On the Weyburn leak claims, these were promptly investigated and determined to 
not be related to the Weyburn field operations.  See a summary here:  
http://switchboard.nrdc.org/blogs/bmordick/investigations_find_no_evidenc.html


Sent from my iPad

On Oct 17, 2014, at 6:58 AM, Schuiling, R.D. (Olaf) 
<[email protected]<mailto:[email protected]>> wrote:

Researchers also calculated that the CO2 pumped into the Weyburn field could 
never escape. Fortunately it is a very thinly populated area so only a number 
of cattle and wild animals died when it started to leak. I am not claiming that 
all potential CCS would start to leak, but there are safer ways to capture CO2. 
There is no reason to capture CO2 from coal fired plants, you can capture it 
anywhere, so go for the safest and cheapest solution(see attachment), Olaf 
Schuiling

From: [email protected]<mailto:[email protected]> 
[mailto:[email protected]] On Behalf Of Andrew Lockley
Sent: donderdag 16 oktober 2014 16:52
To: geoengineering
Subject: [geo] Storing greenhouse gas underground--for a million years | 
Science/AAAS | News


http://news.sciencemag.org/chemistry/2014/10/storing-greenhouse-gas-underground-million-years

MARC HESSE

Storing greenhouse gas underground--for a million years

When Canada switched on its Boundary Dam power plant earlier this month, it 
signaled a new front in the war against climate change. The commercial turbine 
burns coal, the dirtiest of fossil fuels, but it traps nearly all the resulting 
carbon dioxide underground before it reaches the atmosphere. Part of this 
greenhouse gas is pumped into porous, water-bearing underground rock layers. 
Now, a new study provides the first field evidence that CO2 can be stored 
safely for a million years in these saline aquifers, assuaging worries that the 
gas might escape back into the atmosphere."

It's a very comprehensive piece of work," says geochemist Stuart Gilfillan of 
the University of Edinburgh in the United Kingdom, who was not involved in the 
study. "The approach is very novel."

There have been several attempts to capture the carbon dioxide released by the 
world's 7000-plus coal-fired plants. Pilot projects in Algeria, Japan, and 
Norway indicate that CO2can be stored in underground geologic formations such 
as depleted oil and gas reservoirs, deep coal seams, and saline aquifers. In 
the United States, saline aquifers are believed to have the largest capacity 
for CO2 storage, with potential sites spread out across the country, and 
several in western states such as Colorado also host large coal power plants. 
CO2 pumped into these formations are sealed under impermeable cap rocks, where 
it gradually dissolves into the salty water and mineralizes. Some researchers 
suggest the aquifers have enough capacity to store a century's worth of 
emissions from America's coal-fired plants, but others worry the gas can leak 
back into the air through fractures too small to detect.

To resolve the dilemma, geoscientists need to know how long it takes for the 
trapped CO2 to dissolve. The faster the CO2 dissolves and mineralizes, the less 
risk that it would leak back into the atmosphere. But determining the rate of 
dissolution is no easy feat. Lab simulations suggest that the sealed gas could 
completely dissolve over 10,000 years, a process too slow to be tested 
empirically.

So computational geoscientist Marc Hesse of the University of Texas, Austin, 
and colleagues turned to a natural lab: the Bravo Dome gas field in New Mexico, 
one of the world's largest natural CO2 reservoirs. Ancient volcanic activities 
there have pumped the gas into a saline aquifer 700 meters underground. Since 
the 1980s, oil companies have drilled hundreds of wells there to extract the 
gas for enhanced oil recovery, leaving a wealth of data on the site's geology 
and CO2storage.

To find out how fast CO2 dissolves in the aquifers, the researchers needed to 
know two things: the total amount of gas dissolved at the reservoir and how 
long it has been there. Because the gas is volcanic in origin, the researchers 
reasoned that it must have arrived at Bravo Dome steaming hot--enough to warm 
up the surrounding rocks. So they examined the buildup of radiogenic elements 
in the mineral apatite. These elements accumulate at low temperatures, but are 
released if the mineral is heated above 75°C, allowing the researchers to 
determine when the mineral was last heated above such a high temperature. The 
team estimated that the CO2 was pumped into the reservoir about 1.2 million 
years ago.Then the scientists calculated the amount of gas dissolved over the 
millennia, using the helium-3 isotope as a tracer. Like CO2, helium-3 is 
released during volcanic eruptions, and it is rather insoluble in saline water. 
By studying how the ratio of helium-3 to CO2 changes across the reservoir, the 
researchers found that out of the 1.6 gigatons of gas trapped underground at 
the reservoir,only a fifth has dissolved over 1.2 million years. That's the 
equivalent of 75 years of emissions from a single 500-megawatt coal power 
plant, they report online this week in the Proceedings of the National Academy 
of Sciences.

More intriguingly, the analysis also provided the first field evidence of how 
CO2 dissolves after it is pumped into the aquifers. In theory, the CO2 
dissolves through diffusion, which takes place when the gas comes into contact 
with the water surface. But the process could move faster if convection--in 
which water saturated with CO2 sinks and fresh water flows into its place to 
absorb more gas--were also at work. Analysis revealed that at Bravo Dome, 10% 
of the total gas at the reservoir dissolved after the initial emplacement. 
Diffusion alone cannot account for that amount, the researchers argue, as the 
gas accumulating at the top of the reservoir would have quickly saturated still 
water. Instead, convection most likely occurred.Hesse says constraints on 
convection might explain why CO2 dissolves much more slowly in saline aquifers 
at Bravo Dome than previously estimated, at a rate of 0.1 gram per square meter 
per year. The culprit would be the relatively impermeable Brava Dome rocks, 
which limit water flow and thus the rate of convective CO2 dissolution. At 
storage sites with more porous rocks, the gas could dissolve much faster and 
mineralize earlier, he says.Even so, the fact that CO2 stayed locked up 
underground for so long at Bravo Dome despite ongoing industrial drilling 
should allay concerns about potential leakage, Hesse says. Carbon capture and 
storage "can work, if you do it in the right place," he says. "[This is] an 
enormous amount of CO2 that has sat there, for all we can tell, very peacefully 
for more than a million years."

Posted in Chemistry, Earth

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