just ruling this one out at the start!

Oliver.
--
Oliver Tickell
On 22/07/2011 18:29, John Nissen wrote:


    Dear all,

    In case you were not aware, the workshop, which was to have been
    3-4th September, is now going to be on 15-16th October.  Here is
    the background and purpose of the workshop...

    A group of scientists and engineers (including myself) is deeply
    concerned about the potential of methane from thawing permafrost
    in the Arctic to cause irreversible, catastrophic and
    unsurvivable global warming.   Major factors are the unexpectedly
    rapid retreat of sea ice [1] and the unexpectedly large
    quantities of carbon which might be emitted as methane [2].  In
    June 2010 we wrote an open letter to Obama's scientific adviser,
    Dr John Holdren, suggesting action was urgently needed to address
    the methane issue [3].   Some sea ice experts, including
    Professor Peter Wadhams in our group, now reckon the Arctic Ocean
    will very likely become seasonably ice free this decade if there
    is no action to cool the Arctic.

    Recently Peter Wadhams has drawn my attention to work of Natalia
    Shakhova with Igor Semiletov on East Siberian Arctic Shelf (ESAS)
    - particularly concerning the present large emissions of methane
    and the possibility of release of much larger quantities "at any
    time".   So we have been wondering whether anything can be done
    quickly to reduce this methane threat.   We have been discussing
    possible action, and plan further brainstorming at a workshop in
    October in London.

    We are hoping this workshop will lead on to a pilot project to
    trial the most promising techniques.  Here is an extract from the
    proposal, concerning management of the methane environment at the
    local level (e.g. in ESAS):

    [begin quote]

    Approaches can be categorised according to where the intervention
    action takes place.Where the methane is from lake or sea bed, the
    action could be:

        * below the permafrost, where there may already be methane or
          methane hydrate;
        * in the permafrost, or to plug gaps in the permafrost where
          methane is rising;
        * in the bed of the sea or lake, above the permafrost layer;
        * in the water at the bottom of the sea or lake;
        * at the surface of the sea or lake, and below any ice;
        * at the point of emergence of methane into the atmosphere.


    In the case of methane from wetlands, some of the above actions
    would be relevant to ponds, commonly forming above permafrost and
    emitting most of the wetlands methane.There is also the
    possibility of pond drainage as a means to reduce methane emissions.

    Returning to the case of lakes and deeper water, the problem with
    trying to deal with methane below the permafrost is that any
    disturbance is liable to trigger an eruption of methane through
    gaps in permafrost known as taliks.Commercial methods of
    extraction of natural gas can be used when there is in
    impermeable layer above the gas, but cannot be applied in our
    situation because of the danger either from puncture of the
    permafrost or from enlarging existing taliks.

    In the bed of the sea or lake there may be aerobic microbes,
    capable of ‘digesting’ the methane and converting it into less
    harmful products.Supply of oxygen and nutrients to such microbes
    could be helpful.Microbes may also congregate in a ‘biotic layer’
    at the bottom of the sea or lake.These could be boosted or
    encouraged to proliferate.

    Methane can dissolve in the water.At atmospheric pressure and
    freezing point, 0.04 grams of methane will dissolve in a litre of
    water.Therefore one approach could be to extract the water when
    it is nearly saturated with methane.A more commercial approach
    would be to use a specific methane solvent in a relatively heavy
    layer, resting on the seabed (or lake bed).From time to time the
    solvent would be extracted, scrubbed to remove the methane, and
    replaced.A major issue could be containing the solvent and making
    sure there was no long-term harm to the marine habitat.

    A general problem with emissions of soluble gas from the beds of
    lakes and shallow seas is that the water column can become
    unstable – with the dissolved gases coming out of solution,
    leading to a sometime violent upwelling.Because of the low
    density of the rising column of bubble-filled water, ships on the
    surface can sink!Furthermore any turnover of the water allows
    warmer surface water to be transported towards the bottom, which
    can lead to permafrost melt and enhanced methane production.Thus
    any underwater approach to methane must take into account the
    stability of the water column.

    However if the methane is already bubbling to the surface, then
    one could consider capturing it before it escapes into the
    atmosphere.One way would be to use ice, which will anyway be
    present in winter.The methane collects under the ice, and boring
    through the ice, one could collect the methane that emerges.The
    problem would be keeping an intact layer of ice throughout the
    year.Therefore one might consider strengthening the ice to
    produce ‘pykrete’ [3].However a more promising approach would be
    to have mats, preferably of methane-absorbing substance
    (biological or chemical) which could be harvested to collect the
    methane.But care would be needed not to deplete oxygen from water
    underneath the mats, since oxygen is required from the important
    methane-digesting microbes in any biotic layer that has formed
    above the sea or lake bed.

    If and when some methane bursts into the atmosphere, it could be
    burnt or ‘flared’.In remote areas, and in open water, this could
    be problematic.Furthermore, methane only burns in air at between
    5% and 15% concentration by volume.As it disperses quickly, one
    would need to torch the methane within a few seconds of
    eruption.It is almost impossible to imagine how this could be
    done in a remote location, unless the methane is laser-zapped
    from a monitoring satellite!

    [end quote]

    The pilot project will promote a three-prong attack, though
    trials will focus on local action (particular item 2):

    1. cooling the Arctic, regionally or locally, using SRM
    geoengineering;
    2. management of the methane environment at the local level (see
    quoted text above);
    3. capture or destruction of methane, already in the atmosphere.

    The capture or destruction of methane in the atmosphere is a last
    resort, if other approaches fail.  It would also be vital if
    there were a sudden large emission of methane with serious
    warming potential.Such "air capture" or destruction could be
    local or not.  The advantage of local air capture is that
    efficiency may be improved through having the methane at higher
    concentration (as the efficiency is for CO2 air capture).

    The workshop is intended as a brainstorming session to establish
    the most promising techniques which might be trialled in the
    pilot project.   If you have already expressed an interest in
attending the workshop, please confirm that the new date is OK. If you have not yet expressed an interest, and would like to
    attend, let me know.

    John Nissen

    Chiswick, London W4

    [1] Copenhagen Diagnosis, 2009
    http://www.ccrc.unsw.edu.au/Copenhagen/Copenhagen_Diagnosis_LOW.pdf
    see figure 13 page 30.

    [2] Ibid, see page 21 - referring to Shuur et al 2008.

    [3]
    
http://geo-engineering.blogspot.com/2010/06/sea-ice-loss-stuns-scientists.html





--
You received this message because you are subscribed to the Google Groups 
"geoengineering" group.
To post to this group, send email to [email protected].
To unsubscribe from this group, send email to 
[email protected].
For more options, visit this group at 
http://groups.google.com/group/geoengineering?hl=en.

Reply via email to