Which groups are able to run a chemistry column model? If it's not been
done, it's a glaring omission in the science.

On a similar modelling note, does anyone know a group which does modelling
of monoterpenes? I had an idea to genetically modify trees, which I'd like
to test.

A
On 28 Jul 2014 06:45, "Govindasamy Bala" <[email protected]> wrote:

> Hi Nathan,
>
> The changes to amount of water vapor in the lower stratosphere, like in
> the troposphere, is likely controlled by the stratospheric temperature
> change. i.e. follows C-C relationship. Therefore, the source mechanism for
> H2O in the low stratosphere may not be that important. I do agree that a
> full climate-chemistry investigation is still lacking for aerosol
> geoengineering!
>
>
> On Sun, Jul 27, 2014 at 8:40 PM, Nathan Currier <[email protected]>
> wrote:
>
>>
>>
>> Hi, Ken –
>>
>> Thanks much for your response. Of course I see how you meant this, and I
>> don’t really disagree as long as it’s clearly stated that, given the
>> successful achievement of the same radiative forcing impacts with the two
>> approaches, then there’s not much difference between the SRM and turning
>> down the sun. What I was saying – and, as I said, it was more question than
>> comment – grows out of a general sense that we should all still be looking
>> for any possible ways that one might not successfully achieve the forcing
>> impacts currently assumed, for some reason or another.
>>
>> So, while you write that the surface temperature is not “super sensitive
>> to changes in the stratosphere,” I was referencing one of the possible ways
>> in which the surface apparently can be quite sensitive to such changes: for
>> me, at least, when I first heard of the Solomon et al paper a few years
>> back, what first popped out at me was how, with so little H2O up in the
>> stratosphere, changes in it could have such huge impacts on surface
>> temperature, comparable with changes in CO2 forcing, I think, over the same
>> period. Then later I began wondering whether stratospheric SRM techniques
>> could impact this stratospheric hydrology, as opposed to the much more
>> frequently discussed surface hydrology SRM impacts.
>>
>> So, that’s why I brought up the methane issue, since there clearly is an
>> interaction at the surface between sulfur chemistry and methane oxidation,
>> and methane is very clearly an important source of H2O to the stratosphere.
>> Luckily, the methane doesn’t seem to be getting oxidized in the right place
>> to have such a big impact, but could *that* somehow or another get
>> shifted if you add a bunch of sulfur to the stratosphere? Again, it was
>> really a question, where I was asking: have such possibilities been
>> explored?
>>
>> Cheers,
>>
>>
>> Nathan
>>
>>
>>
>>
>>
>> On Saturday, July 26, 2014 3:01:47 PM UTC-4, kcaldeira wrote:
>>
>>> Nathan,
>>>
>>> Your questions are interesting but your initial statement is not true
>>> when it comes to first order effects on surface temperature and hydrology.
>>> [".. the similarity ("turning down the sun" and the SRM) depends on the
>>> ability of the models to reproduce, among other things, the stratospheric
>>> chemistry correctly. "]
>>>
>>> Surface temperature and hydrology is not super sensitive to changes in
>>> the stratosphere. Key is getting the effective radiative forcing right both
>>> in terms of total amount and latitudinal distribution.
>>>
>>> To repeat what I said in the previous email:
>>>
>>> *Of course, what tool you use depends on your goals in using a tool. The
>>> attached paper shows results indicating that for many purposes, "turning
>>> down the sun" is a clear and efficient way of simulating many aspects of
>>> solar geoengineering.*
>>>
>>> *If you are looking at effects on the stratosphere or looking at effects
>>> of diffuse radiation, then you would need to simulate aerosols, but if you
>>> are just trying to get an idea of temperature and hydrological changes,
>>> then it seems that "turning down the sun" does a pretty good job.*
>>>
>>> Best,
>>>
>>> Ken
>>>
>>> _______________
>>> Ken Caldeira
>>>
>>> Carnegie Institution for Science
>>>  Dept of Global Ecology
>>> 260 Panama Street, Stanford, CA 94305 USA
>>> +1 650 704 7212 [email protected]
>>> http://dge.stanford.edu/labs/caldeiralab
>>> https://twitter.com/KenCaldeira
>>>
>>> Assistant:  Dawn Ross <[email protected]>
>>>
>>>
>>>
>>> On Sat, Jul 26, 2014 at 10:57 AM, Nathan Currier <[email protected]>
>>> wrote:
>>>
>>>>  This is more question than comment, but it seem to go without saying
>>>> that the similarity ("turning down the sun" and the SRM) depends on the
>>>> ability of the models to reproduce, among other things, the stratospheric
>>>> chemistry correctly.
>>>>
>>>> Solomon et al, 2010* (see below) concerned the hugely under-represented
>>>> impacts of stratospheric water vapor on surfacing warming, and suggested
>>>> increased stratospheric water vapor might have accounted for 30% of global
>>>> warming in the 90s. They also noted:
>>>>
>>>> Current global climate models simulate lower-stratospheric temperature
>>>> trends poorly, and even up-to-date stratospheric chemistry-climate models
>>>> do not consistently reproduce tropical tropopause minimum temperatures or
>>>> recently observed changes in stratospheric water vapor.
>>>>
>>>>
>>>>
>>>> Their paper only dealt with changes in one of the two ways that the
>>>> stratosphere gets its water vapor, but I’ve often wondered about the
>>>> potential impacts of sulfur SRM on the other one – that is, stratospheric
>>>> methane. Solomon et al, while suggesting that methane’s role is relatively
>>>> weak in H2O creation near the tropopause (where it apparently counts most
>>>> for surface warming), noted:
>>>>
>>>> Estimates of the forcing due to (stratospheric) methane oxidation have
>>>> varied widely among different studies, perhaps because of different shapes
>>>> of the water profile in the region of greatest sensitivity.
>>>>
>>>>
>>>> One of my questions has been whether prolonged use of stratospheric
>>>> sulfur SRM, unlike the sudden pulse of a volcano, could potentially give
>>>> rise to analogous “competitive” reactions to those seen in the troposphere
>>>> involving sulfur chemistry and methane hydroxylation (i.e., Shindell et al
>>>> 2007, 2009, 2012, etc), one of the factors that have driven our assumed
>>>> increase in the indirect forcing effects of methane over the last half
>>>> decade.
>>>>
>>>> I wonder, if additions of sulfur did actually lead, at the decadal
>>>> scale of the methane lifetime, to increases in stratospheric H2O, what
>>>> could its maximum impact be? What percentage of all stratospheric H2O comes
>>>> from methane, in the first place? Does current SRM modeling account for
>>>> such possible interactions?
>>>>
>>>> Best,
>>>>
>>>> Nathan
>>>>
>>>>
>>>>
>>>> *Solomon et al 2010:
>>>>
>>>>
>>>>
>>>> abstract
>>>> http://www.sciencemag.org/content/327/5970/1219.abstract
>>>>
>>>> full paper
>>>> http://www.climate.unibe.ch/~plattner/papers/solomon10sci.pdf
>>>>
>>>> discussions of, from NOAA & RealClimate:
>>>> http://www.noaanews.noaa.gov/stories2010/20100128_watervapor.html
>>>>
>>>> http://www.realclimate.org/index.php/archives/2010/01/
>>>> the-wisdom-of-solomon/
>>>>
>>>>
>>>>
>>>> On Friday, July 25, 2014 11:39:52 AM UTC-4, kcaldeira wrote:
>>>>
>>>>> Folks,
>>>>>
>>>>> Andrew wrote something the other day about "turning down the sun"
>>>>> experiments NOT being a good analogue for stratospheric aerosol
>>>>> geoengineering.
>>>>>
>>>>> Of course, what tool you use depends on your goals in using a tool.
>>>>> The attached paper shows results indicating that for many purposes,
>>>>> "turning down the sun" is a clear and efficient way of simulating many
>>>>> aspects of solar geoengineering.
>>>>>
>>>>> If you are looking at effects on the stratosphere or looking at
>>>>> effects of diffuse radiation, then you would need to simulate aerosols, 
>>>>> but
>>>>> if you are just trying to get an idea of temperature and hydrological
>>>>> changes, then it seems that "turning down the sun" does a pretty good job.
>>>>>
>>>>> Enjoy,
>>>>>
>>>>> Ken
>>>>>
>>>>>
>>>>> http://link.springer.com/article/10.1007/s00382-014-2240-3
>>>>>
>>>>>
>>>>>
>>>>> *Modeling of solar radiation management: a comparisonof simulations
>>>>> using reduced solar constant and stratospheric sulphate aerosols*
>>>>>
>>>>> Sirisha Kalidindi · Govindasamy Bala ·
>>>>> Angshuman Modak · Ken Caldeira
>>>>>
>>>>>
>>>>> Abstract The climatic effects of Solar Radiation Management
>>>>> (SRM) geoengineering have been often modeled
>>>>> by simply reducing the solar constant. This is most likely
>>>>> valid only for space sunshades and not for atmosphere and
>>>>> surface based SRM methods. In this study, a global climate
>>>>> model is used to evaluate the differences in the climate
>>>>> response to SRM by uniform solar constant reduction and
>>>>> stratospheric aerosols. Our analysis shows that when global
>>>>> mean warming from a doubling of CO2 is nearly cancelled
>>>>> by both these methods, they are similar when important
>>>>> surface and tropospheric climate variables are considered.
>>>>> However, a difference of 1 K in the global mean stratospheric
>>>>> (61–9.8 hPa) temperature is simulated between the
>>>>> two SRM methods. Further, while the global mean surface
>>>>> diffuse radiation increases by ~23 % and direct radiation
>>>>> decreases by about 9 % in the case of sulphate aerosol
>>>>> SRM method, both direct and diffuse radiation decrease by
>>>>> similar fractional amounts (~1.0 %) when solar constant
>>>>> is reduced. When CO2 fertilization effects from elevated
>>>>> CO2 concentration levels are removed, the contribution
>>>>> from shaded leaves to gross primary productivity (GPP)
>>>>> increases by 1.8 % in aerosol SRM because of increased
>>>>> diffuse light. However, this increase is almost offset by
>>>>> a 15.2 % decline in sunlit contribution due to reduced
>>>>> direct light. Overall both the SRM simulations show similar
>>>>> decrease in GPP (~8 %) and net primary productivity
>>>>> (~3 %). Based on our results we conclude that the climate
>>>>> states produced by a reduction in solar constant and addition
>>>>> of aerosols into the stratosphere can be considered
>>>>> almost similar except for two important aspects: stratospheric
>>>>> temperature change and the consequent implications
>>>>> for the dynamics and the chemistry of the stratosphere
>>>>> and the partitioning of direct versus diffuse radiation reaching
>>>>> the surface. Further, the likely dependence of global
>>>>> hydrological cycle response on aerosol particle size and the
>>>>> latitudinal and height distribution of aerosols is discussed.
>>>>> _______________
>>>>> Ken Caldeira
>>>>>
>>>>> Carnegie Institution for Science
>>>>> Dept of Global Ecology
>>>>> 260 Panama Street, Stanford, CA 94305 USA
>>>>>  +1 650 704 7212 [email protected]
>>>>> http://dge.stanford.edu/labs/caldeiralab
>>>>> https://twitter.com/KenCaldeira
>>>>>
>>>>> Assistant:  Dawn Ross <[email protected]>
>>>>>
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>>>
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>
>
>
> --
> Best wishes,
>
> -------------------------------------------------------------------
> G. Bala
> Professor
> Center for Atmospheric and Oceanic Sciences
> Indian Institute of Science
> Bangalore - 560 012
> India
>
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