Poster's note : this idea was discussed by Lockley in reference to control
of methane emissions from water bodies. A methane pilot plant called
Kivuwatt is in development or operation

http://www.sciencedaily.com/releases/2014/12/141218103217.htm?utm_source=feedburner&utm_medium=feed&utm_campaign=Feed%3A+sciencedaily%2Fstrange_science+%28Strange+%26+Offbeat+News+--+ScienceDaily%29

Pilot plant for removal of extreme gas charges from deep waters

December 18, 2014
Helmholtz Centre for Environmental Research - UFZ

Summary:
Being part of the mining area Herrerias, Andalusia, deep waters of Pit Lake
Guadiana show extremely high concentration of dissolved carbon dioxide. In
the case of a spontaneous ebullition, human beings close-by would be
jeopardized. To demonstrate the danger and the possible solution,
scientists constructed a pilot plant for degassing.

Being part of the mining area Herrerias in Andalusia, deep waters of Pit
Lake Guadiana show extremely high concentration of dissolved carbon dioxide
(CO2). In the case of a spontaneous ebullition, human beings close-by would
be jeopardized. To demonstrate the danger and the possible solution,
scientists of the Spanish Institute of Geology and Mining, the University
of the Basque Country (UPV/EHU, Bilbao) and the Helmholtz Centre for
Environmental Research (UFZ) constructed a pilot plant for degassing. A
fountain pulls deep water through a pipe to the surface, where the gas can
escape from the water. The buoyancy produced by the bubbles provides the
energy required for driving the flow.

"The deep water in the residual lake Guadiana contains an extremely high
volume of carbon dioxide (CO2). Oxidation of ores has created a very acidic
milieu, which is also known from other mining areas. In the mining area
Herrerias however, this acidity dissolves carbonate from the rocks and
produces carbonic acid (dissolved CO2), which can be accumulated under the
high pressures of deep waters in the lake. There is not much circulation
beyond 25 meter depth to remove the gas load" says Dr. Bertram Boehrer of
UFZ, who is physicist and has been investigating stratification in lakes at
many places on Earth. Due to the high hydrostatic pressure, each liter of
deep water contains about 2.5 liters of CO2 gas. As long as the
stratification remains stable, the gas is retained in the deep water. A
land slide or other processes producing large water movements could
facilitate a sudden release of gas previously confined under high pressure.
Inhaled air of 8 percent CO2 are considered deadly for humans.Now the
scientists installed a degasing pipe which is the heart of the new pilot
plant: Deep water enters a pipe at 61m depth. On the way up, hydrostatic
pressure drops and gas bubbles form. The reduced density of the
water-gas-mixture allows that deep water is pushed out of the pipe at the
upper end to form a fountain above the water table, where gas is released
to the atmosphere. This is an elegant solution, as the system does not
require any additional driver, and the controlled release of CO2 does not
pose any problem. "With this pilot plant, we could demonstrate that this
approach also works in Guadiana pit lake. This can now be proposed to
authorities as a possible approach to deal with the gas load." Though the
lake in the mining area is fenced and access is not permitted to the
public, this prohibition is difficult to survey.

Earlier installations in Lake Nyos in Cameroon served as a good example for
this approach. In this lake, degassing pipes had been installed, which
released the gas load with three fountains. On August 21st 1986, a large
volume of gas escaped from the lake suddenly. The gas entered valleys of
the surrounding area. 1700 human beings and thousands of animals were
killed. The trigger could have been a land slide though this was never
really proven. To avoid a repetition of this disaster, the gas load is
slowly removed from the lake. One more crater lake called Monoun in
Cameroon suffocated 37 human beings close to its shores in a similar
eruption. Also in Monoun degasing fountains have been installed.In Guadiana
pit lake we do not see the same danger as in Lake Nyos, due to smaller size
and depth. In addition, a density gradient between surface waters and deep
waters is keeping the system stable. However, gas concentrations are so
high that precaution must be taken. More detailed investigations must be
implemented and remediation must be considered, says Dr. Boehrer. For the
formation of such extreme gas loads, lakes must be sufficiently deep with
incomplete winter recirculation (meromixis) and a strong carbon dioxide
source. At the moment, we do not have such a lake in

Source:The above story is based on materials provided by Helmholtz Centre
for Environmental Research - UFZ. The original article was written by Tilo
Arnhold. Note: Materials may be edited for content and length.

Journal Reference:

Javier Sánchez-España, Bertram Boehrer, Iñaki Yusta. Extreme Carbon Dioxide
Concentrations in Acidic Pit Lakes Provoked by Water/Rock
Interaction.Environmental Science & Technology, 2014; 48 (8): 4273
DOI: 10.1021/es5006797

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